1. In a driven reaction of elemental zinc and hydrochloric acid, 10.0 grams of zinc, 10.0 mL of 0.50 M hydrochloric acid and 25.0 grams of zinc chloride are placed into a 100-mL flask and the flask is sealed. Identify what will happen in the flask and the quantities of elements and compounds in the flask when the reaction has reached a theoretical 100% yield.

A common demonstration in chemistry courses involves adding a tiny speck of manganese(IV) oxide to a concentrated hydrogen peroxide (H2O2) solution. Hydrogen peroxide decomposes quite spectacularly under these conditions to produce oxygen gas and steam (water vapor). Manganese(IV) oxide is a catalyst for the decomposition of hydrogen peroxide and is not consumed in the reaction. Write the balanced equation for the decomposition reaction of hydrogen peroxide.

(a) Butane gas, C4H10, can burn completely in air [use O2(g) as the other reactant] to give carbon dioxide gas and water vapor. Write a balanced equation for this combustion reaction. (b) Write a balanced chemical equation for the complete combustion of C3H7BO3, a gasoline additive. The products of combustion are CO2(g), H2O(g), and B2O3(s).

Ethanol, C2H5OH, is a gasoline additive that can be produced by fermentation of glucose. C6H12O62C2H5OH+2CO2 (a) Calculate the mass (g) of ethanol produced by the fermentation of 1.000 lb glucose. (b) Gasohol is a mixture of 10.00 mL ethanol per 90.00 mL gasoline. Calculate the mass (in g) of glucose required to produce the ethanol in 1.00 gal gasohol. Density of ethanol = 0.785 g/mL. (c) By 2022, the U. S. Energy Independence and Security Act calls for annual production of 3.6 1010 gal of ethanol, no more than 40% of it produced by fermentation of corn. Fermentation of 1 ton (2.2 103 lb) of corn yields approximately 106 gal of ethanol. The average corn yield in the United States is about 2.1 105 lb per 1.0 105 m2. Calculate the acreage (in m2) required to raise corn solely for ethanol production in 2022 in the United States.

The reaction of equal molar amounts of benzene, C6H6, and chlorine, Cl2, carried out under special conditions completely consumes the reactants and yields a gas and a clear liquid. Analysis of the liquid shows that it contains 64.03% carbon, 4.48% hydrogen, and 31.49% chlorine, and has a molar mass of 112.5 g/mol. Write the balanced equation for this reaction.

The carbon dioxide exhaled in the breath of astronauts is often removed from the spacecraft by reaction with lithium hydroxide 2LiOH(s)+CO2(g)Li2CO3(s)+H2O(l) Estimate the grams of lithium hydroxide required per astronaut per day. Assume that each astronaut requires 2.50 103 kcal of energy per day. Further assume that this energy can be equated to the heat of combustion of a quantity of glucose, C6H12O6, to CO2(g) and H2O(l). From the amount of glucose required to give 2.50 103 kcal of heat, calculate the amount of CO2 produced and hence the amount of LiOH required. The H for glucose(s) is 1273 kJ/mol.

Determine the volume of sulfuric acid solution needed to prepare 37.4 g of aluminum sulfate, Al2(SO4)3, by the reaction 2Al(s)+3H2SO4(aq)Al2(SO4)3(aq)+3H2(g) The sulfuric acid solution, whose density is 1.104 g/mL, contains 15.0% H2SO4 by mass.

Polychlorinated biphenyls (PCBs) have been used extensively as dielectric materials in electrical transformers. Because PCBs have been shown to be potentially harmful, analysis for their presence in the environment has become very important. PCBs are manufactured according to the following generic reaction: C12H10+nCl2C12H10nCln.+nHCl This reaction results in a mixture of PCB products. The mixture is analyzed by decomposing the PCBs and then precipitating the resulting Cl asAgCl. a. Develop a general equation that relates the average value of n to the mass of a given mixture of PCBs and the mass of AgCl produced. b. A 0.1947-g sample of a commercial PCB yielded 0.4791 g of AgCl. What is the average value of n for this sample?

Acetone, (CH3)2CO, is an important industrial compound. Although its toxicity is relatively low, workers using it must be careful to avoid flames and sparks because this compound burns readily in air. Write the balanced equation for the combustion of acetone.

Calcium carbonate forms carbon dioxide and calcium oxide when it is heated above 900 °C in a limekiln. When heated to 1000 °C in a laboratory, 4.31 g calcium carbonate produces 2.40 g calcium oxide and 1.90 g carbon dioxide. Outline a method similar to combustion analysis by which you could determine the empirical formula for calcium carbonate from these data. Carry out the determination.