CHEM 102 Recitation Week 3

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Drexel University *

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102

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Chemistry

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Feb 20, 2024

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5

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CHEM 102 – Recitation Week 3 Using the "Key Concepts" and the "Key Equations and Relationships" in the Chapter Summary at the end of each chapter, identify and type in this Word document some concepts and/or equations needed to solve each item. Be prepared to share your ideas in class discussions. You are NOT required to solve the problems in detail. If you choose to do it to better participate in class discussion, keep in mind that full problem-solving is not graded for the pre-recitation assignment. To get full recitation credit, you must identify at least 1-2 correct and also different concepts for each question (see the Answer Key posted for week 1, which shows comprehensive examples of concept identification). Copying and pasting very general concepts (such as, “units of measure” or “dimensional analysis”, etc.) as the only identified concepts for multiple questions is not allowed. Ch. 11, 71. Identify the states present at points a through g in the phase diagram shown below. Phase diagram Critical point Temperature heating curves 1
Ch. 11, 72. Consider the phase diagram for iodine shown below. Phase Diagrams Temperature heating curve Phase changes a) What is the normal boiling point for iodine? b) What is the melting point for iodine at 1 atm? c) Which physical state is present at room temperature and normal atmospheric pressure? d) Which physical state of iodine is present at 186 o C and 1 atm? Ch. 11, 79. Explain the role water plays in moderating Earth's climate. Evaporation Endothermic reactions/Vaporization Ch. 11, 106. A substance has a triple point at a temperature of 17 o C and a pressure of 3.2 atm. In which states can the substance exist on the surface of Earth at sea level (15 o C, 1 atm), open to the atmosphere? Phase diagram Triple points Pressure changes 2
Ch. 21, 33. Based on the molecular formula, determine whether each compound is an alkane, alkene or alkyne. Assume that the hydrocarbons are noncyclic and there is no more than one multiple bond. Hyrdocarbons Single bond, double bond, triple bond a. C 5 H 12 b. C 3 H 6 c. C 7 H 12 d. C 11 H 22 Ch. 21, 42. Name each alkane below. Structural formulas Aliphatic hydrocarbons a. b. c. d. Ch. 21, 44. Draw a structure for each alkane below. Structural formulas Hydrocarbon Nomenclature b. 3-isopropylheptane c. 4-ethyl-2,2-dimethylhexane Ch. 21, 51. Name each alkene below. Structural formulas Aliphatic hydrocarbons 3
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a. d. Ch. 21, 54. Name each alkyne below. Structural formulas Aliphatic hydrocarbons c. d. Ch. 21, 55. Draw the correct structure for each compound below. Structural formulas Hydrocarbon Nomenclature a. 4-octyne d. 5-ethyl-3,6-dimethyl-2-heptene Honors only Ch. 11, 97. One prediction of global warming is the melting of global ice, which may result in coastal flooding. A criticism of this prediction is that the melting of icebergs does not increase ocean levels any more than the melting of ice in a glass of water increases the level of liquid in the glass. Is this a valid criticism? Does the melting of an ice cube in a cup of water raise the level of the liquid in the cup? Why or why not? In response to this criticism, scientists have asserted that they are not worried about melting icebergs, but rather the melting of ice sheets that sit on the continent of Antarctica. Would the melting of this ice increase ocean levels? Why or why not? 4
Ch. 21, 96. How many kilograms of CO 2 does the complete combustion of 3.8 kg of n -octane produce? 5