exam 2 F2023 (1)

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Dec 6, 2023

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Name: Anthony Moore CHM 111 Exam 2 SHOW ALL WORK FOR FULL CREDIT Express your answers using the proper number of significant figures c= 3.00x10 8 m/s h=6.626x10 -34 Js 1Hz=s -1 1J = 1 kg m 2 /s 2 1 nm = 1x10 -9 m 1. (6 points) Calculate the moles in 500 mL of a 2.5M HNO 3 solution. N = (0.500)(2.5) = 1.25 mol 2. (6 points) If 275 ml of 2.9 M HNO 3 must be used to make 3.0 L of solution, what is the final concentration of this solution? 2.9 0.275 3 = 0.265 ??? 3. ( 6 points ) A student needs to prepare 1.5 L of a 0.45 M solution of aqueous MgSO 4 . How many grams of MgSO 4 do they need to dissolve in 1.5 L of water in order to prepare the solution? 1.5 ? 1 ? 0.45 ? = 0.675 ??? 0.675 ???⋅ 120.366 ? = 81.247 ??? ???? 4 4. ( 20 points ) Write balanced net ionic equations for the reactions that occur in each of the following cases. Identify the spectator ion or ions in each reaction . 1
Name: Anthony Moore CHM 111 Exam 2 (a) ___3__AgNO 3 (aq) + ___3__Na 3 PO 4 (aq) à + ¿ ( ?? ) ?? 4 3 ( ?? ) + 3 ?? ¿ Spectator Ions: + ¿ , ? ? 3 ? ? ¿ (b) ___2___NH4Cl(aq) + Mg(CH3COO)2(aq) à MgCl 2 (aq) + NH 4 (CH 3 COO) 2 (aq) à 2 + ¿ ( ?? ) + 2 ?? ( ?? ) = ???? 2 ( ? ) ? ? ¿ Spectator Ions: ________ + ¿ , ? ? 3 ?? ? ? 4 ¿ _____ (c) K 2 SO 4 (aq) + BaCl 2 (aq) à 2 ??? + ???? 4 2 + ¿ ( ?? ) + ?? 4 2 ( ?? ) = ??? ? 4 ( ? ) ? ? ¿ Spectator Ions: + ¿ , ?? 2 ? 2 ¿ (d) _____H 3 PO 3 (aq) + ___2__KOH(aq) à 2 H 2 O ( l )+ K 2 HPO 3 ( aq ) ? 3 ? ? 3 ( ?? ) + 2 ? ? ( ?? ) = 2 ? 2 ? ( ? ) + ?? ? 3 2 Spectator Ions: _____ + ¿ ? ¿ _____ 2
Name: Anthony Moore CHM 111 Exam 2 5. (20 points) Using the activity series (Table 4.5), write balanced NET IONIC chemical equations for the following reactions. If no reaction occurs, write “no reaction” (a) Solid lithium is added to a solution of chromium(III) nitrate 2 ?? ( ? ) + ?? ( ? ? 3 ) 2 = ?? + 2 ??? ? 3 (b) Solid lead is added to chromium(III) nitrate ?? ( ? ) + ?? ( ? ? 3 ) 3 = ?????????? (c) Hydrochloric acid is added to manganese metal ?? ( ? ) + 2 ??? ( ?? ) = ???? 2 ( ?? ) + ? 2 ( ? ) (d) Hydrocbromic acid is added to solid calcium 2 + ¿ ( ?? ) + ?? 2 ( ? ) + ¿ ( ?? ) + ???? 3 ( ? ) = ? 2 ? ( ? ) + ? ? ¿ 2 ? ¿ (e) Solid iron is added to zinc chloride ?? ( ? ) + ??? ? 2 = ???? 2 + ?? ( ? ) 3
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Name: Anthony Moore CHM 111 Exam 2 6. ( 10 points ) Given the data in the table below, determine ΔH° rxn for the reaction 4NO (g) + 6 H 2 O (l) à 4NH 3 (g) + 5 O 2 (g) [ 4 ( 46 ) + 5 ( 0 ) ] [ 4 ( 90 ) + 6 ( 286 ) ] = 1172 ?? ??? 7. ( 12 points ) Consider the following reaction: 4Al(s) + 3O 2 (g) à 2Al 2 O 3 (s) H = -1669.8 kJ a. Calculate the amount of heat transferred when 5.5 g of Al(s) is consumed during this reaction. 5.5 ? ?? ( ? ) ( 1 ??? 26.98 ? )( 1669.8 ?? 4 ??? ) = 85.10 ?? b. How many grams of Al 2 O 3 will form when -2709.4 kJ of heat is released? 2709.4 ?? ( 2 ??? 1669.8 ?? )( 101.96 ? 1 ??? ) = 661.75 ??? ?? 2 ? 3 4
Name: Anthony Moore CHM 111 Exam 2 8. ( 12 points) Use the following thermochemical equations (and Hess’s Law) to calculate ΔH° rxn for B 2 H 6 (g) à 2B(s) + 3H 2 (g) using the following thermochemical information 4B(s) + 3O 2 (g) à 2 B 2 O 3 (s) H o = -2509.1 kJ 2H 2 (g) + O 2 (g) à 2H 2 O(l) H o = -571.7 kJ B 2 H 6 (g) + 3 O 2 (g) à B 2 O 3 (s) + 3H 2 O(l) H o = -2147.5 kJ 4B(s) + 3O 2 (g) à 2 B 2 O 3 (s) H o = -2509.1 kJ 2H 2 (g) + O 2 (g) à 2H 2 O(l) H o = -571.7 kJ B 2 O 3 (s) + 3H 2 O(l) à B 2 H 6 (g) + 3 O 2 (g) H o = +2147.5 kJ 4B(s) + 3O 2 (g) à 2 B 2 O 3 (s) H o = -2509.1 kJ 2H 2 (g) + O 2 (g) à 2H 2 O(l) H o = (-571.7 kJ)*2 B 2 O 3 (s) + 3H 2 O(l) à B 2 H 6 (g) + 3 O 2 (g) H o = (+2147.5 kJ)*3 4B(s) + 6H 2 à 2B 2 H 6 (g) = -2509.1 kJ + (-571.7 kJ)*2 + (2147.5 kJ)*3 = 70.8 kJ 70.8 kJ/2 = 35.5 kJ 2B(s) + 3H 2 à B 2 H 6 (g) H o = 35.5 kJ 9. ( 8 points ) A 124.5 g sample of an unknown metal absorbs 1276.25 J of heat, upon which the temperature of the sample increases from 50.41 °C to 61.80 °C. a. Calculate the specific heat capacity of the metal. ?? = 1276.25 ? 1418.055 ° ? = 0.900 5 Substance Specific Heat Capacity (c) (J/g °C) Aluminum 0.900 Brass 0.402 Copper 0.385 Lead 0.160 Magnesium 1.017 Tin 0.213 Zinc 0.388
Name: Anthony Moore CHM 111 Exam 2 b. Use the chart to identify the metal Aluminum 10. (8 points) For the following processes, calculate the change in internal energy of the system and determine whether the process is endothermic or exothermic a. The system performs 92 kJ of work on its surroundings and loses 9 kJ of heat. 9 ?? + ( 92 ?? ) = 101 ?? b. A gas is cooled and releases 215 J of heat into the atmosphere while the atmosphere does 4.500 kJ of work on the gas. 0.215 ?? + 4.500 ?? = 4.285 ?? Endothermic 11. ( 8 points ) What is the oxidation number of carbon? C __+/-4___ CO 3 2- ___+4__ CH 4 ___-4__ H 2 CO 2 ___+4__ 12.( 10 points ) A laser has a frequency of 2.5x10 14 Hz. a. Calculate the energy of one photon of this laser in J 6.626 10 34 ? ⋅ ?⋅ 2.5 10 14 ? 1 = 1.657 10 19 ? b. What is the wavelength of the laser? 6
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Name: Anthony Moore CHM 111 Exam 2 ( 3 10 8 ? ? ) ( 2.5 10 14 1 ? ) = 1.2 10 6 ? 13.( 12 points) Circle each of the following that represent an acceptable set of quantum numbers for an electron in an atom. Describe the error in each incorrect set . n l m l m s Error 3 2 0 3/2 M s cannot equal 3/2 2 1 0 -1/2 acceptable 1 1 0 1/2 If n=1, l cannot equal 1 3 2 2 -1/2 m must equal an integer between +1 and -1 4 1 -2 1/2 m must equal an integer between +1 and -1 0 1 -1 -1/2 n must have an integer value greater than 0 14. (12 points) Write the condensed electron configurations for the following atoms or ions a. Br: [ ?? ] 4 ? 2 3 ? 10 4 ? 5 b. Cs: [ ?? ] 6 ? 1 c. Cu: [ ?? ] 4 ? 1 3 ? 10 7
Name: Anthony Moore CHM 111 Exam 2 d. I: [ ?? ] 5 ? 2 4 ? 10 5 ? 5 8