. (8 pts.) Consider the stereochemical changes that accompany the dissociation mechanisms for ligand substitution reactions involving complexes of the form A-cis-[M(LL)2BX]. The three possible 5-coordinate intermediate ligand arrangements are shown. Draw all reaction pathways that lead to A product isomers. X B -B B - X -X B + Y - X B до + Y + Y ? ?

Organic Chemistry
8th Edition
ISBN:9781305580350
Author:William H. Brown, Brent L. Iverson, Eric Anslyn, Christopher S. Foote
Publisher:William H. Brown, Brent L. Iverson, Eric Anslyn, Christopher S. Foote
Chapter24: Catalytic Carbon-carbon Bond Formation
Section: Chapter Questions
Problem 24.22P
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. (8 pts.) Consider the stereochemical changes that accompany the dissociation mechanisms
for ligand substitution reactions involving complexes of the form A-cis-[M(LL)2BX]. The
three possible 5-coordinate intermediate ligand arrangements are shown. Draw all reaction
pathways that lead to A product isomers.
X
B
-B
B
- X
-X
B
+ Y
- X
B
до
+ Y
+ Y
?
?
Transcribed Image Text:. (8 pts.) Consider the stereochemical changes that accompany the dissociation mechanisms for ligand substitution reactions involving complexes of the form A-cis-[M(LL)2BX]. The three possible 5-coordinate intermediate ligand arrangements are shown. Draw all reaction pathways that lead to A product isomers. X B -B B - X -X B + Y - X B до + Y + Y ? ?
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