A given reaction H3COH + H* + Br → H3CBr + H2O has the following proposed mechanism step 1: H3COH + H*→ H3COH* (k1) step 2: H3COH2* → H3COH + H* (k2) step 3: Br + H3COH2* → H3CB + H2O (k3) Using the steady state approximation, derive dHIC Brl for the reaction. dt k[H,COH]+k}[H*][Br¯]| kzky[Br-] rate = O rate = kik2 [H*] [Br¯] O rate = k2 (H,COH) [H*] [Br| kikilH,COH][H*][Br"]| rate = kz+ ks[Br"] O rate = kıkaka[Br-1² %3D

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A given reaction
H3COH + H* + Br → H3CB + H20
has the following proposed mechanism
step 1: H3COH + H*→ H3COH* (k1)
step 2: H3COH2* → H3COH + H* (k2)
step 3: Br + H3COH2* → H3CB + H2O (k3)
d[H¸CBr],
Using the steady state approximation, derive
for the reaction.
dt
k,[H,COH]+ks[H*][Br-]
kzky[Br-]
rate =
O rate = kık2 [H*] [Br¯]
O rate = (H;COH| [H*] [Br¯]
kiks[H,COH](H*][Br"]
kz+ k3[Br"]
rate =
O rate = kıkɔka[Br-1²
Transcribed Image Text:A given reaction H3COH + H* + Br → H3CB + H20 has the following proposed mechanism step 1: H3COH + H*→ H3COH* (k1) step 2: H3COH2* → H3COH + H* (k2) step 3: Br + H3COH2* → H3CB + H2O (k3) d[H¸CBr], Using the steady state approximation, derive for the reaction. dt k,[H,COH]+ks[H*][Br-] kzky[Br-] rate = O rate = kık2 [H*] [Br¯] O rate = (H;COH| [H*] [Br¯] kiks[H,COH](H*][Br"] kz+ k3[Br"] rate = O rate = kıkɔka[Br-1²
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