1 Figure 14.23 Heterogeneous Hydrogen catalysis. Mechanism for reaction of ethylene with hydrogen on a catalytic surface. Carbon H2 and C2H4 adsorb on metal surface. After H-H bond breaks, H atoms migrate along metal surface. One free H attaches to C2H4 to form C2H5 (ethyl group) intermediate. Second free H is about to attach to C2H5 intermediate to form C2Hg. Ethane, C2H6, desorbs from metal surface.

Chemistry
10th Edition
ISBN:9781305957404
Author:Steven S. Zumdahl, Susan A. Zumdahl, Donald J. DeCoste
Publisher:Steven S. Zumdahl, Susan A. Zumdahl, Donald J. DeCoste
Chapter1: Chemical Foundations
Section: Chapter Questions
Problem 1RQ: Define and explain the differences between the following terms. a. law and theory b. theory and...
icon
Related questions
Question

The first step in the heterogeneous
hydrogenation of ethylene is adsorption of the
ethylene molecule on a metal surface. One proposed explanation for the “sticking” of ethylene to a metal
surface is the interaction of the electrons in the C—C π
bond with vacant orbitals on the metal surface. (a) If this
notion is correct, would ethane be expected to adsorb to a metal surface, and, if so, how strongly would ethane bind
compared to ethylene? (b) Based on its Lewis structure,
would you expect ammonia to adsorb to a metal surface
using a similar explanation as for ethylene?

1 Figure 14.23 Heterogeneous
Hydrogen
catalysis. Mechanism for reaction
of ethylene with hydrogen on a
catalytic surface.
Carbon
H2 and C2H4 adsorb on
metal surface.
After H-H bond breaks, H atoms
migrate along metal surface.
One free H attaches to
C2H4 to form C2H5 (ethyl
group) intermediate.
Second free H is about to attach to
C2H5 intermediate to form C2Hg.
Ethane, C2H6, desorbs from
metal surface.
Transcribed Image Text:1 Figure 14.23 Heterogeneous Hydrogen catalysis. Mechanism for reaction of ethylene with hydrogen on a catalytic surface. Carbon H2 and C2H4 adsorb on metal surface. After H-H bond breaks, H atoms migrate along metal surface. One free H attaches to C2H4 to form C2H5 (ethyl group) intermediate. Second free H is about to attach to C2H5 intermediate to form C2Hg. Ethane, C2H6, desorbs from metal surface.
Expert Solution
trending now

Trending now

This is a popular solution!

steps

Step by step

Solved in 3 steps

Blurred answer
Knowledge Booster
Kinetics of Reactions in Solution
Learn more about
Need a deep-dive on the concept behind this application? Look no further. Learn more about this topic, chemistry and related others by exploring similar questions and additional content below.
Similar questions
  • SEE MORE QUESTIONS
Recommended textbooks for you
Chemistry
Chemistry
Chemistry
ISBN:
9781305957404
Author:
Steven S. Zumdahl, Susan A. Zumdahl, Donald J. DeCoste
Publisher:
Cengage Learning
Chemistry
Chemistry
Chemistry
ISBN:
9781259911156
Author:
Raymond Chang Dr., Jason Overby Professor
Publisher:
McGraw-Hill Education
Principles of Instrumental Analysis
Principles of Instrumental Analysis
Chemistry
ISBN:
9781305577213
Author:
Douglas A. Skoog, F. James Holler, Stanley R. Crouch
Publisher:
Cengage Learning
Organic Chemistry
Organic Chemistry
Chemistry
ISBN:
9780078021558
Author:
Janice Gorzynski Smith Dr.
Publisher:
McGraw-Hill Education
Chemistry: Principles and Reactions
Chemistry: Principles and Reactions
Chemistry
ISBN:
9781305079373
Author:
William L. Masterton, Cecile N. Hurley
Publisher:
Cengage Learning
Elementary Principles of Chemical Processes, Bind…
Elementary Principles of Chemical Processes, Bind…
Chemistry
ISBN:
9781118431221
Author:
Richard M. Felder, Ronald W. Rousseau, Lisa G. Bullard
Publisher:
WILEY