Introduction to Chemistry4th EditionRich Bauer, James Birk Professor Dr., Pamela S. Marks Publisher: McGraw-Hill EducationISBN: 9780073523002
Introduction to Chemistry
Solutions for Introduction to Chemistry
Problem 2QC:
How can the composition of atom differ?Problem 3QC:
How do ions differ from the atoms of elements?Problem 1PP:
For the atom represented in the following diagram, (a)Â Â Determine the number of protons and...Problem 2PP:
A rare isotope of carbon has a mass number of 14. How many protons, electrons, and neutrons are in...Problem 3PP:
Write two representations for the following isotope.Problem 4PP:
Determine the number of neutrons in each of the following isotopes. aI53131b37Clccarbon-13Problem 5PP:
How many protons and electrons compose the following ions? Identify each as a cation or anion....Problem 6PP:
Write the isotope symbols for ions that have the following numbers of protons, neutrons, and...Problem 7PP:
The copper mined from Earth’s crust consists of 63Cu (62.93 amu) and 65Cu (64.93 amu). Which...Problem 8PP:
The element lithium is composed of two isotopes, lithium-6 and lithium-7. The mass and percent...Problem 9PP:
Identify the element that is described. (a) the element that is in group VA (15) and in period 2,...Problem 1QP:
Match the key terms with the descriptions provided. (a) an electrically neutral subatomic particle...Problem 2QP:
Match the key terms with the descriptions provided. (a) a member of one of the B groups of elements...Problem 9QP:
Does the following diagram represent a chemical reaction that obeys the law of conservation of mass?...Problem 10QP:
Does the following diagram represent a chemical reaction that obeys the law of conservation of mass?...Problem 11QP:
Which experiment showed that all atoms contain negatively charged particles with masses far less...Problem 12QP:
What information about the structure of the atom did Rutherford's gold foil experiment provide?Problem 13QP:
Which subatomic particles are negatively charged?Problem 14QP:
Which subatomic particles are positively charged?Problem 15QP:
Helium is used in balloons and blimps because of its lifting power. Draw a nuclear model of a helium...Problem 16QP:
Hydrogcn-3 (tritium) is used as a tracer in chemical, biological, and medical research. Draw a...Problem 18QP:
Which of the following best describes about how many times greater in mass a proton is than an...Problem 19QP:
Explain why the mass of a carbon atom is about twice the mass of the protons in a carbon atom. What...Problem 22QP:
How many protons are in each atom of each of the following elements? aheliumbargoncleadProblem 24QP:
How do isotopes of an element differ?Problem 27QP:
Which of the following are always the same for atoms of the same element? (a) mass number (b) atomic...Problem 28QP:
Which of the following are different for isotopes of an element? (a) mass number (b) atomic number...Problem 29QP:
Given the composition of the nuclei, what are the atomic number, neutron number, and mass number of...Problem 30QP:
Identify the element from the atom shown. What are the atomic number, neutron number, and mass...Problem 31QP:
What are the atomic number, neutron number, and mass number of the following isotopes?...Problem 32QP:
Identify the element from the atom shown. What are the atomic number, neutron number, and mass...Problem 34QP:
How many protons, neutrons, and electrons are in each of the following? (a) a hydrogen atom with a...Problem 35QP:
What is the isotope symbol for atoms that contain the following numbers of subatomic particles? (a)...Problem 36QP:
What is the isotope symbol for atoms that contain the following numbers of subatomic particles? (a)...Problem 37QP:
How many protons and neutrons are in an atom represented by the following? a2656Feb39kccopper-65Problem 38QP:
How many protons and neutrons are in an atom represented by the following? a511BbZ68nciodine127Problem 39QP:
A study of blood flow in heart muscle uses nitrogen-l3 incorporated into a chemical agent. How many...Problem 40QP:
Phosphorus-32 can be used to treat eye tumors. How many protons and neutrons are found in the P-32...Problem 41QP:
Complete the following table for the designated atoms.Problem 42QP:
Complete the following table for the designated atoms.Problem 43QP:
How do an atom and an ion of the same element differ?Problem 46QP:
What forms when an ion with a 1+ charge undergoes each of the following changes? (a) It gains one...Problem 48QP:
Write the symbol for the ion that is formed after each of the following changes. Identify each ion...Problem 57QP:
How do 7Li+6Li each differ from a neutral lithium-7 atom? Which differs from lithium-7 by the...Problem 58QP:
How do B3579r and B3581r Br differ in their numbers of subatomic particles? Which should have the...Problem 59QP:
Potassium citrate is a compound found in some sparkling beverages. The potassium in this compound is...Problem 60QP:
Calcium citrate is a compound found in some calcium supplement medications. The calcium in this...Problem 61QP:
What is the basis for the atomic mass unit (amu) scale?Problem 62QP:
What is the mass of a carbon-12 atom on the amu scale? ls this value exact or approximate?Problem 63QP:
What is the approximate mass, in atomic mass units, of the following isotopes? aH12 Â bU92238Problem 66QP:
Approximately how much greater in mass is a D2O molecule than an H2O molecule? (Assume the oxygen...Problem 69QP:
Why do we use the amu mass scale instead of the gram mass scale when discussing masses of atoms?Problem 70QP:
What is the relationship between grams and atomic mass units? How many atomic mass units are in 1g ?Problem 73QP:
How is the mass of an individual atom determined? How do you determine the mass number of an atom?Problem 74QP:
Which of the following is most likely the mass of a nickel-62 atom: 62,0000000 amu, 62,495654 amu,...Problem 75QP:
Naturally occurring calcium is composed of two isotopes: calcium-40 and calcium-44. Which isotope is...Problem 77QP:
An unknown element (X) discovered on a planet in another galaxy was found to exist as two isotopes....Problem 78QP:
Suppose that the isotope abundance of magnesium on another planet has been determined to be...Problem 79QP:
The mass spectrum of nickel is shown. (a) What is the most abundant isotope of nickel? (b) What is...Problem 80QP:
The mass spectrum of magnesium is shown. (a) What is the most abundant isotope of magnesium? (b)...Problem 81QP:
What is the mass in amu of 1000 boron atoms?Problem 82QP:
What is the mass in amu of 1000 mercury atoms?Problem 84QP:
A sample of pure silver and a simple of pure gold have the same mass. Which contains the greatest...Problem 85QP:
Identify which of the elements Br, K, Mg, Al, Mn, and Ar can be classified in each of the following...Problem 86QP:
Identify which of the elements He, Zn, Pb, L Ca, and Na can be classified in each of the following...Problem 89QP:
What element is in group IVB (4) and in period 4?Problem 90QP:
What element is in group IVA (14) and in period 2?Problem 91QP:
Identify each of the following elements as a metal, nonmetal, or metalloid. (a) calcium (b) carbon...Problem 92QP:
Identify each of the following elements as a metal, nonmetal, or metalloid. (a) phosphorus (b)...Problem 93QP:
Identify the following elements as a main-group element, transition metal, lanthanide, or actinide....Problem 94QP:
Identify the following elements as a main-group element, transition metal, lanthanide, or actinide....Problem 100QP:
The noble gases are sometimes called “inert gases." Why? Why do they not form ions?Problem 101QP:
The ions of many of the main-group elements have the same number of as the noble gas nearest to...Problem 103QP:
Identify the groups of the periodic table in which all the elements form ions of the charge...Problem 104QP:
For each group listed. identify the charge on the ions that they form. (a) group VIA (16) (b)...Problem 108QP:
Chlorine gas reacts with potassium to form a compound with properties similar to table salt. Which...Problem 109QP:
When iron rusts. a compound forms with the formula Fe2O3 . When iron nails rust, should their mass...Problem 111QP:
A 100-g sample of zinc sul�de contains 67.1 g zinc and 32.9 g sulfur. if a 1.34-g sample of zinc...Problem 112QP:
A 100-g sample of HgO contains 92.6 g mercury and 7.4 g oxygen. What mass of mercury atoms and what...Problem 113QP:
What properties of electrons contributed to why they were the �rst subatomic particles to be...Problem 114QP:
What experimental evidence led to each of the following advances in our understanding of atomic...Problem 116QP:
Why is it impossible for an element to have a mass number less than its atomic number?Problem 117QP:
How many protons and neutrons are in a potassium-39 atom?Problem 119QP:
Explain why the relative atomic mass of cobalt is greater than that of nickel. although the atomic...Problem 120QP:
Which element has an isotope that has a mass approximately three times greater than its most...Problem 121QP:
Some tables list relative atomic mass to as many signi�cant �gures as can be reported...Problem 122QP:
How many atoms are in each of the following samples of carbon-12? (a) 120 amu (b) 12,000 amu (c)...Problem 125QP:
A sample of pure carbon and a sample of pure iodine have the same mass. Which has the greatest...Problem 126QP:
Two equal-volume balloons contain the same number of atoms. One contains helium and one contains...Problem 127QP:
Naturally occurring boron comprises two isotopes, boron-10 and boron-l1. The atomic mass of boron-10...Problem 130QP:
Nitrogen and oxygen are the main components of the air we breathe. Write formulas to represent these...Problem 132QP:
Which element is the only nonmetal in group IVA (14)?Problem 137QP:
Positron emission tomography (PET) is used in medicine to produce an image of functions inside the...Problem 138QP:
When silver tarnishes, a chemical reaction occurs in which a compound of silver and sulfur forms on...Problem 139QP:
The iron found in the human body is in the form of fe2+ or Fe3+ ions. How do neutral atoms and the...Problem 140QP:
Which has the greater density, an ice cube containing the hydrogen-l isotope or an ice cube...Problem 142QP:
After he conducted cathode ray tube experiments proving the existence of negatively charged...Problem 143QP:
Analysis of carbon-14 content is used to date fossils up to about 60,000 years old. There are two...Problem 144QP:
A naturally occurring isotope of potassium has a mass number of 40. One of argon’s naturally...Problem 146QP:
A monatomic ion with a 4+ charge has the same number of electrons as an argon atom. What is the...Problem 147QP:
Which of the following has the greatest number of electrons? A.Ca2+B.K+C.ClD.S2 E. These all have...Problem 149QP:
Atoms that are isotopes of the same element differ in A. number of neutrons B. number of protons C....Problem 150QP:
Which of the following statements about atoms and subatomic particles is true? A. The nucleus of an...Problem 151QP:
Elements in which group always form monatomic ions with a negative 1 1 charge? A. alkali metals B....Problem 152QP:
Identify the number of protons and neutrons in an atom of the isotope 64Zn. A. 64 protons, 34...Browse All Chapters of This Textbook
Chapter 1 - Matter And EnergyChapter 2 - Atoms, Ions, And The Periodic TableChapter 3 - Chemical CompoundsChapter 4 - Chemical CompositionChapter 5 - Chemical Reactions And EquationsChapter 6 - Quantities In Chemical ReactionsChapter 7 - Electron Structureof The AtomChapter 8 - Chemical BondingChapter 9 - The Gaseous StateChapter 10 - The Liquid And Solid States
Book Details
Introduction to Chemistry, 4e by Bauer/Birk/Marks offers today's student a fresh perspective to the introduction of chemistry. This textbook offers a conceptual approach to chemistry by starting first with macroscopic phenomena, and then presenting the underlying microscopic detail. Each chapter opens with a real-life scenario that helps students connect abstract chemical concepts to their own lives. The math found in
Introduction to Chemistry, 4e is introduced on a need-to-know basis, with "Math Toolboxes" in select chapters to help support the math skills required in that chapter.
Sample Solutions for this Textbook
We offer sample solutions for Introduction to Chemistry homework problems. See examples below:
Chapter 1, Problem 1QCChapter 1, Problem 9PPSignificant figures are the digit numbers in which the answer is described in accuracy. It starts...The calculation can be carried out by simply applying the multiplication method:...Chapter 1, Problem 8QPChapter 1, Problem 19QPChapter 1, Problem 20QPChapter 1, Problem 21QPThe conversion factor for centiometer to feet is as follows. 1 cm=0.0328084 ft1=0.0328084 ft1 cm For...
Chapter 1, Problem 23QPThe relation between Foot ft and in is shown below: 1 ft=12 in The conversion factors used to...Chapter 1, Problem 86QPChapter 1, Problem 113QPChapter 1, Problem 122QPChapter 1, Problem 124QPChapter 1, Problem 142QPChapter 1, Problem 145QPChapter 1, Problem 156QPChapter 1, Problem 157QPChapter 2, Problem 1QCGiven information: The table is provided in the question. In the first row of the table, the mass...The differences between ionic and molecular compounds are explained below: In ionic compounds,...Given Information:Table is provided in the question. Ca2+ cation combines with Cl− to form CaCl2...Given Information:Table is provided in the question. Ba2+ cation combines with Br− to form BaBr3...Chapter 3, Problem 55QPGiven Information: Table is provided in the question. Sodium cation Na+ combines with chloride anion...Ammonia is a combination of nitrogen and hydrogen in which a covalent bond is formed by sharing of...The charges and symbols of elements are analyzed on the basis of their position in the periodic...In a compound, the mass composition of an element is determined by dividing the mass of that element...The given compound is Hg2Cl2 . Molar mass can be determined by adding the masses of the...Chapter 4, Problem 28QPThe given compound is K2SO4 . Number of moles is determined using the molar mass and mass of the...The molar mass of 15 g Na2CO3 is to be converted into an equivalent number of moles. The number of...Chapter 4, Problem 53QPChapter 4, Problem 55QPChapter 4, Problem 56QPChapter 4, Problem 73QPChapter 4, Problem 87QPThe percent composition of any substance is calculated by dividing the mass of the substance in a...The percent composition of any substance is calculated by dividing the mass of substance in a sample...The percent composition of any substance is calculated by dividing the mass of substance in a sample...The molarity of the acetic acid solution is to be determined. The number of moles is calculated from...The number of moles is calculated from the following expression: n=mMm …… (1) Here, m is the...The conversion of volume from milliliters to liters is given as follows: VolumeL=x mL×1 L1000 mL...C3H4 contains three moles of carbon and four moles of hydrogen. The mass of three moles of carbon is...The number of moles of Ca3PO42 can be calculated by using the expression of molarity as follows:...Chemical reaction is defined as a process in which reactant species interact with each other in...The skeleton equation for the chemical equation is shown in (1) where, on the left side, the number...The skeleton equation for the chemical equation is shown below, where on the left side, the number...The chemical equation that is shown below is balanced because the number of atoms on the left side...Sodium chloride NaCl and sodium sulfate Na2SO4 are electrolytes whereas silver sulfate Ag2SO4 and...Except for chromium (III) hydroxide (Cr(OH)3), all other substances in the given reaction are...Chapter 5, Problem 111QPAmmonium nitrate and chromium chloride are electrolytes that react to produce chromium (III)...The given reaction is, C4H10g+O2g→CO2g+H2Og The reactant side contains 4 carbon atoms, 10 hydrogen...The numerical coefficients in a chemical equation show the ratio of the molecules of each of the...Given Information: The given reaction: Na2CO3s+2HClg→2NaClaq+H2Ol+CO2g Moles of Na2CO3 is 11 g and...The balanced equation of the given reaction is: 2C7H5NO23s→7Cs+7COg+3N2g+5H2Og It is apparent from...The balanced equation of the given reaction is: 2NH4NO3s→2N2g+O2g+4H2Og It is apparent from the...The mass of the first reactant is 0.600 g . The relation among the number of moles, molar mass and...The relation among the number of moles, molar mass and mass is, n= mMM Here, n is the number of...Given information: A reaction is given in the question. Initially, 0.269 g of C2H6 is mixed. So, the...Given Information: A reaction is given in the question. Initially, 0.130 g of C4H10 is mixed. So,...Given Information: Mass of pipe and water is 175 g and 100 g , respectively. The temperatures of...Chapter 6, Problem 126QPThe given balanced equation shows that one mole of MgNO32 dissolves and dissociates into Mg2+ and 2...4 moles of C3H3N3O9 decomposes to produce 6 moles of N2 . The number of moles of N2 produced by 1.0...One mole of N2 reacts with three moles of H2 . Thus, N2 is present in excess. So, the number of...The electromagnetic spectrum includes different radiations that are categorized on the basis of...When a metal and a non-metal are present in the formula, then ionic bond is formed. In ionic...Chapter 8, Problem 89QPChapter 8, Problem 131QPThe general properties of gases are discussed below. Compressibility: As the intermolecular spaces...The conversion factor required to convert the value of pressure is: 760 torr=1 atm1=1 atm760 torr...The conversion factor which is used to convert the pressure from atm to torr is as follows: 1...The calculation for determining the final volume of the gas. The conversion of temperature from...: The calculation for determining the final pressure of the gas. The conversion of temperature from...Ideal gas law gives a relation between pressure P , volume V , temperature T , and the number of...Ideal gas law gives a relation between pressure P , volume V , temperature T , and the number of...Ideal gas law gives a relation between pressure P , volume V , temperature T , and the number of...The molar mass of a gas at STP can be determined by using the value of its density. The density ρ of...The ideal gas equation is an equation that determines the relation between the pressure P ,...Given Information: The volume of N2O is 145 L at 2850 torr and 42°C . The reaction is as follows:...Given Information: The volume of argon gas collected over water is 3 L at 27.0°C and 765 torr . The...Given Information: The volume of the tank is 2.00 L . Tank contains 72.0 g N2 and 66.0 g Ar . The...Given Information: The amount of limestone used daily is 1.00×105 kg at 735 torr and 25.0°C . The...The number of moles of a gas n is equal to the ratio of the amount of gas m present in the container...Given Information: Table 9.2 The partial pressure of a gas in a mixture is defined as the force...The ideal gas equation states that pressure P and volume V of a gas is directly proportional to the...The ideal gas equation states that pressure P and volume of a gas V is directly proportional to...The number of moles of a gas n is equal to the ratio of mass of the gas m to the molar mass MM of...Oxygen is produced by the following reaction: 2KClO3s→2KCls+3O2g According to the reaction, 2 mol...Chapter 10, Problem 1QCChapter 10, Problem 37QPGiven Information: Mass of steam is 32.0 g , the temperature of steam is 115.0°C , the specific heat...Chapter 10, Problem 40QPA homogeneous mixture that has a uniform composition is called a solution. Solutions can be mixtures...Given Information: The molarity of lead nitrate solution is 0.105 M and the molarity of potassium...Chapter 11, Problem 69QPGiven Information: The (ppb) concentration of nitrate ions in tap water is 95 ppb . Parts per...Given Information: 100 mL of 0.15 M Pb2+ ion solution and 1.0 M KI solution are given. The given...Given Information: 20.00 mL of 0.1033 M NaOH is neutralized with 0.850 M H2SO4 solution. : The...The balanced chemical equation is, HCl(aq)+NaOH(aq)→NaCl(aq)+H2O(l) The moles of HCl present in...The balanced chemical equation is, HCl(aq)+NaOH(aq)→NaCl(aq)+H2O(l) The moles of NaOH present in...Given Information: Percent by mass concentration of H2SO4 solution is 24% and density of solution is...Given Information: The molarity of Acetic acid solution is 1 M and density of the solution is 1.005...Given Information: The molarity of silver nitrate solution is 0.200 M and of sodium carbonate...Given Information: The molarity of barium chloride solution is 0.100 M and of potassium sulfate...Consider the given statement, “The dissolution process of Mg(NO3)2 in water forms 0.20 M...KCl is an ionic compound and water is a polar solvent. Thus, KCl is easily soluble in water to and...The reaction between silver nitrate and potassium sulphate forms the precipitate of aluminium...A solution that gives the highest number of particles has the lowest freezing point. 1.5 m KBr...A reaction takes place under different conditions at different rates. As the concentration of...Chapter 13, Problem 1QCIonic product of water is defined as the product of concentrations of H+ and OH− ions present in the...pH of a solution gives the concentration of hydrogen ions in that solution. Range of pH values is...From the table 13.1 (from the book), H2SO4 is a strong acid. H2SO4aq dissociates completely into...Citric acid is a weak organic acid and furnishes hydronium ions according to its Ka value. The...The given concentration of OH− is 1×10−3 M . Now, OH−×H3O+=1×10−14 M2H3O+=1×10−14 M2OH− Substitute...The given concentration of H3O+ is 1×10−3 M . Now, OH−×H3O+=1×10−14 M2OH−=1×10−14 M2H3O+ Substitute...The given OH− concentration is 1×10−4 M . The expression that shows the relation between pOH and OH−...The given OH− concentration is 6.4×10−4 M . The expression that shows the relation between pOH and...The given concentration of HNO3 is 0.01 M . HNO3 is a strong acid, the H3O+ concentration is equal...The given concentration of KOH is 0.001 M . KOH is a strong base, the OH− concentration is equal to...Ionic product of water is defined as the product of concentrations of H+ and OH− ions present in the...pH of a solution gives the concentration of hydrogen ions in that solution. Range of pH values is...The given value of pH is 5 . The relation between pH and pOH is as follows: pH+pOH=14 Substitute 5...Given Information: The given concentrations of the solutions are 0.1 M HNO3 , 0.5 M HCl , a solution...The given acids are 0.5 M CH3CO2H and 0.10 M HF and their Ka values are 1.8×10−5 and 6.3×10−4 ,...Chapter 13, Problem 147QPIn a oxidation-reduction reaction, the oxidation state of a substance increases due to loss of...Chapter 14, Problem 18QPChapter 14, Problem 19QPChapter 14, Problem 20QPChapter 14, Problem 27QPThe given ion is H2PO4− . The oxidation number of oxygen and hydrogen is −2 and −1 which is...The skeleton equation chemical equation is shown below: H2Saq+Cr2O72−aq→Ss+Cr3+aq …(1) The...Chapter 14, Problem 56QPChapter 14, Problem 57QPChapter 14, Problem 58QPChapter 14, Problem 59QPThe half-cell reactions for the given chemical equations can be obtained by writing the oxidation...The ionic skeleton chemical equation for the given reaction is shown in equation (1)....The isotopes are the atoms with different number of neutrons. They can be stable or unstable...A nuclear reaction involves changes at the subatomic level such as, the changes in the number of...A nuclear reaction involves changes at the subatomic level such as, the changes in the number of...A nuclear reaction involves changes at the subatomic level such as changes in the number of protons,...If the NZ ratio is too high, nuclide undergoes beta decay to lower the ratio. If the NZ ratio is too...If the NZ ratio is too high, nuclide undergoes beta decay to lower the ratio. If the NZ ratio is too...If the NZ ratio is too high, nuclide undergoes beta decay to lower the ratio. If the NZ ratio is too...In the given nuclear reaction shown below, the mass number is not balanced because the total mass...The nuclear reaction that represents the conversion of U92234 to thorium- 230 is shown below....The half-life of technetium- 99 is 6.0 h . Thus, after 6.0 h , the amount of technetium- 99 gets...Organic molecules can be represented by their molecular formulas, ball and stick models, structural...The isomers of a compound have the same molecular formula with a different arrangement of atoms....Chapter 17, Problem 1QCThe simplest amino acid is alanine after glycine because the side chain in alanine is the methyl...
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