Chemistry
10th Edition
ISBN:9781305957404
Author:Steven S. Zumdahl, Susan A. Zumdahl, Donald J. DeCoste
Publisher:Steven S. Zumdahl, Susan A. Zumdahl, Donald J. DeCoste
Chapter1: Chemical Foundations
Section: Chapter Questions
Problem 1RQ: Define and explain the differences between the following terms. a. law and theory b. theory and...
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Transcribed Image Text:**Twelve Constitutional Isomers of C₄H₇Br**
This educational material explores the reactivity of twelve constitutional isomers with the molecular formula C₄H₇Br in substitution and elimination reactions, assuming no rearrangements occur.
**Isomers:**
- **A**
- **B**
- **C**
- **D**
- **E**
- **F**
- **G**
- **H**
- **I**
- **J**
- **K**
- **L**
**Questions:**
1. **Which 2 isomers would react fastest in an Sₙ2 reaction?**
2. **Which 4 isomers could participate in both Sₙ1 and E2?**
3. **Which 4 isomers could create terminal alkenes in bimolecular elimination?**
4. **Which 2 isomers would not work in E1/E2 but could react in Sₙ1/Sₙ2?**
5. **Which 4 isomers would not participate in substitution or elimination?**
6. **Which isomer could participate in Sₙ1 but not Sₙ2?**
7. **Which 3 isomers contain secondary leaving groups?**
8. **Which 3 isomers could create resonance-stabilized carbocations?**
**Diagrams:**
- Each isomer is represented with its structural formula, indicating the position of the bromine (Br) atom and other functional groups or bonding arrangements, which are crucial for understanding their reactivity in various chemical reactions.
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