4NH3(g) + O2(g) → 2N2(g) + 6H2O(g)          ΔrH = -1267 kJmol-1  2NO(g) + O­2(g) → 2NO2(g)     ΔrH = -114 kJmol-1  N2(g) + 2O­2(g)  → 2NO2(g)     ΔrH = 66.4 kJmol-1 2CH4(g) → C2H6(g) + H2(g)     ΔrH = 64.6 kJmol-1 2KClO3(s) → 2KCl(s) + 3O2(g)     ΔrH = -77.6 kJmol-1 which of these are spontaneous at all temps

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4NH3(g) + O2(g) → 2N2(g) + 6H2O(g)          ΔrH = -1267 kJmol-1 

2NO(g) + O­2(g) → 2NO2(g)     ΔrH = -114 kJmol-1 
N2(g) + 2O­2(g)  → 2NO2(g)     ΔrH = 66.4 kJmol-1

2CH4(g) → C2H6(g) + H2(g)     ΔrH = 64.6 kJmol-1
2KClO3(s) → 2KCl(s) + 3O2(g)     ΔrH = -77.6 kJmol-1

which of these are spontaneous at all temps 

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