Predict only the FINAL product (or a mixture of products) for the following synthetic transformation: H3CO A NH Br2 AlBr3 O₂N NO2 B D A. H3CO (2 moles) HNO3 H2SO4 NH2 Chemical Formula: C6H3BгN2O4 O₂N. NO2 OCH 3 ? H3CO. H₂N. NH NO2 O₂N NO2 NO2 NO2 B. C. D.
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- Give the major product for the reaction. Pyrrolidine is a secondary amine. CH CH O CH CH! O OH CH2 O CH. I CH.CH Ї TCH CHE OH CH CH₂CH₂ CH.CH CH.OH2 0= RO pyrrolidine. 2 GH CH2 3 HCI H,0 TOH OH: CH₂CH₂ TCH CH: CH₂CH. CH₂CH₂Below is a structure of Levonorgestrel (Plan B®), used in prevention of pregancy. но HH H. Levonorgestrel Plan B® Below is one of the reactions used in the synthesis. What type of reaction is it? он :CEC-H Lc=c-H THF as solvent Levonorgestrel H,CO H,CO O A grignard reaction. Nucleophilic acyl substitution. O Nucleophilic addition. O An SN2 reaction. O OPredict the product of the following acetal hydrolysis reactions.
- What compound is the limiting reagent?H3C OH 1. Br2, PBг3 2. H₂O H3C OH Br The a-bromination of carbonyl compounds by Br₂ in acetic acid is limited to aldehydes and ketones because acids, esters, and amides don't enolize to a sufficient extent. Carboxylic acids, however, can be a-brominated by first converting the carboxylic acid to an acid bromide by treatment with PBr3. Following enolization of the acid bromide, Br2 reacts in an a-substitution reaction. Hydrolysis of the acid bromide completes the reaction. Draw curved arrows to show the movement of electrons in this step of the mechanism. Arrow-pushing Instructions Br Br зь P-Br Br H₂C H₂C SH Br BrWhat is the major organic product of the following reaction? HO CI 1. CH3CH2MgBr برام (2 equiv) 2. H₂O HO CI CICI EU Multiple Choice TV of IV
- Hydrolysis of amides is an important reaction, because it represents the first step in the digestion of dietary protein. Which of the following compounds is formed as a result of the hydrolysis of N,N-diethylpropanamide as shown below? CH3CH2 N-CH2CH3 + H₂O CH2CH3 HCI OA) B) CH3CH2 NH2 HO N-CH2CH3 CH2CH3 H CH3CH2 NHCH2CH3 D)Identify A, B, and C, intermediates in the synthesis of the five-membered ring called an α- methylene-γ-butyrolactone. This heterocyclic ring system is present in some antitumor agents.H₂C ཏཱཏི 1 ནི OH 1. Br2, PBг3 2. H₂O H3C OH Br The a-bromination of carbonyl compounds by Br2 in acetic acid is limited to aldehydes and ketones because acids, esters, and amides don't enolize to a sufficient extent. Carboxylic acids, however, can be a-brominated by first converting the carboxylic acid to an acid bromide by treatment with PBr3. Following enolization of the acid bromide, Br2 reacts in an a-substitution reaction. Hydrolysis of the acid bromide completes the reaction. Draw curved arrows to show the movement of electrons in this step of the mechanism. Arrow-pushing Instructions :0: H3C Br Br + :::OH2 Br H₂O H3C Br за
- For the following reaction schemes, fill in the appropriate reagents and starting materials you would use to transform the acetoacetic ester and acetone into nabumetone, an NSAID drug used for arthritis and joint pain. Write the correct reagents/reactants next to the number of steps for each transformation.An unsaturated ketone is converted to the 3-cyano derivative shown below. Which reagent could be used to accomplish this? CEN O 1. HCN (hydrogen cyanide) O 2. Methylmagnesium bromide followed by ammonia. O 3. Dimethylcopper lithium followed by sodium amide. O 4. Methylamine followed by a dehydrating agent like P205-Rank the reactivity of the compounds below toward nucleophilic acyl substitution by writing the compounds' letters in the proper blanks in the box below. `NH CI Br CH3 CH3 A В C E rank compounds for acyl substitution reactivity most least reactive reactive