In addition to filling in the blanks below, show all of your work for this problem on paper for later upload. Two mechanisms have been proposed for the formation of HBr from elemental hydrogen and bromine. Here is Mechanism I: Br2 + M 2 2 Br + M fast Br + H2 4 HBr + H slow H + Brz 4 HBr + Br fast where M is called an inert, third body intermediate (for example, N2). Mechanism II is: H + Brz 2 HBr (slow) a) Derive the rate law for Mechanism I (show all work on paper - use a ^ here to indicate a superscript if necessary). b) Derive the rate law for Mechanism II (show all work on paper - use a ^ here to indicate a superscript if necessary).
In addition to filling in the blanks below, show all of your work for this problem on paper for later upload. Two mechanisms have been proposed for the formation of HBr from elemental hydrogen and bromine. Here is Mechanism I: Br2 + M 2 2 Br + M fast Br + H2 4 HBr + H slow H + Brz 4 HBr + Br fast where M is called an inert, third body intermediate (for example, N2). Mechanism II is: H + Brz 2 HBr (slow) a) Derive the rate law for Mechanism I (show all work on paper - use a ^ here to indicate a superscript if necessary). b) Derive the rate law for Mechanism II (show all work on paper - use a ^ here to indicate a superscript if necessary).
Chemistry
10th Edition
ISBN:9781305957404
Author:Steven S. Zumdahl, Susan A. Zumdahl, Donald J. DeCoste
Publisher:Steven S. Zumdahl, Susan A. Zumdahl, Donald J. DeCoste
Chapter1: Chemical Foundations
Section: Chapter Questions
Problem 1RQ: Define and explain the differences between the following terms. a. law and theory b. theory and...
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![### Understanding Reaction Mechanisms and Rate Laws
In chemical kinetics, understanding the mechanisms and deriving the rate laws of reactions is crucial to predict how different factors influence reaction rates. Below, we explore the rate laws for two different proposed mechanisms for a reaction involving hydrogen (H₂) and bromine (Br₂) to produce hydrogen bromide (HBr).
#### Mechanism II:
$$H_2 + Br_2 \xrightarrow{k_2} 2HBr \hspace{5pt} (\text{slow})$$
### Exercises
**a) Derive the rate law for Mechanism I.**
*Show all work on paper - use a ^ here to indicate a superscript if necessary.*
\[ \boxed{\text{Answer}} \]
**b) Derive the rate law for Mechanism II.**
*Show all work on paper - use a ^ here to indicate a superscript if necessary.*
\[ \boxed{\text{Answer}} \]
**c) The observed rate law for the reaction is \(r = k_{obs}[H_2][Br_2]^{1/2}\). Which mechanism is consistent with this observation? Clearly indicate Mechanism I or Mechanism II.**
\[ \boxed{\text{Answer}} \]
**d) Based on your answer to part (c) above, write the observed rate constant \(k_{obs}\) in terms of the rate constants used in the relevant mechanism.**
*Show all work on paper - use a ^ here to indicate a superscript if necessary.*
\[ \boxed{\text{Answer}} \]
### Detailed Explanation of Mechanisms and Graphs/Diagrams
There is no graphical or diagrammatic representation in the image. However, you are requested to derive and analyze the rate laws and mechanisms as described above. Remember to provide detailed steps in your derivations and clearly indicate any assumptions or approximations you make.
These exercises are designed to help you understand how different mechanistic steps impact the overall rate law of the reaction and the importance of intermediates in determining reaction kinetics. In-depth knowledge of these aspects is essential for students aiming to master the principles of chemical kinetics.](/v2/_next/image?url=https%3A%2F%2Fcontent.bartleby.com%2Fqna-images%2Fquestion%2F51136f38-e2b3-40fe-b825-8cf4e5f95f23%2F82109fc3-c2cf-4ccd-a816-fd5528404227%2F112nwaw_processed.jpeg&w=3840&q=75)
Transcribed Image Text:### Understanding Reaction Mechanisms and Rate Laws
In chemical kinetics, understanding the mechanisms and deriving the rate laws of reactions is crucial to predict how different factors influence reaction rates. Below, we explore the rate laws for two different proposed mechanisms for a reaction involving hydrogen (H₂) and bromine (Br₂) to produce hydrogen bromide (HBr).
#### Mechanism II:
$$H_2 + Br_2 \xrightarrow{k_2} 2HBr \hspace{5pt} (\text{slow})$$
### Exercises
**a) Derive the rate law for Mechanism I.**
*Show all work on paper - use a ^ here to indicate a superscript if necessary.*
\[ \boxed{\text{Answer}} \]
**b) Derive the rate law for Mechanism II.**
*Show all work on paper - use a ^ here to indicate a superscript if necessary.*
\[ \boxed{\text{Answer}} \]
**c) The observed rate law for the reaction is \(r = k_{obs}[H_2][Br_2]^{1/2}\). Which mechanism is consistent with this observation? Clearly indicate Mechanism I or Mechanism II.**
\[ \boxed{\text{Answer}} \]
**d) Based on your answer to part (c) above, write the observed rate constant \(k_{obs}\) in terms of the rate constants used in the relevant mechanism.**
*Show all work on paper - use a ^ here to indicate a superscript if necessary.*
\[ \boxed{\text{Answer}} \]
### Detailed Explanation of Mechanisms and Graphs/Diagrams
There is no graphical or diagrammatic representation in the image. However, you are requested to derive and analyze the rate laws and mechanisms as described above. Remember to provide detailed steps in your derivations and clearly indicate any assumptions or approximations you make.
These exercises are designed to help you understand how different mechanistic steps impact the overall rate law of the reaction and the importance of intermediates in determining reaction kinetics. In-depth knowledge of these aspects is essential for students aiming to master the principles of chemical kinetics.
![### Reaction Mechanisms for the Formation of HBr
In addition to filling in the blanks below, show all of your work for this problem on paper for later upload.
#### Mechanism I:
Two mechanisms have been proposed for the formation of HBr from elemental hydrogen and bromine. Here is Mechanism I:
\[
\text{Br}_2 + \text{M} \underset{k_{-1}}{\stackrel{k_1}{\rightleftharpoons}} 2 \text{Br} + \text{M} \quad(\text{fast})
\]
\[
\text{Br} + \text{H}_2 \stackrel{k_2}{\rightarrow} \text{HBr} + \text{H} \quad(\text{slow})
\]
\[
\text{H} + \text{Br}_2 \stackrel{k_3}{\rightarrow} \text{HBr} + \text{Br} \quad(\text{fast})
\]
where M is called an inert, third-body intermediate (for example, \( \text{N}_2 \)).
#### Mechanism II:
Mechanism II is:
\[
\text{H}_2 + \text{Br}_2 \stackrel{k_2}{\rightarrow} 2 \text{HBr} \quad(\text{slow})
\]
### Questions:
a) Derive the rate law for Mechanism I (show all work on paper - use a ^ here to indicate a superscript if necessary).
\[ \boxed{\phantom{Rate\ Law\ Here}} \]
b) Derive the rate law for Mechanism II (show all work on paper - use a ^ here to indicate a superscript if necessary).
\[ \boxed{\phantom{Rate\ Law\ Here}} \]
Please ensure to document each step carefully and write legibly for your submission.](/v2/_next/image?url=https%3A%2F%2Fcontent.bartleby.com%2Fqna-images%2Fquestion%2F51136f38-e2b3-40fe-b825-8cf4e5f95f23%2F82109fc3-c2cf-4ccd-a816-fd5528404227%2Fdvyz41a_processed.jpeg&w=3840&q=75)
Transcribed Image Text:### Reaction Mechanisms for the Formation of HBr
In addition to filling in the blanks below, show all of your work for this problem on paper for later upload.
#### Mechanism I:
Two mechanisms have been proposed for the formation of HBr from elemental hydrogen and bromine. Here is Mechanism I:
\[
\text{Br}_2 + \text{M} \underset{k_{-1}}{\stackrel{k_1}{\rightleftharpoons}} 2 \text{Br} + \text{M} \quad(\text{fast})
\]
\[
\text{Br} + \text{H}_2 \stackrel{k_2}{\rightarrow} \text{HBr} + \text{H} \quad(\text{slow})
\]
\[
\text{H} + \text{Br}_2 \stackrel{k_3}{\rightarrow} \text{HBr} + \text{Br} \quad(\text{fast})
\]
where M is called an inert, third-body intermediate (for example, \( \text{N}_2 \)).
#### Mechanism II:
Mechanism II is:
\[
\text{H}_2 + \text{Br}_2 \stackrel{k_2}{\rightarrow} 2 \text{HBr} \quad(\text{slow})
\]
### Questions:
a) Derive the rate law for Mechanism I (show all work on paper - use a ^ here to indicate a superscript if necessary).
\[ \boxed{\phantom{Rate\ Law\ Here}} \]
b) Derive the rate law for Mechanism II (show all work on paper - use a ^ here to indicate a superscript if necessary).
\[ \boxed{\phantom{Rate\ Law\ Here}} \]
Please ensure to document each step carefully and write legibly for your submission.
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