16.82 An oversimplified version of the CH3CHO decomposi- tion mechanism is (1) CH,CHO →CH, + CHO (2) CH3 + CH3CHO CH4 + CH3CO (3) CH3COCO + CH3 (4) 2CH3 → C₂H6 (The CHO reacts to form minor amounts of various species.) (a) Identify the initiation, propagation, and termination steps. (b) What is the overall reaction, neglecting minor products formed in initiation and termination steps? (c) Show that r =

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16.82 An oversimplified version of the CH3CHO decomposi-
tion mechanism is
(1)
CH,CHO →CH, + CHO
(2)
CH3 + CH3CHO CH4 + CH3CO
(3)
CH3COCO + CH3
(4)
2CH3 → C₂H6
(The CHO reacts to form minor amounts of various species.)
(a) Identify the initiation, propagation, and termination steps.
(b) What is the overall reaction, neglecting minor products
formed in initiation and termination steps? (c) Show that r =
k[CH3CHO] 3/2, where k = k₂(k₁/2k₁)¹/²
Transcribed Image Text:16.82 An oversimplified version of the CH3CHO decomposi- tion mechanism is (1) CH,CHO →CH, + CHO (2) CH3 + CH3CHO CH4 + CH3CO (3) CH3COCO + CH3 (4) 2CH3 → C₂H6 (The CHO reacts to form minor amounts of various species.) (a) Identify the initiation, propagation, and termination steps. (b) What is the overall reaction, neglecting minor products formed in initiation and termination steps? (c) Show that r = k[CH3CHO] 3/2, where k = k₂(k₁/2k₁)¹/²
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