Chemistry
10th Edition
ISBN:9781305957404
Author:Steven S. Zumdahl, Susan A. Zumdahl, Donald J. DeCoste
Publisher:Steven S. Zumdahl, Susan A. Zumdahl, Donald J. DeCoste
Chapter1: Chemical Foundations
Section: Chapter Questions
Problem 1RQ: Define and explain the differences between the following terms. a. law and theory b. theory and...
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Transcribed Image Text:4. Provide a detailed, stepwise mechanism for the following reaction.
Ph Ph
Ph-P
Pdº +
Ph-P
Ph Ph
A
5. Show the intermediates for the following steps of the catalytic cycle for the Suzuki cross-coupling
reaction.
Br
+
oxidative
addition
Br
NO₂
B
HO OH
NO₂
+ OCH₂
transmetallation
SNa
OCH,
NO₂
NO₂
NaOH (aq)
ligand
exchange
F
B(OH)3 is a byproduct of this step
Ph Phi
Ph-P
Pd"
Ph-POH
Ph Ph
reductive
elimination
6. Provide a detailed, stepwise mechanism for the following reaction. What is the correct designation fo
this type of substitution reaction?
S.
A
Designation
CH3
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