27. Complete the following equations providing the right product, reagent or starting material as needed. CH3CI AICI3 ? KMN04 .COOH

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27. Complete the following equations providing the right product, reagent or starting material as needed.
CH;CI
AICI3
?
KMN04
.COOH
Transcribed Image Text:27. Complete the following equations providing the right product, reagent or starting material as needed. CH;CI AICI3 ? KMN04 .COOH
Expert Solution
Step 1

When benzene is treated with MeCl and AlCl3 then toluene is formed. This is called Friedel-Craft alkylation reaction. Me group is EDG. Hence, it activates the phenyl ring. Hence, in next step electrophilic chlorination reaction occurs at streric repulsion free para position. In presence of catalyst chlorination occurs in phenyl ring. Finally on oxidation with KMnO4 gives 4-chloro benzoic acid. 

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