a. (i) Starting from K2₂[PtC14], plan synthetic routes to the two complexes A and B shown below, using your knowledge of the trans effect. Formulate each step by drawing structures of each complex and give a full explanation for your choices. Make sure to assign the correct charges to each complex in each case. 7- 7. (ii) NH₂ NCS- -Pt-Br NO₂ CI-Pt-OH CO Write a detailed discussion of the two factors that may contribute to the overall trans-directing ability of a particular ligand, considering thermodynamic and kinetic aspects. Use appropriate examples and orbital sketches to support your
Catalysis and Enzymatic Reactions
Catalysis is the kind of chemical reaction in which the rate (speed) of a reaction is enhanced by the catalyst which is not consumed during the process of reaction and afterward it is removed when the catalyst is not used to make up the impurity in the product. The enzymatic reaction is the reaction that is catalyzed via enzymes.
Lock And Key Model
The lock-and-key model is used to describe the catalytic enzyme activity, based on the interaction between enzyme and substrate. This model considers the lock as an enzyme and the key as a substrate to explain this model. The concept of how a unique distinct key only can have the access to open a particular lock resembles how the specific substrate can only fit into the particular active site of the enzyme. This is significant in understanding the intermolecular interaction between proteins and plays a vital role in drug interaction.
![3. a. (i) Starting from K₂[PtC14], plan synthetic routes to the two complexes A and B shown
below, using your knowledge of the trans effect. Formulate each step by drawing
structures of each complex and give a full explanation for your choices. Make sure
to assign the correct charges to each complex in each case.
7-
7-
(ii)
NCS
NH₂
-Pt-Br
CI
NO₂
CI-Pt-OH
CO
B
Write a detailed discussion of the two factors that may contribute to the overall
trans-directing ability of a particular ligand, considering thermodynamic and
kinetic aspects. Use appropriate examples and orbital sketches to support your
explanations.](/v2/_next/image?url=https%3A%2F%2Fcontent.bartleby.com%2Fqna-images%2Fquestion%2F61251c21-e5d4-42cb-9cd3-270ad8bec85a%2Fe9d829c9-b2cf-4555-8a4f-a270ac3dae7c%2Foalcdsk_processed.jpeg&w=3840&q=75)
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