000 LL Br >> A C D E Please predict the products for each of the following reactions below (reaction 1): Hint: one of the reactions is the Baeyer-Villiger Reaction Hint: in case of 3, 4, 5, 6, 7 and 8 please consider ONLY the kinetic enolate MCPBA 1. NaOH, Br₂ 2. H3O+ 3. Br2, PBг3 4. H₂O 1. LDA, THF 2. Mel 3. LDA, THF 4. Mel (mixture of two compounds) D 1. NaOH 2. H Br2 H3O+ 2. H3O+ 1. NaOH, Br₂ 10 2 1. LDA, THF 9 3 2. Mel 8 5 2. 1. LDA, THF B 1. LDA, THF 2. Br 1. LDA, THF 2. Br Br Br (Only) E Br Br Br (Only) Br (Only) COOEt (mixture of two compounds) F Br Br Br (mixture of two compounds)

000 LL Br >> A C D E Please predict the products for each of the following reactions below (reaction 1): Hint: one of the reactions is the Baeyer-Villiger Reaction Hint: in case of 3, 4, 5, 6, 7 and 8 please consider ONLY the kinetic enolate MCPBA 1. NaOH, Br₂ 2. H3O+ 3. Br2, PBг3 4. H₂O 1. LDA, THF 2. Mel 3. LDA, THF 4. Mel (mixture of two compounds) D 1. NaOH 2. H Br2 H3O+ 2. H3O+ 1. NaOH, Br₂ 10 2 1. LDA, THF 9 3 2. Mel 8 5 2. 1. LDA, THF B 1. LDA, THF 2. Br 1. LDA, THF 2. Br Br Br (Only) E Br Br Br (Only) Br (Only) COOEt (mixture of two compounds) F Br Br Br (mixture of two compounds)

Organic Chemistry

9th Edition

ISBN:9781305080485

Author:John E. McMurry

Publisher:John E. McMurry

Chapter30: Orbitals And Organic Chemistry: Pericyclic Reactions

Section30.SE: Something Extra

Problem 41AP: In light of your answer to Problem 30-40, explain why a mixture of products occurs in the following...

See similar textbooks

Similar questions

Determine the Ksp of the following reactions. а. NaC:H:0z Na' + CH:O2 b. HBr H* + Br c. Zn(OH)2 Zn + 2HO- d. PbCl: Pb* + 2Cl- + 2dl- -2 + SO. +2 e. SnSO. Sn
Below is the elimination reaction of 4-fluoro-4-(4-nitrophenyl)butan-2-one forming 4-(4- nitrophenyl)but-3-en-2-one. base F- O2N O,N Two sets of experiments were carried out with different reactants as shown below. The k /kp values are also given below. (L is either Hydrogen, H OR Deuterium, D) Set 1 O,N kH/kp = 3.7 Set 2 O,N kH/kp = 1.5 a) Even though Sets 1 and 2 show two different kinetic isotope effect values, both reactions took place via the SAME mechanism. Propose ONE mechanism that would explain both observations in Sets 1 and 2. Explain your answer. b) Suggest another modification on the experiment to further support your above proposal
Write the major products A-E for each of the following reactions. ÇH, K,Cr,0, H. (dehydration H,C. в product) Нeat K2Cr,0, H,C. HCI CH,CH=ĊCH, CH, FeCl, ČH,
Write what the products A, B, C, D, E, F, G, H, I, J and K are in the reactions below.
Which of the following represent the reagents in the correct order for the synthesis of the target molecule? 1. CH3CI, ALC!3; 2. H2/Pd; 3. NBS, light А 1. CH;COCI, ALC!3; 2. Zn(Hg), HCl; 3. NBS, light В 1. CH3COCI, AlCl3; 2. Br2, FeBr C 3; 3. H2/Pd 1. CH3CH2CI, AlCl;; 2. Br2, FeBr3; 3. NBS, light Br 1) 2) 3)
Which set of reagents is appropriate for the second step of the reaction? OMe heat OMe ОН + MeO MeO А. 1. NaBH4/MeОH; 2. Н+ 1. NaBH4/THF; 2. NaOH/H20 С. В. 1. LİAIH4/Et2O; 2. H+ D. 1. LIAIH4/Et20;B 2. NaOНІН20
Determine the Ksp of the following reactions. NaC2H302 2 Na* + C2H3O2 b. HBr 2 H* + Br c. Zn(OH)2 Zn+2 + 2HO- 946
Which sequence of reactions are expected to give the best yield of 3-nitrobenzoic acid? (A) (B) (C) (D) NO₂ OH 1. CH3C1, AlCl3 2. KMnO4, H+ 1.KMnO4, H+ 2.HNO3, H₂SO4 1. HNO3, H₂SO4 2. KMnO4, H+ 1. KMnO4, H+ 2. NaNO₂, H+
What is the purpose of HCl in the iodination of vanillin. And what is the complete mechanism for this reaction, along with how do you synthesize the catalyst and electrophil I-Cl.
Give detailed Solution with explanation needed
Below is the elimination reaction of 4-fluoro-4-(4-nitrophenyl)butan-2-one forming 4-(4- nitrophenyl)but-3-en-2-one. F base F- O2N O,N Two sets of experiments were carried out with different reactants as shown below. The kĦ/kp values are also given below. (L is either Hydrogen, H OR Deuterium, D) Set 1 O,N kh/kp = 3.7 Set 2 O,N" kH/kp = 1.5 Name the kinetic isotope effect for experiments in Set 1 AND Set 2, respectively. Explain your answers. a)
Do both plz dont give incomplete solution DO BOTH MUST