Predict only the FINAL product (or a mixture of products) for the following synthetic transformation: H3CO A NH Br2 AlBr3 O₂N NO2 B D A. H3CO (2 moles) HNO3 H2SO4 NH2 Chemical Formula: C6H3BгN2O4 O₂N. NO2 OCH 3 ? H3CO. H₂N. NH NO2 O₂N NO2 NO2 NO2 B. C. D.
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- Which of the following structures and IUPAC names are incorrectly matched? * oe (A) Methyleyclohexanoate (В) `NH2 Br 4-Bromo-3-chlorohexanamide 2-Ethoxypentane (D) HOOC HOOC 3,5-Nonanedioic acid В A DWhat compound is the limiting reagent?For the following reaction schemes, fill in the appropriate reagents and starting materials you would use to transform the acetoacetic ester and acetone into nabumetone, an NSAID drug used for arthritis and joint pain. Write the correct reagents/reactants next to the number of steps for each transformation.
- An unsaturated ketone is converted to the 3-cyano derivative shown below. Which reagent could be used to accomplish this? CEN O 1. HCN (hydrogen cyanide) O 2. Methylmagnesium bromide followed by ammonia. O 3. Dimethylcopper lithium followed by sodium amide. O 4. Methylamine followed by a dehydrating agent like P205-The following diol is prepared from propanal (CH3CH2CHO) and 3-bromopropanol. Which derivatives will be among intermediate products in this transformation? ОН HOProvide reagents/conditions to accomplish the following syntheses. Several steps are required in some cases. H2N NH2 Но TH. NH2 HO
- The compound shown below is the cyclic hemiacetal of НаС ОН O. CH2CH3 O 6-hydroxyheptanal. 5-hydroxyheptanal. 5-hydroxy-2-heptanone 6-hydroxy-3-heptanone.Give the major organic product(s) for each step of the following reactions: H2 NaCN В HCI/H20 SOCI2 ►E HBr A a) Lindlar 1. NaOH, д -D 2. H* CH3CH2OH 1, 2 eq CH3CH2M9B A- В H30* 2. Hзо* LDA - C b) 1. ВНз/THF HBr 1. C 2. H30* A Mg В Et,0 D 2. H2O2, OH", H20 c)Explain this difference in potency and speed of onset by pointing out the main differences in functional groups between morphine and heroin.
- 3 Treatment of 1-aminoadamantane, C„H„N, with methyl 2,4-dibromobutanoate in the presence of a nonnucleophilic base, R,N, involves two successive S,2 reactions and gives compound A. Propose a structural formula for compound A. R&N NH, + Br. C15H93NO, + 2 R,NH Br OCH Br 1-Aminoadamantane Methyl 2,4-dibromobutanoate A5. Although codeine occurs in low concentration in the opium poppy, most of the codeine used in medicine is prepared from morphine (the principal component of opium) by the following reaction. Explain why selective methylation occurs at only one OH in morphine to give codeine. Codeine is a less potent and less addictive analgesic than morphine. HO, H3CO. 1) KOH 2) CH;I N. но HO Morphine CodeineThis question is about the reaction scheme shown. CH₂ CH₂ step 2 step 1 NO₂ NH₂ NHCOCK, Amine A CH₂CI step 4 step 5 Amine B State the reagents needed for step 1 and the reagents needed for step 2. step 1 step 2 Give the name of the mechanism for the reaction in step 3. CH₂ CHÍNH, step 3