CML 511 Quantum Chemistry: Tutorial 3, Due date: 6th Sep 2024, 9 am I sem, 2024-25 1. A particle of mass m is confined to a one-dimensional box of length L. Calculate the probability of finding it in the following regions: (a) 0 ≤ x ≤ ½-½ 4, (b) 0 ≤ x ≤ ≤L, (c) L - 8x ≤ x ≤L + 8x. Derive expressions for a general value of n. Then evaluate the probabilities (i) for n = 1, (ii) in the limit n co. Compare the latter to the classical expectations.

Principles of Modern Chemistry
8th Edition
ISBN:9781305079113
Author:David W. Oxtoby, H. Pat Gillis, Laurie J. Butler
Publisher:David W. Oxtoby, H. Pat Gillis, Laurie J. Butler
Chapter4: Introduction To Quantum Mechanics
Section: Chapter Questions
Problem 17P: In a FranckHertz experiment on sodium atoms, the first excitation threshold occurs at 2.103 eV....
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CML 511
Quantum Chemistry: Tutorial 3, Due date: 6th Sep 2024, 9 am
I sem, 2024-25
1. A particle of mass m is confined to a one-dimensional box of length L. Calculate the probability of
finding it in the following regions: (a) 0 ≤ x ≤ ½-½ 4, (b) 0 ≤ x ≤ ≤L, (c) L - 8x ≤ x ≤L + 8x.
Derive expressions for a general value of n. Then evaluate the probabilities (i) for n = 1, (ii) in the
limit n co. Compare the latter to the classical expectations.
Transcribed Image Text:CML 511 Quantum Chemistry: Tutorial 3, Due date: 6th Sep 2024, 9 am I sem, 2024-25 1. A particle of mass m is confined to a one-dimensional box of length L. Calculate the probability of finding it in the following regions: (a) 0 ≤ x ≤ ½-½ 4, (b) 0 ≤ x ≤ ≤L, (c) L - 8x ≤ x ≤L + 8x. Derive expressions for a general value of n. Then evaluate the probabilities (i) for n = 1, (ii) in the limit n co. Compare the latter to the classical expectations.
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