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- 6. Consider the following acid/base reaction. OH a) Show an arrow pushing mechanism. b) Calculate Keq. H CNA -0Explain why ethene does not react with HX ( X=Cl , Br or I) under normal conditions.The key step in a reported laboratory synthesis of sativene, a hydrocarbon isolated from the mold Helminthosporium sativum, involves the following base treatment of a keto tosylate. What kind of reaction is occurring? How would you complete the synthesis?
- Electrostatic potential maps of anisole and thioanisole are shown. Which do you think is the stronger acid, p-methoxybenzoic acid or p-(methylthio)benzoic acid? Explain.a) b) - Fill in the reagents above/below the arrow in the following reactions. c) CN F CO₂H OH ХонDraw the appropriate curved arrows and products for each set of reactants undergoing a coordination step. Identify each reactant species as a nucleophile or electrophile. (a) NH₂ + AICI, →? (b) H₂O + BF₂? (c) ³0° H₂C OH - >?
- N(CH2CH3)3 + HNO3 --------> a.) rewrite the reaction using bond-line structure of reagents and products of the reaction b.) supply the curved arrows explaining the mechanism of the reaction5. What is the major product of the following reaction? OH A) I B) || C) III D) all of the above E) none of the above H₂SO4 heat ||| LOSO3HMechanism. Provide the complete mechanism for the reaction below. You must include appropriate arrows, intermediates, and formal charges. میلیم OH u o OH NH 2. Heat
- In the presence of light or heat, diazomethane (CH,N2) creates a carbene, which then adds to an alkene to make a cyclopropane. In the boxes below. draw the mechanism arrows for the reaction. H INEN: INE N:For the reaction shown below, circle the major product obtained when the | reaction is allowed to reach equilibrium. Place a box around the product that is formed the fastest. а H2C= CI H-CI CIH2C CIH,C H3C CI CI `CH3 H2C CIH,C H;C CIThe following reaction can be carried out in two steps. Choose the correct reagents i) and ii) to perform the following reaction. CN i) 11) or Oi) CN; ii) heat Oi) CN ; ii) H₂O, acid catalyst O i) Br₂; ii) CN- O i) H₂O, acid catalyst; ii) CN O i) HBr; ii) CN
