Predict only the FINAL product (or a mixture of products) for the following synthetic transformation: H3CO A NH Br2 AlBr3 O₂N NO2 B D A. H3CO (2 moles) HNO3 H2SO4 NH2 Chemical Formula: C6H3BгN2O4 O₂N. NO2 OCH 3 ? H3CO. H₂N. NH NO2 O₂N NO2 NO2 NO2 B. C. D.
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- 3A Complete the reactions below. H₂SO4/H₂O HgSO4 A NaBH4 EtOH B лH₂SO4 CCoumarin, a naturally occurring compound isolated from lavender, sweet clover, and tonka bean, is made in the laboratory from o-hydroxybenzaldehyde by the reaction depicted below. Draw a stepwise mechanism for this reaction. Coumarin derivatives are useful synthetic anticoagulants.Although codeine occurs in low concentration in the opium poppy, most of the codeine used in medicine is prepared from morphine (the principal component of opium) by the following reaction. Explain why selective methylation occurs at only one OH in morphine to give codeine. Codeine is a less potent and less addictive analgesic than morphine. но. CH,0. [1 кон H [2] CH3I H. CH3 H Ho morphine H. CH3 Ho codeine
- Below is a structure of Levonorgestrel (Plan B®), used in prevention of pregancy. но HH H. Levonorgestrel Plan B® Below is one of the reactions used in the synthesis. What type of reaction is it? он :CEC-H Lc=c-H THF as solvent Levonorgestrel H,CO H,CO O A grignard reaction. Nucleophilic acyl substitution. O Nucleophilic addition. O An SN2 reaction. O OWhat compound is the limiting reagent?Among the choices shown, which reagents would lead to 3-pentanone from bromoethane? Al 1 Li Cul 2) C13CH2OTS | BI1 NECNn DMSO 2) CH3CH2M;Br 3)H2O C)CH13CH2-CO CI D CH3CH2-CO OCH2CI13
- For the following reaction schemes, fill in the appropriate reagents and starting materials you would use to transform the acetoacetic ester and acetone into nabumetone, an NSAID drug used for arthritis and joint pain. Write the correct reagents/reactants next to the number of steps for each transformation.An unsaturated ketone is converted to the 3-cyano derivative shown below. Which reagent could be used to accomplish this? CEN O 1. HCN (hydrogen cyanide) O 2. Methylmagnesium bromide followed by ammonia. O 3. Dimethylcopper lithium followed by sodium amide. O 4. Methylamine followed by a dehydrating agent like P205-Rank the reactivity of the compounds below toward nucleophilic acyl substitution by writing the compounds' letters in the proper blanks in the box below. `NH CI Br CH3 CH3 A В C E rank compounds for acyl substitution reactivity most least reactive reactive
- 4. Which of the following reactions can be used to prepare 11-diphenyl-1-propanol? OH I. II. III. CH₂CH₂C снене-ось CH₂CH₂C -OCH3 PO 1. 2. H₂00 1. ? 2. H30Ⓡ MgBr MgBr 1. CH3CH₂ MgBr 2. H30The following diol is prepared from propanal (CH3CH2CHO) and 3-bromopropanol. Which derivatives will be among intermediate products in this transformation? ОН HODraw the products for the following substitution reactions: