Consider this step in a radical reaction:Br-CH3What type of step is this? Check all that apply.Draw the products of the step on the right-hand side of the drawing areabelow. If more than one set of products is possible, draw any set.Also, draw the mechanism arrows on the left-hand side of the drawingarea to show how this happens.passivationpropagationinternalizationinitializationnone of the aboveBrCH3d5Click and drag to startdrawing a structure.

Free radical mechanism:Free radical mechanism has three stepsChain initiationChain propagationChain…

Answered: Consider this step in a radical…

Organic Chemistry: A Guided Inquiry

2nd Edition

ISBN:9780618974122

Author:Andrei Straumanis

Publisher:Andrei Straumanis

Chapter15: Radical Reactions

Section: Chapter Questions

Problem 12E

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6. Draw a detailed free energy diagram for the following reaction. Include and label the overall reactants, the overall products, the intermediate(s), and the axis, activation energies, transition state(s) and overall Gibbs free energy. HOC(CH₂) E1 Draw the Intermediate Draw the Product
ow the mechanism for the following reaction conducted at -5 °C in CC14: cyclohexene + bromine yields a dibromocyclohexane Draw structures - including charges and electrons - and add curved arrows. Details count. Step 1 Add three curved arrows to the first step. Draw the step 1 products: 1 organic species; 1 inorganic species. Step 2 • Reproduce the step 1 products. Add two curved arrows to show the bromide ion reacting with the organic species. Draw the final product. 1L o ↑ Map
5. Each of the following may participate in an elimination reaction, under the proper conditions. (a) Circle the alpha (a) carbon. (b) Circle the beta (B) carbon(s). (c) Draw the alkene product(s) that may form, with the new double bond between the a and B positions. (d) If more than one alkene product is possible, circle the most stable (Zaitsev) product. X tx + 3
Consider this organic reaction Bri CHIỌ Draw the major products of the reaction in the drawing area below. If there won't be any major products, because this reaction won't happen at a significent s rate, check the box under the drawing area instead Z
Curved arrows are used to illustrate the flow of electrons. Follow the curved arrows and draw the structure of the missing reactants, intermediates, or products in the following mechanism. Include all lone pairs. Ignore stereochemistry. Ignore inorganic byproducts.?
Do not give handwriting solution.
7) Assign partial charges on the Cl-Cl (polarized) below. This reaction proceeds through a three-membered ring halonium intermediate. The first step involves arrows similar to the carbene reaction above plus an additional arrow showing the Cl-Cl bond breaking. The second step is SN2 at the more substituted carbon. 8) Complete the following reaction by adding curved arrows, intermediates, and the expected products. St r :CI-CI: :CI: 9) Label the Mechanistic steps above and the halonium ion intermediate. Because the second step is similar to SN2 the halides add anti to each other.
None
octane + NOx + hv (assume hydrogen on second carbon bonded the weakest) For each mechanism, provide the photolytic cycle, a source for hydroxyl radical (if needed) AND atermination step. You may stop when you have accounted for all radicals AND all VOCs are stable (i.e., ifformaldehyde is a product of your mechanism, you do not have to oxidize that molecule to).
1. Draw the mechanism for the following reaction. You should show the initiation and both propogation steps, you do not have to show termination steps Br₂ heat or light Br Draw a reaction coordinate diagram for the reaction in 1. Hint: How many steps are there? In what step is the organic plecule most reactive and least stable?
6. Explain why halogenation occurs twice in the following reaction. Ch₂ NaOH give both answer asap thanks 7. Draw a complete, detailed mechanism for the following reaction. Label the electron-rich and electron-poor sites in each step. H₂SO₂ OSOH

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