Which statement below is not correct?O The lattice energy depends on the sizes and charges of the ions present.Olonic bonding is favored over other types when atoms with small ionization energies combine with atoms that have largeexothermic electron affinities.O The attraction of positive and negative ions leads to an ionic bond between two ions.The lattice energy of NaCl is the energy released when 1 mole of this ionic compound forms from Na(s) and Cl2(g).

"Ionic bonding is favored over other types when atoms with small ionization energies combine with…

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Chemistry: Principles and Practice

3rd Edition

ISBN:9780534420123

Author:Daniel L. Reger, Scott R. Goode, David W. Ball, Edward Mercer

Publisher:Daniel L. Reger, Scott R. Goode, David W. Ball, Edward Mercer

Chapter9: Chemical Bonds

Section: Chapter Questions

Problem 9.32QE

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Arrange the following series of compounds in order of increasing lattice energies. (a) NaBr, NaCl, KBr (b) MgO, CaO, CaCl2 (c) LiF, BeF2, BeO
For which of the following substances is the least energy required to convert one mole of the solid into separate ions? (a) MgO (b) SrO (c) KF (d) CsF (e) MgF2
Bond Enthalpy When atoms of the hypothetical element X are placed together, they rapidly undergo reaction to form the X2 molecule: X(g)+X(g)X2(g) a Would you predict that this reaction is exothermic or endothermic? Explain. b Is the bond enthalpy of X2 a positive or a negative quantity? Why? c Suppose H for the reaction is 500 kJ/mol. Estimate the bond enthalpy of the X2 molecule. d Another hypothetical molecular compound, Y2(g), has a bond enthalpy of 750 kJ/mol, and the molecular compound XY(g) has a bond enthalpy of 1500 kJ/mol. Using bond enthalpy information, calculate H for the following reaction. X2(g)+Y2(g)2XY(g) e Given the following information, as well as the information previously presented, predict whether or not the hypothetical ionic compound AX is likely to form. In this compound, A forms the A+ cation, and X forms the X anion. Be sure to justify your answer. Reaction: A(g)+12X2(g)AX(s)The first ionization energy of A(g) is 400 kJ/mol. The electron affinity of X(g) is 525 kJ/mol. The lattice energy of AX(s) is 100 kJ/mol. f If you predicted that no ionic compound would form from the reaction in Part e, what minimum amount of AX(s) lattice energy might lead to compound formation?
Write all resonance structures of chlorobenzene, C6H5Cl, a molecule with the same cyclic structure as benzene. In all structures, keep the CCl bond as a single bond. Which resonance structures are the most important?
What main factors control the magnitude of lattice energies? Give a specific example of a compound that should have a high lattice energy, and explain why its lattice energy is high.
Draw Lewis structures for the following molecules or polyatomic ions. a. SO3 b. SO32
Compare your answers from parts a and b of Exercise 69 of Chapter 3 with H values calculated for each reaction using standard enthalpies of formation in Appendix 4. Do enthalpy changes calculated from bond energies give a reasonable estimate of the actual values?
An ionic compound has the following composition (by mass): Ca, 30.3%; N, 21.2%; O, 48.5%. What are the formula and name of the compound? Write the Lewis formulas for the ions.
A polyatomic ion is composed of C, N, and an unknown element X. The skeletal Lewis structure of this polyatomic ion is [XCN]. The ion X2 has an electron configuration of [Ar]4s23d104p6. What is element X? Knowing the identity of X, complete the Lewis structure of the polyatomic ion, including all important resonance structures.
Using the standard enthalpy of formation data in Appendix G, calculate the bond energy of the carbon-sulfur double bond in CS2.
Which of the following atoms would be expected to form negative ions in binary ionic compounds and which would be expected to form positive ions: Br, Ca, Na, N, F, Al, Sn, S, Cd?
Write the Lewis symbols of the ions in each of the following ionic compounds and the Lewis symbols of the atom from which they are formed: (a) MgS (b) Al2O3 (c) GaCl3 (d) K2O (e) Li3N (f) KF

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