3) A redox titration: 160.00 mL of 0.0500 M Sn2+ solution was titrated with 0.200 M Ce according to the reaction below. Buret containing Ce Calomel reference electrode. 0.00500 M Sn Magnetic stirring bar Titration reaction: 2 Ce++ Sn2+-------> 2 Ce3+ + Sn4+ Eº Cee-------> Ce3+ Sn+ + 2e------> Sn²+ 1.470 V 0.139 V a) What is V. (the equivalence volume) (of Ce") needed to reach the endpoint? b) Calculate the potential (voltage), when 10.00 mL Ce" is added. c) What is the cell potential at the equivalence point? d) What is the cell potential when 60 mL Ce4+ is added? SCE = +0.241 V

Fundamentals Of Analytical Chemistry
9th Edition
ISBN:9781285640686
Author:Skoog
Publisher:Skoog
Chapter16: Applications Of Neutralization Titrations
Section: Chapter Questions
Problem 16.40QAP
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3) A redox titration: 160.00 mL of 0.0500 M Sn2+ solution was titrated with 0.200 M Ce according to the
reaction below.
Buret containing Ce
Calomel
reference
electrode.
0.00500 M Sn
Magnetic
stirring bar
Titration reaction:
2 Ce++ Sn2+-------> 2 Ce3+ + Sn4+
Eº
Cee-------> Ce3+
Sn+ + 2e------> Sn²+
1.470 V
0.139 V
a) What is V. (the equivalence volume) (of Ce") needed to reach the endpoint?
b) Calculate the potential (voltage), when 10.00 mL Ce" is added.
c) What is the cell potential at the equivalence point?
d) What is the cell potential when 60 mL Ce4+ is added?
SCE = +0.241 V
Transcribed Image Text:3) A redox titration: 160.00 mL of 0.0500 M Sn2+ solution was titrated with 0.200 M Ce according to the reaction below. Buret containing Ce Calomel reference electrode. 0.00500 M Sn Magnetic stirring bar Titration reaction: 2 Ce++ Sn2+-------> 2 Ce3+ + Sn4+ Eº Cee-------> Ce3+ Sn+ + 2e------> Sn²+ 1.470 V 0.139 V a) What is V. (the equivalence volume) (of Ce") needed to reach the endpoint? b) Calculate the potential (voltage), when 10.00 mL Ce" is added. c) What is the cell potential at the equivalence point? d) What is the cell potential when 60 mL Ce4+ is added? SCE = +0.241 V
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