Practice Exam 5 Spring 2024

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Arizona State University *

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113

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Chemistry

Date

Feb 20, 2024

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9

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Practice Exam 5 Spring 2024 »+ Question 1 0/0pts Comparing the lattice energies of NaCl and MgO, which of the following factors contribute to the greater lattice energy for Mg0? m both ion charge and ionic radii ionic radii only nuclear charge and ionic radii ion charge only none of these choices Question 2 0/0pts The type of compound that is most likely to contain a covalent bond is | m one composed of elements with high electronegativities. one that is composed of a metal from the far left of the periodic table and a nonmetal from the far right of the periodic table a solid metal held together by the electrostatic forces between oppositely charged ions there is no general rule to predict covalency in bonds
Question 3 0/0pts How many valence electrons are in the Lewis structure of CH3CH,CI? 20 12 18 10 14
Question 4 One correct Lewis structure of the carbonate polyatomic ion, €032 is - 2- 0. I C N\ / 0: lo:
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Question 5 0/0pts Which of the following cannot be drawn without violating the octet rule. Consider all resonance structures. Sefy NF3 CFy Question 6 0/0pts For resonance forms of a molecule or ion, the observed structure is an average of the equivalent resonance forms one always corresponds to the observed structure all the resonance structures are observed in various proportions the same atoms need not be bonded to each other in all resonance forms there cannot be more than two resonance structures for a given species
Question 7 0/0pts The formal charge on nitrogen in the polyatomic ion NO5” is 1= +2 2 Question 8 1/1pts The following reaction shows decomposition of carbon tetrachloride into elemental carbon and diatomic chlorine. CCla(g) C(s) + 2Cl2(9) Using the bond enthalpies, calculate AH p. D Bond |y ymol c—cl | 328 c—c| 22 EEZED oo AHnn=86kJ AHnn=570kJ AHnn= —378kJ AHnn= —78kJ
Question 9 0/0pts For which of the molecules is the molecular geometry (shape) the same as the VSEPR electron domain arrangement (electron domain geometry)? (i) XeFq (ii) CBry ) SCly (iv) BCl3 (v) SFe (i), () an (v) (i) and (i) (ii) and (iil) (iil, and (iv) (iv) and (v) Question 10 0/0pts The molecular geometry of the right most carbon atom in the molecule below is trigonal planar trigonal bipyramidal tetrahedral octahedral Tshape
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Question 11 0/0pts Which of the following fluorinated chiorines are polar? CIF;” CIFy CIFs ClFsonly CIEs only CIFs and G- CIF and CF Question 12 0/0pts The hybridization of the oxygen atom labeled y n the structure below is The 0=C-0 pproximate bond angle is Ole—x L EE o 120
Question 13 0/0pts ‘Assuming the central atom is sulfur, which of the following molecules or ions will extibit defocalized x bonding? (Assume S does not violate octet rule uness necessary) S0, SO; S05% and s077 Fthese will extib alized boncing, Question 14 0/0pts The benzene molecule (CsHe) can be represented as two eauivalent resonance structures (A and B). @) Which of the following statements s false? Each carbon's s unhybridized atomic orital forms the g bond with hycrogen. Thes Esch C-C bond s inermediate i length between a single 3nd a Esch cart bonding. ses 1 unhy bialthat partcipates nthe
' Question 15 0/0pts In the molecular orbital description of the B,* ion, which statement is true? Hint: Fill in the MO diagram for B>". | m B,* is paramagnetic because there is one unpaired electron. B, is paramagnetic because there are three unpaired electr
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