The following initial rate data are for the oxidation of arsenate ion by cerium(IV) ion in aqueous solution: AsO3 + 2Ce++ H2O → AsO43+ 2Ce3++ 2H+ Experiment [AsO] [C] Initial Rate, M-8-1 M M 1 0.0254 0.325 0.00133 2 0.0508 0.325 0.00267 3 0.0254 0.650 0.00533 4 0.0508 0.650 0.0107 Complete the rate law for this reaction in the box below. Use the form k[A] [B]", where '1' is understood for mor n and concentrations taken to the zero power do not appear. Don't enter 1 for m or n. Rate= k M-2.8-1

Chemistry for Engineering Students
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Author:Lawrence S. Brown, Tom Holme
Publisher:Lawrence S. Brown, Tom Holme
Chapter11: Chemical Kinetics
Section: Chapter Questions
Problem 11.32PAE: 11.32 The following experimental data were obtained for the reaction 2A + 3 B—C + 2D [A](mol L 1)...
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The following initial rate data are for the oxidation of arsenate ion by cerium(IV) ion in aqueous solution:
AsO3 + 2Ce++ H2O → AsO43+ 2Ce3++ 2H+
Experiment
[AsO] [C]
Initial Rate,
M-8-1
M
M
1
0.0254
0.325
0.00133
2
0.0508
0.325
0.00267
3
0.0254
0.650
0.00533
4
0.0508
0.650
0.0107
Complete the rate law for this reaction in the box below.
Use the form k[A] [B]", where '1' is understood for mor n and concentrations taken to the zero power do not appear. Don't enter 1
for m or n.
Rate=
k
M-2.8-1
Transcribed Image Text:The following initial rate data are for the oxidation of arsenate ion by cerium(IV) ion in aqueous solution: AsO3 + 2Ce++ H2O → AsO43+ 2Ce3++ 2H+ Experiment [AsO] [C] Initial Rate, M-8-1 M M 1 0.0254 0.325 0.00133 2 0.0508 0.325 0.00267 3 0.0254 0.650 0.00533 4 0.0508 0.650 0.0107 Complete the rate law for this reaction in the box below. Use the form k[A] [B]", where '1' is understood for mor n and concentrations taken to the zero power do not appear. Don't enter 1 for m or n. Rate= k M-2.8-1
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