OWLV2 FOR OXTOBY/GILLIS/BUTLER'S PRINCI8th EditionButler Publisher: IACCENGAGEISBN: 9781305271579
OWLV2 FOR OXTOBY/GILLIS/BUTLER'S PRINCI
Solutions for OWLV2 FOR OXTOBY/GILLIS/BUTLER'S PRINCI
Problem 1P:
Which of the following combinations of quantum numbers are allowed for an electron in a one-electron...Problem 2P:
Which of the following combinations of quantum numbers are allowed for an electron in a one-electron...Problem 3P:
Label the orbitals described by each of the following sets of quantum numbers: (a) n=4,l=1 (b)...Problem 4P:
Label the orbitals described by each of the following sets of quantum numbers: (a) n=3,l=2 (b)...Problem 5P:
Estimate the probability of finding an electron which is excited into the 2s orbital of the H atom,...Problem 6P:
Using Table 5.2, write down the mathematical expression for the 2px wave function for an...Problem 7P:
How many radial nodes and how many angular nodes does each of the orbitals in Problem 3 have?Problem 8P:
How many radial nodes and how many angular nodes does each of the orbitals in Problem 4 have?Problem 9P:
Use the mathematical expression for the 2pz wave function of a one-electron atom (see Table 5.2) to...Problem 10P:
(a) Use the radial wave function for the 3p orbital of a hydrogen atom (see Table 5.2) to calculate...Problem 11P:
Calculate the average distance of the electron from the nucleus in a hydrogen atom when the electron...Problem 12P:
The helium ion He+ is a one-electron system whose wave functions and energy levels are obtained from...Problem 13P:
Spectroscopic studies show that Li can have electrons in its 1s, 2s, and 2p Hartree orbitals, and...Problem 14P:
Spectroscopic studies of Li also show that Zeff(2p)=1.02 . Estimate the energy of the 2p orbital of...Problem 15P:
Spectroscopic studies show that Na can have electrons in its 1s, 2s, 2p, and 3s Hartree orbitals,...Problem 16P:
Using data from Problems 13 and 15, calculate the average distance of the electron from the nucleus...Problem 17P:
Give the ground-state electron configurations of the following elements: (a) C (b) Se (c) FeProblem 18P:
Give the ground-state electron configurations of the following elements: (a) P (b) Tc (c) HoProblem 20P:
Write ground-state electron configurations for the ions Li,B+,F,Al3+,S,Ar+,Br+, and Te . Which do...Problem 21P:
Identify the atom or ion corresponding to each of the following descriptions: (a) an atom with...Problem 22P:
Identify the atom or ion corresponding to each of the following descriptions: (a) an atom with...Problem 23P:
Predict the atomic number of the (as yet undiscovered) element in the seventh period that is a...Problem 24P:
(a) Predict the atomic number of the (as yet undiscovered) alkali-metal element in the eighth...Problem 25P:
Suppose that the spin quantum number did not exist, and therefore only one electron could occupy...Problem 26P:
Suppose that the spin quantum number had three allowed values (ms=0,+12,12) . Give the atomic...Problem 27P:
Photoelectron spectra of mercury (Hg) atoms acquired with radiation from a helium lamp at 584.4 Å...Problem 28P:
Quantum mechanics predicts that the energy of the ground state of the H atom is 13.6eV . Insight...Problem 30P:
Photoelectron spectroscopy studies of silicon atoms excited by X-rays with wavelength 9.8901010m...Problem 31P:
Photoelectron spectroscopy studies have determined the orbital energies for fluorine atoms to be...Problem 33P:
For each of the following pairs of atoms or ions, state which you expect to have the larger radius....Problem 34P:
For each of the following pairs of atoms or ions, state which you expect to have the larger radius....Problem 35P:
Predict the larger ion in each of the following pairs. Give reasons for your answers. (a) O,S2 (b)...Problem 37P:
The first ionization energy of helium is 2370kJmol1 , the highest for any element. (a) Define...Problem 38P:
The energy needed to remove one electron from a gaseous potassium atom is only about two-thirds as...Problem 39P:
Without consulting any tables, arrange the following substances in order and explain your choice of...Problem 40P:
Both the electron affinity and the ionization energy of chlorine are higher than the corresponding...Problem 41P:
The cesium atom has the lowest ionization energy, 375.7kJmol1 , of all the neutral atoms in the...Problem 42P:
Until recently, it was thought that Ca was unstable, and that the Ca atom therefore had a negative...Problem 43AP:
In the hydrogen atom, the transition from the 2p state to the 1s state emits a photon with energy...Problem 44AP:
The energy needed to ionize an atom of element X when it is in its most stable state is 500kJmol1 ....Problem 45AP:
Suppose an atom in an excited state can return to the ground state in two steps. It first falls to...Problem 46AP:
For the Li atom, the energy difference between the ground state and the first excited state, in...Problem 47AP:
How does the 3dxy orbital of an electron in O7+ resemble the 3dxy orbital of an electron in a...Problem 48AP:
The wave function of an electron in the lowest (that is, ground) state of the hydrogen atom is (r)=(...Problem 49AP:
An atom of sodium has the electron configuration [Ne]6s1 . Explain how this is possible.Problem 50AP:
(a) The nitrogen atom has one electron in each of the 2px , 2py , and 2pz orbitals. By using the...Problem 51AP:
Chromium(IV) oxide is used in making magnetic recording tapes because it is paramagnetic. It can be...Problem 53AP:
Arrange the following seven atoms or ions in order of size, from smallest to largest:...Problem 54AP:
Which is higher, the third ionization energy of lithium or the energy required to eject a 1s...Problem 55AP:
The outermost electron in an alkali-metal atom is sometimes described as resembling an electron in...Problem 56AP:
In two-photon ionization spectroscopy, the combined energies carried by two different photons are...Problem 57AP:
For the H atom, the transition from the 2p state to the 1s state is accompanied by the emission of a...Browse All Chapters of This Textbook
Chapter 1 - The Atom In Modern ChemistryChapter 2 - Chemical Formulas, Equations, And Reaction YieldsChapter 3 - Atomic Shells And Classical Models Of Chemical BondingChapter 4 - Introduction To Quantum MechanicsChapter 5 - Quantum Mechanics And Atomic StructureChapter 6 - Quantum Mechanics And Molecular StructureChapter 7 - Bonding In Organic MoleculesChapter 8 - Bonding In Transition Metal Compounds And Coordination ComplexesChapter 9 - The Gaseous StateChapter 10 - Solids, Liquids, And Phase Transitions
Chapter 11 - SolutionsChapter 12 - Thermodynamic Processes And ThermochemistryChapter 13 - Spontaneous Processes And Thermodynamic EquilibriumChapter 14 - Chemical EquilibriumChapter 15 - Acid–base EquilibriaChapter 16 - Solubility And Precipitation EquilibriaChapter 17 - ElectrochemistryChapter 18 - Chemical KineticsChapter 19 - Nuclear ChemistryChapter 20 - Molecular Spectroscopy And PhotochemistryChapter 21 - Structure And Bonding In SolidsChapter 22 - Inorganic MaterialsChapter 23 - Polymeric Materials And Soft Condensed MatterChapter A - Scientific Notation And Experimental Error
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