AH KJ/mol S°, J/mol AG, KJ/mol CH3OH -201.2 237.6 -161.9 H2 130.58 -32.89 C2H6 H20 -84.68 229.5 -241.82 188.83 -228.57 2CH;OH(g) + H2(g) C,H5(g) + 2H,0(g) AH° = -165.92 kJ/mol AS° = 1.18 J/mol AG° = -166.23 kJ/mol Is the reaction exothermic or endothermic? Explain your answer. Is the reaction endergonic or exergonic? Explain your answer.

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Author:Steven S. Zumdahl, Susan A. Zumdahl, Donald J. DeCoste
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**Transcription and Explanation for an Educational Website**

**Thermochemical Data Table:**
- **Standard Enthalpy Change (\(ΔH^\circ\) KJ/mol):**
  - CH\(_3\)OH: -201.2
  - H\(_2\): 0
  - C\(_2\)H\(_6\): -84.68
  - H\(_2\)O: -241.82

- **Standard Entropy (\(S^\circ\) J/mol):**
  - CH\(_3\)OH: 237.6
  - H\(_2\): 130.58
  - C\(_2\)H\(_6\): 229.5
  - H\(_2\)O: 188.83

- **Standard Gibbs Free Energy Change (\(ΔG^\circ\) KJ/mol):**
  - CH\(_3\)OH: -161.9
  - H\(_2\): 0
  - C\(_2\)H\(_6\): -32.89
  - H\(_2\)O: -228.57

**Chemical Reaction:**

\[ 2\text{CH}_3\text{OH(g)} + \text{H}_2\text{(g)} \rightleftharpoons \text{C}_2\text{H}_6\text{(g)} + 2\text{H}_2\text{O(g)} \]

**Calculated Thermochemical Values for the Reaction:**
- \(ΔH^\circ = -165.92 \text{ kJ/mol}\)
- \(ΔS^\circ = 1.18 \text{ J/mol}\)
- \(ΔG^\circ = -166.23 \text{ kJ/mol}\)

**Discussion Questions:**

1. **Is the reaction exothermic or endothermic? Explain your answer.**

2. **Is the reaction endergonic or exergonic? Explain your answer.**

3. **Is the reaction spontaneous in the forward direction? Explain your answer.**

4. **Draw Lewis structures for the system under study in this experiment.**

5. **Is the reaction in question 8 isodesmic? Explain how you know.**

**Graphical Explanation:**
No graphs
Transcribed Image Text:**Transcription and Explanation for an Educational Website** **Thermochemical Data Table:** - **Standard Enthalpy Change (\(ΔH^\circ\) KJ/mol):** - CH\(_3\)OH: -201.2 - H\(_2\): 0 - C\(_2\)H\(_6\): -84.68 - H\(_2\)O: -241.82 - **Standard Entropy (\(S^\circ\) J/mol):** - CH\(_3\)OH: 237.6 - H\(_2\): 130.58 - C\(_2\)H\(_6\): 229.5 - H\(_2\)O: 188.83 - **Standard Gibbs Free Energy Change (\(ΔG^\circ\) KJ/mol):** - CH\(_3\)OH: -161.9 - H\(_2\): 0 - C\(_2\)H\(_6\): -32.89 - H\(_2\)O: -228.57 **Chemical Reaction:** \[ 2\text{CH}_3\text{OH(g)} + \text{H}_2\text{(g)} \rightleftharpoons \text{C}_2\text{H}_6\text{(g)} + 2\text{H}_2\text{O(g)} \] **Calculated Thermochemical Values for the Reaction:** - \(ΔH^\circ = -165.92 \text{ kJ/mol}\) - \(ΔS^\circ = 1.18 \text{ J/mol}\) - \(ΔG^\circ = -166.23 \text{ kJ/mol}\) **Discussion Questions:** 1. **Is the reaction exothermic or endothermic? Explain your answer.** 2. **Is the reaction endergonic or exergonic? Explain your answer.** 3. **Is the reaction spontaneous in the forward direction? Explain your answer.** 4. **Draw Lewis structures for the system under study in this experiment.** 5. **Is the reaction in question 8 isodesmic? Explain how you know.** **Graphical Explanation:** No graphs
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