proposed mechanism for the formation of phosgene (COCl₂) can be written in a simplified form as: Cl₂ (g) Part A What rate law corresponds to this mechanism? ks Oks ks k3 ka k3 ka ka ₂ [CO][C1₂13/2 k₁ k₁ k₂ [co]³/²[C1₂] [CO][C1₂]³/2 k₂ kı [CO]³/2 [C1₂] 2Cl(g) Cl(g) + CO(g) COCI(g) k4 COCI(g) + Cl₂(g) → COC1₂ (g) +Cl(g) ks Fast Fast Slow

Chemistry
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Author:Steven S. Zumdahl, Susan A. Zumdahl, Donald J. DeCoste
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Chapter1: Chemical Foundations
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he proposed mechanism for the formation of phosgene (COC1₂) can be written in a simplified form as:
Cl₂ (g)
Part A
What rate law corresponds to this mechanism?
k5
k3
kı
K₁ K₂
k₁
k₂
Oks kz ki
k5
[CO]³/² [C1₂]
k4
k₂
K5 K3 k₁
[CO][C1₂]3/2
k3
k₁
K₁ K₂
[CO][C1₂]3/2
[CO]³/2[C1₂]
2C1(g)
Cl(g) + CO(g)
COCI(g)
COCI(g) + Cl₂(g) → COC12 (g) + Cl(g)
ks
Fast
Fast
Slow
Transcribed Image Text:he proposed mechanism for the formation of phosgene (COC1₂) can be written in a simplified form as: Cl₂ (g) Part A What rate law corresponds to this mechanism? k5 k3 kı K₁ K₂ k₁ k₂ Oks kz ki k5 [CO]³/² [C1₂] k4 k₂ K5 K3 k₁ [CO][C1₂]3/2 k3 k₁ K₁ K₂ [CO][C1₂]3/2 [CO]³/2[C1₂] 2C1(g) Cl(g) + CO(g) COCI(g) COCI(g) + Cl₂(g) → COC12 (g) + Cl(g) ks Fast Fast Slow
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