4. Use your answer to Q3 to predict the product(s) of yourreaction if you had started with (Z)-stilbene. Use wordsand drawings to support any regio-stereochemistry in your product(s).andHBrH2O2Ethanol

Answered: Image /qna-images/answer/683cb900-97d2-4a6a-8562-67d5cfccde3a.jpg

Answered: 4. Use your answer to Q3 to predict the…

Chemistry

10th Edition

ISBN:9781305957404

Author:Steven S. Zumdahl, Susan A. Zumdahl, Donald J. DeCoste

Publisher:Steven S. Zumdahl, Susan A. Zumdahl, Donald J. DeCoste

Chapter1: Chemical Foundations

Section: Chapter Questions

Problem 1RQ: Define and explain the differences between the following terms. a. law and theory b. theory and...

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For the following reactions, fill in the boxes with the starting material that leads to the predominant product or products.
2. Show the mechanism with arrow formalism to show the formation of the most stable product. Which of the following terms apply to the mechanism(s) i) Regioselectivity (ii)stereoselectivity (iii)stereospecificity. Explain H+ (aq) from sulfuric acid NaCN most stable product
2. What Alkene would be used to synthesize 3-bromohexane? + HBr CH;CH,CHCH,CH,CH3 br 3. Write down the mechanism for the following reaction and predict which of the two possible products will be formed in the greatest yield ( 2nd and 3d carbocation). Write down the structures of the two possible products and explain your answer. CH;CH = CHCH, CH, CH3 + HBr
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4. Propose a reasonable mechanism for the reaction shown below. Include all mechanistic intermediates in their correct order, use arrows correctly to indicate bond making/breaking (i.e., movement of electrons, NOT atoms or charge symbols), and clearly show which atoms (if any) contain formal charges. NaOH U. Ef H₂O نز
Predict the major substitution products of the following reaction. Br CH3 H20 H3C" • Use the wedge/hash bond tools to indicate stereochemistry where it exists. • If there is more than one major product possible, draw all of them. • Draw one structure per sketcher. Add additional sketchers using the drop-down menu in the bottom right corner. • Separate multiple products using the + sign from the drop-down menu. opy aste ChemDoodle
What product(s) would you expect from the following reaction? CH3 NBS, Br2 ? CCIL, hv • You do not have to consider stereochemistry. • If more than one structure fits the description, draw them all. • Draw one structure per sketcher. Add additional sketchers using the drop-down memu in the bottom right comer. • Separate structures with + signs from the drop-down memu.
4. The reaction of the epoxide with methoxide produces one of the two constitutional isomers of methoxy-methylcyclopentanol shown below. Write the steps in the mechanism for this process. Be sure to show the following: (1) the structure of any intermediates that are formed during the mechanism, (2), what, if anything, is added or lost during each step of the mechanism, (3) any non-zero formal charges found on the structures that you write. REMEMBER: You may not use any materials except those that are given in the equation. OH H₂C * F OH NaOME/McOH
This question has multiple parts. Work all the parts to get the most points. meta-Chloroperoxybenzoic acid (m-CPBA) is not the only peroxy acid capable of reacting with alkenes to form epoxides. For the reaction below: H3C H3C CH₂ + CF3CO3H a Draw the structure of the major organic product derived from the alkene. • Use the wedge/hash bond tools to indicate stereochemistry where it exists. • Use wedge and hash bonds ONLY when needed to show reaction stereochemistry. . If the reaction produces a racemic mixture, just draw one stereoisomer. 3*2 c C -> O 000 - IF
3. Show the synthetic steps needed to make cis-1-ethyl-2-methylcyclopropane from acetylene. Show intermediate products, not mechanisms.
4.
(b) The activating and deactivating groups could affect the position(s) of the next incoming group(s) to the benzene ring. Based on the structure below, analyze and explain the group(s) on the benzene ring is activating or deactivating group. Then, identify the product(s) formed from the following reactions. NH, CC, CH;CH,COCI AICI, (i) NH, HNO, H,SO, (ii) H Br AICI, (iii) Page 3 of 4

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4. Use your answer to Q3 to predict the product(s) of your reaction if you had started with (Z)-stilbene. Use words and drawings to support any regio- stereochemistry in your product(s). and HBr H2O2 Ethanol