CLG 12 – Delocalized Electrons II (10/18/21) 1. 2,3-dimethyl-1,3-pentadiene can conceivably give four products when reacted with HCI, however, only two products predominate. Write a mechanism for this reaction that shows the two products and how they are formed. Which product is favored under kinetically controlled conditions and which is favored under thermodynamically controlled conditions? Explain. 2. Write structural formulas for the major organic product(s) for the following reactions. Be sure to carefully indicate the stereochemistry when relevant. (а) (b) CH,=CH-CH=CH, CH,=CH-CEN heat (c) + H,C=CH-c-H

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CLG 12 – Delocalized Electrons II
(10/18/21)
1.
2,3-dimethyl-1,3-pentadiene can conceivably give four products when reacted with HCI,
however, only two products predominate. Write a mechanism for this reaction that shows
the two products and how they are formed. Which product is favored under kinetically
controlled conditions and which is favored under thermodynamically controlled conditions?
Explain.
2.
Write structural formulas for the major organic product(s) for the following reactions. Be
sure to carefully indicate the stereochemistry when relevant.
(a)
H.
(b)
CH,=CH-CH=CH2
CH,=CH-CEN
heat
(c)
+ H2C=CH-c-H
Transcribed Image Text:CLG 12 – Delocalized Electrons II (10/18/21) 1. 2,3-dimethyl-1,3-pentadiene can conceivably give four products when reacted with HCI, however, only two products predominate. Write a mechanism for this reaction that shows the two products and how they are formed. Which product is favored under kinetically controlled conditions and which is favored under thermodynamically controlled conditions? Explain. 2. Write structural formulas for the major organic product(s) for the following reactions. Be sure to carefully indicate the stereochemistry when relevant. (a) H. (b) CH,=CH-CH=CH2 CH,=CH-CEN heat (c) + H2C=CH-c-H
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