(a) Interpretation: The structure of 5-phenylpentanamide is to be drawn. Concept introduction: The structure of an amide can be drawn on the basis of its IUPAC name. The name consists of a root name indicating the longest continuous carbon chain that includes the carbonyl carbon of the amide group. Any prefixes present indicate the substituents on the alkyl chain or on the nitrogen if the locant is ‘N’. If the amide contains a chiral center, the absolute configuration, R or S, is shown at the start, along with its locant.

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Answer 1

Question

Chapter F, Problem F.19P

Interpretation Introduction

(a)

Interpretation:

The structure of 5-phenylpentanamide is to be drawn.

Concept introduction:

The structure of an amide can be drawn on the basis of its IUPAC name. The name consists of a root name indicating the longest continuous carbon chain that includes the carbonyl carbon of the amide group. Any prefixes present indicate the substituents on the alkyl chain or on the nitrogen if the locant is ‘N’.

If the amide contains a chiral center, the absolute configuration, R or S, is shown at the start, along with its locant.

Interpretation Introduction

(b)

Interpretation:

The structure of (2S, 3S)-2, 3-dimethoxyhexanediamide is to be drawn.

Concept introduction:

The structure of an amide can be drawn on the basis of its IUPAC name. The name consists of a root name indicating the longest continuous carbon chain that includes the carbonyl carbon of the amide group. Any prefixes present indicate the substituents on the alkyl chain or on the nitrogen if the locant is ‘N’.

If the amide contains a chiral center, the absolute configuration, R or S, is shown at the start, along with its locant.

Interpretation Introduction

(c)

Interpretation:

The structure of N-phenylcyclobutanecarboxamide is to be drawn.

Concept introduction:

The structure of an amide can be drawn on the basis of its IUPAC name. The name consists of a root name indicating the longest continuous carbon chain that includes the carbonyl carbon of the amide group. Any prefixes present indicate the substituents on the alkyl chain or on the nitrogen if the locant is ‘N’.

If the amide contains a chiral center, the absolute configuration, R or S, is shown at the start, along with its locant.

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6. A solution (0.0004 M) of Fe(S2CNEt2)3 (see the structural drawing below) in chloroform has absorption bands at: 350 nm (absorbance A = 2.34); 514 nm(absorbance A = 0.0532); Calculate the molar absorptivity values for these bands. Comment on their possible nature (charge transfer transitions or d-d S N- transitions?). (4 points)

Answer 2

Question

Chapter F, Problem F.19P

Interpretation Introduction

(a)

Interpretation:

The structure of 5-phenylpentanamide is to be drawn.

Concept introduction:

The structure of an amide can be drawn on the basis of its IUPAC name. The name consists of a root name indicating the longest continuous carbon chain that includes the carbonyl carbon of the amide group. Any prefixes present indicate the substituents on the alkyl chain or on the nitrogen if the locant is ‘N’.

If the amide contains a chiral center, the absolute configuration, R or S, is shown at the start, along with its locant.

Interpretation Introduction

(b)

Interpretation:

The structure of (2S, 3S)-2, 3-dimethoxyhexanediamide is to be drawn.

Concept introduction:

The structure of an amide can be drawn on the basis of its IUPAC name. The name consists of a root name indicating the longest continuous carbon chain that includes the carbonyl carbon of the amide group. Any prefixes present indicate the substituents on the alkyl chain or on the nitrogen if the locant is ‘N’.

If the amide contains a chiral center, the absolute configuration, R or S, is shown at the start, along with its locant.

Interpretation Introduction

(c)

Interpretation:

The structure of N-phenylcyclobutanecarboxamide is to be drawn.

Concept introduction:

The structure of an amide can be drawn on the basis of its IUPAC name. The name consists of a root name indicating the longest continuous carbon chain that includes the carbonyl carbon of the amide group. Any prefixes present indicate the substituents on the alkyl chain or on the nitrogen if the locant is ‘N’.

If the amide contains a chiral center, the absolute configuration, R or S, is shown at the start, along with its locant.

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Answer 3

Question

Chapter F, Problem F.19P

Interpretation Introduction

(a)

Interpretation:

The structure of 5-phenylpentanamide is to be drawn.

Concept introduction:

The structure of an amide can be drawn on the basis of its IUPAC name. The name consists of a root name indicating the longest continuous carbon chain that includes the carbonyl carbon of the amide group. Any prefixes present indicate the substituents on the alkyl chain or on the nitrogen if the locant is ‘N’.

If the amide contains a chiral center, the absolute configuration, R or S, is shown at the start, along with its locant.

Interpretation Introduction

(b)

Interpretation:

The structure of (2S, 3S)-2, 3-dimethoxyhexanediamide is to be drawn.

Concept introduction:

The structure of an amide can be drawn on the basis of its IUPAC name. The name consists of a root name indicating the longest continuous carbon chain that includes the carbonyl carbon of the amide group. Any prefixes present indicate the substituents on the alkyl chain or on the nitrogen if the locant is ‘N’.

If the amide contains a chiral center, the absolute configuration, R or S, is shown at the start, along with its locant.

Interpretation Introduction

(c)

Interpretation:

The structure of N-phenylcyclobutanecarboxamide is to be drawn.

Concept introduction:

The structure of an amide can be drawn on the basis of its IUPAC name. The name consists of a root name indicating the longest continuous carbon chain that includes the carbonyl carbon of the amide group. Any prefixes present indicate the substituents on the alkyl chain or on the nitrogen if the locant is ‘N’.

If the amide contains a chiral center, the absolute configuration, R or S, is shown at the start, along with its locant.

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Answer 4

Question

Chapter F, Problem F.19P

Interpretation Introduction

(a)

Interpretation:

The structure of 5-phenylpentanamide is to be drawn.

Concept introduction:

The structure of an amide can be drawn on the basis of its IUPAC name. The name consists of a root name indicating the longest continuous carbon chain that includes the carbonyl carbon of the amide group. Any prefixes present indicate the substituents on the alkyl chain or on the nitrogen if the locant is ‘N’.

If the amide contains a chiral center, the absolute configuration, R or S, is shown at the start, along with its locant.

Interpretation Introduction

(b)

Interpretation:

The structure of (2S, 3S)-2, 3-dimethoxyhexanediamide is to be drawn.

Concept introduction:

The structure of an amide can be drawn on the basis of its IUPAC name. The name consists of a root name indicating the longest continuous carbon chain that includes the carbonyl carbon of the amide group. Any prefixes present indicate the substituents on the alkyl chain or on the nitrogen if the locant is ‘N’.

If the amide contains a chiral center, the absolute configuration, R or S, is shown at the start, along with its locant.

Interpretation Introduction

(c)

Interpretation:

The structure of N-phenylcyclobutanecarboxamide is to be drawn.

Concept introduction:

The structure of an amide can be drawn on the basis of its IUPAC name. The name consists of a root name indicating the longest continuous carbon chain that includes the carbonyl carbon of the amide group. Any prefixes present indicate the substituents on the alkyl chain or on the nitrogen if the locant is ‘N’.

If the amide contains a chiral center, the absolute configuration, R or S, is shown at the start, along with its locant.

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Answer 5

Chapter F, Problem F.19P

Interpretation Introduction

(a)

Interpretation:

The structure of 5-phenylpentanamide is to be drawn.

Concept introduction:

The structure of an amide can be drawn on the basis of its IUPAC name. The name consists of a root name indicating the longest continuous carbon chain that includes the carbonyl carbon of the amide group. Any prefixes present indicate the substituents on the alkyl chain or on the nitrogen if the locant is ‘N’.

If the amide contains a chiral center, the absolute configuration, R or S, is shown at the start, along with its locant.

Interpretation Introduction

(b)

Interpretation:

The structure of (2S, 3S)-2, 3-dimethoxyhexanediamide is to be drawn.

Concept introduction:

The structure of an amide can be drawn on the basis of its IUPAC name. The name consists of a root name indicating the longest continuous carbon chain that includes the carbonyl carbon of the amide group. Any prefixes present indicate the substituents on the alkyl chain or on the nitrogen if the locant is ‘N’.

If the amide contains a chiral center, the absolute configuration, R or S, is shown at the start, along with its locant.

Interpretation Introduction

(c)

Interpretation:

The structure of N-phenylcyclobutanecarboxamide is to be drawn.

Concept introduction:

The structure of an amide can be drawn on the basis of its IUPAC name. The name consists of a root name indicating the longest continuous carbon chain that includes the carbonyl carbon of the amide group. Any prefixes present indicate the substituents on the alkyl chain or on the nitrogen if the locant is ‘N’.

If the amide contains a chiral center, the absolute configuration, R or S, is shown at the start, along with its locant.

Answer 6

Chapter F, Problem F.19P

Interpretation Introduction

(a)

Interpretation:

The structure of 5-phenylpentanamide is to be drawn.

Concept introduction:

The structure of an amide can be drawn on the basis of its IUPAC name. The name consists of a root name indicating the longest continuous carbon chain that includes the carbonyl carbon of the amide group. Any prefixes present indicate the substituents on the alkyl chain or on the nitrogen if the locant is ‘N’.

If the amide contains a chiral center, the absolute configuration, R or S, is shown at the start, along with its locant.

Answer 7

Chapter F, Problem F.19P

Interpretation Introduction

(a)

Interpretation:

The structure of 5-phenylpentanamide is to be drawn.

Concept introduction:

The structure of an amide can be drawn on the basis of its IUPAC name. The name consists of a root name indicating the longest continuous carbon chain that includes the carbonyl carbon of the amide group. Any prefixes present indicate the substituents on the alkyl chain or on the nitrogen if the locant is ‘N’.

If the amide contains a chiral center, the absolute configuration, R or S, is shown at the start, along with its locant.

Answer 8

Interpretation Introduction

(b)

Interpretation:

The structure of (2S, 3S)-2, 3-dimethoxyhexanediamide is to be drawn.

Concept introduction:

The structure of an amide can be drawn on the basis of its IUPAC name. The name consists of a root name indicating the longest continuous carbon chain that includes the carbonyl carbon of the amide group. Any prefixes present indicate the substituents on the alkyl chain or on the nitrogen if the locant is ‘N’.

If the amide contains a chiral center, the absolute configuration, R or S, is shown at the start, along with its locant.

Answer 9

Interpretation Introduction

(b)

Interpretation:

The structure of (2S, 3S)-2, 3-dimethoxyhexanediamide is to be drawn.

Concept introduction:

The structure of an amide can be drawn on the basis of its IUPAC name. The name consists of a root name indicating the longest continuous carbon chain that includes the carbonyl carbon of the amide group. Any prefixes present indicate the substituents on the alkyl chain or on the nitrogen if the locant is ‘N’.

If the amide contains a chiral center, the absolute configuration, R or S, is shown at the start, along with its locant.

Answer 10

Interpretation Introduction

(c)

Interpretation:

The structure of N-phenylcyclobutanecarboxamide is to be drawn.

Concept introduction:

The structure of an amide can be drawn on the basis of its IUPAC name. The name consists of a root name indicating the longest continuous carbon chain that includes the carbonyl carbon of the amide group. Any prefixes present indicate the substituents on the alkyl chain or on the nitrogen if the locant is ‘N’.

If the amide contains a chiral center, the absolute configuration, R or S, is shown at the start, along with its locant.

Answer 11

Interpretation Introduction

(c)

Interpretation:

The structure of N-phenylcyclobutanecarboxamide is to be drawn.

Concept introduction:

The structure of an amide can be drawn on the basis of its IUPAC name. The name consists of a root name indicating the longest continuous carbon chain that includes the carbonyl carbon of the amide group. Any prefixes present indicate the substituents on the alkyl chain or on the nitrogen if the locant is ‘N’.

If the amide contains a chiral center, the absolute configuration, R or S, is shown at the start, along with its locant.

Answer 12

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Answer 13

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Answer 14

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Answer 15

Ch. F - Prob. F.1P Ch. F - Prob. F.2P Ch. F - Prob. F.3P Ch. F - Prob. F.4P Ch. F - Prob. F.5P Ch. F - Prob. F.6P Ch. F - Prob. F.7P Ch. F - Prob. F.8P Ch. F - Prob. F.9P Ch. F - Prob. F.10P

Solution Summary: The structure of 5-phenylpentanamide is to be drawn on the basis of its IUPAC name.

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Chapter F Solutions