The chiral Mn complex below undergoes racemization according to the equation shown. 7-8 Mn + PhMe/25 °C ´PPH3 PPH3 Ph3P" NO NO NO Ph ti/2 = 21 min. Rate x 1/[PPH3] Ph Ph Propose a mechanism that is consistent with the rate being affected inversely by the concentration of PPH3.
The chiral Mn complex below undergoes racemization according to the equation shown. 7-8 Mn + PhMe/25 °C ´PPH3 PPH3 Ph3P" NO NO NO Ph ti/2 = 21 min. Rate x 1/[PPH3] Ph Ph Propose a mechanism that is consistent with the rate being affected inversely by the concentration of PPH3.
Chemistry
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ISBN:9781305957404
Author:Steven S. Zumdahl, Susan A. Zumdahl, Donald J. DeCoste
Publisher:Steven S. Zumdahl, Susan A. Zumdahl, Donald J. DeCoste
Chapter1: Chemical Foundations
Section: Chapter Questions
Problem 1RQ: Define and explain the differences between the following terms. a. law and theory b. theory and...
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![7-8
The chiral Mn complex below undergoes racemization according to the
equation shown.
Mn,
PhMe/25 °C
´PPH3
´PPH3
Ph3P"
Ph
NO
ti/2 = 21 min.
Ph
NO
NO Ph
Rate x
1/[PPh3]
Propose a mechanism that is consistent with the rate being affected
inversely by the concentration of PPh;.](/v2/_next/image?url=https%3A%2F%2Fcontent.bartleby.com%2Fqna-images%2Fquestion%2F40713c2a-7db1-425d-933e-3ce74c306410%2F0a4a270e-dfc2-428c-be06-36fbefb6236b%2Fyi5wlmp_processed.png&w=3840&q=75)
Transcribed Image Text:7-8
The chiral Mn complex below undergoes racemization according to the
equation shown.
Mn,
PhMe/25 °C
´PPH3
´PPH3
Ph3P"
Ph
NO
ti/2 = 21 min.
Ph
NO
NO Ph
Rate x
1/[PPh3]
Propose a mechanism that is consistent with the rate being affected
inversely by the concentration of PPh;.
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