CML 511 Quantum Chemistry: Tutorial 3, Due date: 6th Sep 2024, 9 am I sem, 2024-25 1. A particle of mass m is confined to a one-dimensional box of length L. Calculate the probability of finding it in the following regions: (a) 0 ≤ x ≤ ½-½ 4, (b) 0 ≤ x ≤ ≤L, (c) L - 8x ≤ x ≤L + 8x. Derive expressions for a general value of n. Then evaluate the probabilities (i) for n = 1, (ii) in the limit n co. Compare the latter to the classical expectations.

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Chapter5: Electron Configurations And The Periodic Table
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CML 511
Quantum Chemistry: Tutorial 3, Due date: 6th Sep 2024, 9 am
I sem, 2024-25
1. A particle of mass m is confined to a one-dimensional box of length L. Calculate the probability of
finding it in the following regions: (a) 0 ≤ x ≤ ½-½ 4, (b) 0 ≤ x ≤ ≤L, (c) L - 8x ≤ x ≤L + 8x.
Derive expressions for a general value of n. Then evaluate the probabilities (i) for n = 1, (ii) in the
limit n co. Compare the latter to the classical expectations.
Transcribed Image Text:CML 511 Quantum Chemistry: Tutorial 3, Due date: 6th Sep 2024, 9 am I sem, 2024-25 1. A particle of mass m is confined to a one-dimensional box of length L. Calculate the probability of finding it in the following regions: (a) 0 ≤ x ≤ ½-½ 4, (b) 0 ≤ x ≤ ≤L, (c) L - 8x ≤ x ≤L + 8x. Derive expressions for a general value of n. Then evaluate the probabilities (i) for n = 1, (ii) in the limit n co. Compare the latter to the classical expectations.
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