4-tert-butylcyclohexanol S(ppm)JEOLOFilenameAuthorExperimentSample_IdSolventActual_Start_TimeRevision Time- Comp sample 4_PROTO- delta- proton.jxp- Comp sample 4- CHLOROFORM-D- 30-SEP-2021 16:18:3- 30-SEP-2021 16:05:3Data FormatDin SizeX DomainDin TitleDim UnitaDimenaionsSpectrometer- 1D COMPLEX- 26214- Proton- Proton- [ppm)- JNM-ECZ400S/L1Field StrengthX_Aoq DurationX_DomainX_Freqx OffsetX_Pointax_PrescansX_ResolutionX_SweepX_Sveep_ClipPpedIEE DomainIrr FreqIrr offsetTri DomainTri PreqTri OffsetBlankingClippedScana- 9. 389766 (2) (400 (M- 4.37256192[a)- Proton- 399. 78219838 (MH)- 5(ppm)- 32768- 0.22869888[Hz)- 7.4940048 (kHa)- 5.99520384 (kHz)- Proton- 399. 78219838 (Mz)- S(ppm)- Proton- 399. 78219838 (MEz)- Stppm]- 2[us)- FALSE- 32- 32Total_ScansRelaxation DelayRecve GainTanp Getx 90 WidthXX Acq TimeX_AngleX_Atn* PulseIrr ModeTri ModeDante LoopDante PresatDecimation_RateExperiment PathInitial WaitPhase- 4[0]- 42- 23[dc)- 6.097 (ua)- 4.37256192[8]- 45(deg)- 2[dB]- 3.0485 (us)- off- off- 400- PALSEêthanolimpurity- e: \Program Piles\JE- (0, 90, 270, 180, 1Presat TimePresat Time FlagRalaxation Delay Cale = O(e)Relaxation Delay Temp- 4(]Repatition Time- FALSE= 8.37256192 (s]4.03.02.01.0X: parts per Million : Protonabundance0 0.01 0.02 0.03 0.04 0.05 0.06 0.07 0.08 0.09 0,1 0.11 0.12 0.13 0.14 0.15 0.16 0.17 0.18 0.19 0.2 0.21 0.22 0.233.62 What is the ratio of cis- : trans-isomers in the product mixture?Is the ratio an enantiomeric ratio (er) or a diastereomeric ratio (dr)?One of the reasons that the spectral signals are well-resolved is that the products areconformationally locked and cannot “ring flip". What structural feature is responsible for thiseffect, and why?

The objective of this question is to explain the signals present in the given spectrum. The nmr…

07 0.08 0.09 0.1 0.11 0.12 0.13 0.14 0.15 0.16 0.17 0.18 0.19 0.2 0.21 0.22 0.23 3.62 Filename Author JEOLO Experiment Sample Id Solvent Actual Start Time Revision Time Data Format Din Size X_Domain Din Title Din Units Dimensions Spectrometer Field Strength X_Aoq Duration X Domain X Freq X_Offset x Points X Prescans X_Resolution X Sweep X Irr Domain Irr_ Freq IEF Offset Tri Domain Tri Freq Tri offeet Blanking Clipped Scans Total Scans Sweep_Clipped Relaxation Delay Comp sample 4 PROTO delta - - proton.jxp Comp sample 4 CHLOROFORM-D - 30-SEP-2021 16:18:3 - 30-SEP-2021 16:05:3 1D COMPLEX - 26214 - Proton - Proton - [(ppm) J-ECZ4008/11 -9.389766 [7] (400 [ME -4.37256192[*] - Proton -399.78219838) - 5(ppm) -32768 -0 -0.22869888(N) -7.4940048[k] -5.99520384[k] -399.78219838] - Proton - 5(ppm) - Proton - 399.78219838) <- 5(ppm) <-2[us] = FALSE -32 -32 <- 4[0]

07 0.08 0.09 0.1 0.11 0.12 0.13 0.14 0.15 0.16 0.17 0.18 0.19 0.2 0.21 0.22 0.23 3.62 Filename Author JEOLO Experiment Sample Id Solvent Actual Start Time Revision Time Data Format Din Size X_Domain Din Title Din Units Dimensions Spectrometer Field Strength X_Aoq Duration X Domain X Freq X_Offset x Points X Prescans X_Resolution X Sweep X Irr Domain Irr_ Freq IEF Offset Tri Domain Tri Freq Tri offeet Blanking Clipped Scans Total Scans Sweep_Clipped Relaxation Delay Comp sample 4 PROTO delta - - proton.jxp Comp sample 4 CHLOROFORM-D - 30-SEP-2021 16:18:3 - 30-SEP-2021 16:05:3 1D COMPLEX - 26214 - Proton - Proton - [(ppm) J-ECZ4008/11 -9.389766 [7] (400 [ME -4.37256192[*] - Proton -399.78219838) - 5(ppm) -32768 -0 -0.22869888(N) -7.4940048[k] -5.99520384[k] -399.78219838] - Proton - 5(ppm) - Proton - 399.78219838) <- 5(ppm) <-2[us] = FALSE -32 -32 <- 4[0]

Chemistry

10th Edition

ISBN:9781305957404

Author:Steven S. Zumdahl, Susan A. Zumdahl, Donald J. DeCoste

Publisher:Steven S. Zumdahl, Susan A. Zumdahl, Donald J. DeCoste

Chapter1: Chemical Foundations

Section: Chapter Questions

Problem 1RQ: Define and explain the differences between the following terms. a. law and theory b. theory and...

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Question

4-tert-butylcyclohexanol

S(ppm)
JEOLO
Filename
Author
Experiment
Sample_Id
Solvent
Actual_Start_Time
Revision Time
- Comp sample 4_PROTO
- delta
- proton.jxp
- Comp sample 4
- CHLOROFORM-D
- 30-SEP-2021 16:18:3
- 30-SEP-2021 16:05:3
Data Format
Din Size
X Domain
Din Title
Dim Unita
Dimenaions
Spectrometer
- 1D COMPLEX
- 26214
- Proton
- Proton
- [ppm)
- JNM-ECZ400S/L1
Field Strength
X_Aoq Duration
X_Domain
X_Freq
x Offset
X_Pointa
x_Prescans
X_Resolution
X_Sweep
X_Sveep_ClipPped
IEE Domain
Irr Freq
Irr offset
Tri Domain
Tri Preq
Tri Offset
Blanking
Clipped
Scana
- 9. 389766 (2) (400 (M
- 4.37256192[a)
- Proton
- 399. 78219838 (MH)
- 5(ppm)
- 32768
- 0.22869888[Hz)
- 7.4940048 (kHa)
- 5.99520384 (kHz)
- Proton
- 399. 78219838 (Mz)
- S(ppm)
- Proton
- 399. 78219838 (MEz)
- Stppm]
- 2[us)
- FALSE
- 32
- 32
Total_Scans
Relaxation Delay
Recve Gain
Tanp Get
x 90 Width
X
X Acq Time
X_Angle
X_Atn
* Pulse
Irr Mode
Tri Mode
Dante Loop
Dante Presat
Decimation_Rate
Experiment Path
Initial Wait
Phase
- 4[0]
- 42
- 23[dc)
- 6.097 (ua)
- 4.37256192[8]
- 45(deg)
- 2[dB]
- 3.0485 (us)
- off
- off
- 400
- PALSE
êthanol
impurity
- e: \Program Piles\JE
- (0, 90, 270, 180, 1
Presat Time
Presat Time Flag
Ralaxation Delay Cale = O(e)
Relaxation Delay Temp- 4(]
Repatition Time
- FALSE
= 8.37256192 (s]
4.0
3.0
2.0
1.0
X: parts per Million : Proton
abundance
0 0.01 0.02 0.03 0.04 0.05 0.06 0.07 0.08 0.09 0,1 0.11 0.12 0.13 0.14 0.15 0.16 0.17 0.18 0.19 0.2 0.21 0.22 0.23
3.62

What is the ratio of cis- : trans-isomers in the product mixture?
Is the ratio an enantiomeric ratio (er) or a diastereomeric ratio (dr)?
One of the reasons that the spectral signals are well-resolved is that the products are
conformationally locked and cannot “ring flip". What structural feature is responsible for this
effect, and why?

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Step 2: 4-tert-butylcyclohexanol nmr

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Step 3: Ratio of cis and trans isomers

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Step 4: Enantiomeric ratio (er) or diastereomer ratio (dr)

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Step 5: c) Conforming locking and ring rotation

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