(a) Draw and label a process flow diagram for this process. Number each stream. Clearly label the components (E,W,B) in each stream. (b) Calculate the flow rate (mol/hr) of all unknown streams entering and exiting the system. (c) Calculate the flow rate (mol/hr) and mole fractions of the stream exiting the bottom of the distillation column.

Introduction to Chemical Engineering Thermodynamics
8th Edition
ISBN:9781259696527
Author:J.M. Smith Termodinamica en ingenieria quimica, Hendrick C Van Ness, Michael Abbott, Mark Swihart
Publisher:J.M. Smith Termodinamica en ingenieria quimica, Hendrick C Van Ness, Michael Abbott, Mark Swihart
Chapter1: Introduction
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Problem 1.1P
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A two-unit separation is used to dewater ethanol. First, a 110 mol/hr feed of a mixture of 0.750 mole
fraction ethanol (E) and the balance water (W) is distilled. The extractive agent, benzene (B), is added to
the distillation column in a mixture of 0.940 mole fraction benzene (0.060 mole fraction water). This
mixture consists of fresh benzene and the recycle stream of benzene and water recovered from the
separator. The company wishes to produce 0.995 mole fraction ethanol (0.005 mole fraction benzene)
product stream from the overhead of the distillation column. The bottoms product, containing just
benzene and water, is sent to the separator. The composition of the benzene/water mixture leaving the
bottom of the separator is 0.85 mole fraction benzene and the balance water. Some of the bottom
stream leaving the separator is recycled and added to the fresh benzene feed to the column and the rest
of the bottom stream (121 mol/hr) is sent to another unit (not included in this analysis). The stream
leaving the top of the separator is pure water.

(a) Draw and label a process flow diagram for this process. Number each stream. Clearly label the
components (E,W,B) in each stream.
(b) Calculate the flow rate (mol/hr) of all unknown streams entering and exiting the system.
(c) Calculate the flow rate (mol/hr) and mole fractions of the stream exiting the bottom of the
distillation column.

Expert Solution
Step 1: Given data

Here two unit is used to dewater ethanol.

Molar flow rate of feed, F = 110 mol/hr 

Mole fraction of ethanol = 0.750 

Benzene is added as a solvent. 

Mole fraction of benzene = 0.940 

Product stream mole fraction = 0.995


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