000 LL Br >> A C D E Please predict the products for each of the following reactions below (reaction 1): Hint: one of the reactions is the Baeyer-Villiger Reaction Hint: in case of 3, 4, 5, 6, 7 and 8 please consider ONLY the kinetic enolate MCPBA 1. NaOH, Br₂ 2. H3O+ 3. Br2, PBг3 4. H₂O 1. LDA, THF 2. Mel 3. LDA, THF 4. Mel (mixture of two compounds) D 1. NaOH 2. H Br2 H3O+ 2. H3O+ 1. NaOH, Br₂ 10 2 1. LDA, THF 9 3 2. Mel 8 5 2. 1. LDA, THF B 1. LDA, THF 2. Br 1. LDA, THF 2. Br Br Br (Only) E Br Br Br (Only) Br (Only) COOEt (mixture of two compounds) F Br Br Br (mixture of two compounds)

Organic Chemistry
9th Edition
ISBN:9781305080485
Author:John E. McMurry
Publisher:John E. McMurry
Chapter30: Orbitals And Organic Chemistry: Pericyclic Reactions
Section30.SE: Something Extra
Problem 41AP: In light of your answer to Problem 30-40, explain why a mixture of products occurs in the following...
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000
LL
Br
>>
A
C
D
E
Please predict the products for each of the following reactions below (reaction 1):
Hint: one of the reactions is the Baeyer-Villiger Reaction
Hint: in case of 3, 4, 5, 6, 7 and 8 please consider ONLY the kinetic enolate
MCPBA
1. NaOH, Br₂
2. H3O+
3. Br2, PBг3
4. H₂O
1. LDA, THF
2. Mel
3. LDA, THF
4. Mel
(mixture of two compounds)
D
1. NaOH
2.
H
Br2
H3O+
2. H3O+
1. NaOH, Br₂
10
2
1. LDA, THF
9
3
2. Mel
8
5
2.
1. LDA, THF
B
1. LDA, THF
2.
Br
1. LDA, THF
2.
Br
Br
Br
(Only)
E
Br
Br
Br
(Only)
Br
(Only)
COOEt
(mixture of two compounds)
F
Br
Br
Br
(mixture of two compounds)
Transcribed Image Text:000 LL Br >> A C D E Please predict the products for each of the following reactions below (reaction 1): Hint: one of the reactions is the Baeyer-Villiger Reaction Hint: in case of 3, 4, 5, 6, 7 and 8 please consider ONLY the kinetic enolate MCPBA 1. NaOH, Br₂ 2. H3O+ 3. Br2, PBг3 4. H₂O 1. LDA, THF 2. Mel 3. LDA, THF 4. Mel (mixture of two compounds) D 1. NaOH 2. H Br2 H3O+ 2. H3O+ 1. NaOH, Br₂ 10 2 1. LDA, THF 9 3 2. Mel 8 5 2. 1. LDA, THF B 1. LDA, THF 2. Br 1. LDA, THF 2. Br Br Br (Only) E Br Br Br (Only) Br (Only) COOEt (mixture of two compounds) F Br Br Br (mixture of two compounds)
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