Ketones and aldehydes react with sodium acetylide (the sodium salt of acetylene) to give alcohols, as shown in the following example: R₁ OH 1. HC=C: Na* + R₂ Rí R2 2. H3O+ HC Draw the structure of the major reaction product when the following compound reacts with sodium acetylide, assuming that the reaction takes preferentially from the Re face of the carbonyl group. • Use the wedge/hash bond tools to indicate stereochemistry where it exists. • You do not have to explicitly draw H atoms. •If a group is achiral, do not use wedged or hashed bonds on it. E CH3 H3C

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Ketones and aldehydes react with sodium acetylide (the sodium salt of acetylene) to give
alcohols, as shown in the following example:
R₁ OH
1. HC=C: Na*
+
R₂
Rí
R2
2. H3O+
HC
Draw the structure of the major reaction product when the following compound reacts with
sodium acetylide, assuming that the reaction takes preferentially from the Re face of the
carbonyl group.
• Use the wedge/hash bond tools to indicate stereochemistry where it exists.
• You do not have to explicitly draw H atoms.
•If a group is achiral, do not use wedged or hashed bonds on it.
E
CH3
H3C
Transcribed Image Text:Ketones and aldehydes react with sodium acetylide (the sodium salt of acetylene) to give alcohols, as shown in the following example: R₁ OH 1. HC=C: Na* + R₂ Rí R2 2. H3O+ HC Draw the structure of the major reaction product when the following compound reacts with sodium acetylide, assuming that the reaction takes preferentially from the Re face of the carbonyl group. • Use the wedge/hash bond tools to indicate stereochemistry where it exists. • You do not have to explicitly draw H atoms. •If a group is achiral, do not use wedged or hashed bonds on it. E CH3 H3C
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