(a) Interpretation: Each asymmetric carbon in the given molecule is to be assigned R or S configuration. Concept introduction: The four groups attached to an asymmetric carbon are assigned priorities on the basis of the atomic number of the atom that is directly attached. In the case of a tie, the atoms one bond away are compared. If the priority groups 1 to 3 are arranged clockwise with the lowest priority group at the back, the asymmetric carbon is assigned an R configuration. If they are arranged counterclockwise, the configuration is S. When writing the IUPAC name of a molecule, each R and S designation can be written immediately before the first number used to locate the substituent attached to the asymmetric carbon atom. An alternate way is to write all the R and S designations together at the front of the name. The locator number for each asymmetric carbon atom must appear before its R or S designation and the designations must be separated from each other by a comma.

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Answer 1

Question

Chapter C, Problem C.20P

Interpretation Introduction

(a)

Interpretation:

Each asymmetric carbon in the given molecule is to be assigned R or S configuration.

Concept introduction:

The four groups attached to an asymmetric carbon are assigned priorities on the basis of the atomic number of the atom that is directly attached. In the case of a tie, the atoms one bond away are compared. If the priority groups 1 to 3 are arranged clockwise with the lowest priority group at the back, the asymmetric carbon is assigned an R configuration. If they are arranged counterclockwise, the configuration is S.

When writing the IUPAC name of a molecule, each R and S designation can be written immediately before the first number used to locate the substituent attached to the asymmetric carbon atom. An alternate way is to write all the R and S designations together at the front of the name. The locator number for each asymmetric carbon atom must appear before its R or S designation and the designations must be separated from each other by a comma.

Interpretation Introduction

(b)

Interpretation:

Each asymmetric carbon in the given molecule is to be assigned R or S configuration.

Concept introduction:

The four groups attached to an asymmetric carbon are assigned priorities on the basis of the atomic number of the atom that is directly attached. In the case of a tie, the atoms one bond away are compared. If the priority groups 1 to 3 are arranged clockwise with the lowest priority group at the back, the asymmetric carbon is assigned an R configuration. If they are arranged counterclockwise, the configuration is S.

When writing the IUPAC name of a molecule, each R and S designation can be written immediately before the first number used to locate the substituent attached to the asymmetric carbon atom. An alternate way is to write all the R and S designations together at the front of the name. The locator number for each asymmetric carbon atom must appear before its R or S designation and the designations must be separated from each other by a comma.

Interpretation Introduction

(c)

Interpretation:

Each asymmetric carbon in the given molecule is to be assigned R or S configuration.

Concept introduction:

The four groups attached to an asymmetric carbon are assigned priorities on the basis of the atomic number of the atom that is directly attached. In the case of a tie, the atoms one bond away are compared. If the priority groups 1 to 3 are arranged clockwise with the lowest priority group at the back, the asymmetric carbon is assigned an R configuration. If they are arranged counterclockwise, the configuration is S.

When writing the IUPAC name of a molecule, each R and S designation can be written immediately before the first number used to locate the substituent attached to the asymmetric carbon atom. An alternate way is to write all the R and S designations together at the front of the name. The locator number for each asymmetric carbon atom must appear before its R or S designation and the designations must be separated from each other by a comma.

Interpretation Introduction

(d)

Interpretation:

Each asymmetric carbon in the given molecule is to be assigned R or S configuration.

Concept introduction:

The four groups attached to an asymmetric carbon are assigned priorities on the basis of the atomic number of the atom that is directly attached. In the case of a tie, the atoms one bond away are compared. If the priority groups 1 to 3 are arranged clockwise with the lowest priority group at the back, the asymmetric carbon is assigned an R configuration. If they are arranged counterclockwise, the configuration is S.

When writing the IUPAC name of a molecule, each R and S designation can be written immediately before the first number used to locate the substituent attached to the asymmetric carbon atom. An alternate way is to write all the R and S designations together at the front of the name. The locator number for each asymmetric carbon atom must appear before its R or S designation and the designations must be separated from each other by a comma.

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For the decomposition reaction of N2O5(g): 2 N2O5(g) → 4 NO2(g) + O2(g), the following mechanism has been proposed: N2O5 NO2 + NO3 (K1) | NO2 + NO3 → N2O5 (k-1) | NO2 + NO3 NO2 + O2 + NO (k2) | NO + N2O51 NO2 + NO2 + NO2 (K3) → Give the expression for the acceptable rate. → → (A). d[N205] dt == 2k,k₂[N₂O₂] k₁+k₁₂ (B). d[N2O5] =-k₁[N₂O] + k₁[NO₂] [NO3] - k₂[NO₂]³ dt (C). d[N2O5] =-k₁[N₂O] + k [NO] - k₂[NO] [NO] d[N2O5] (D). = dt = -k₁[N2O5] - k¸[NO][N₂05] dt Do not apply the calculations, based on the approximation of the stationary state, to make them perform correctly. Basta discard the 3 responses that you encounter that are obviously erroneous if you apply the formula to determine the speed of a reaction.

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Answer 2

Question

Chapter C, Problem C.20P

Interpretation Introduction

(a)

Interpretation:

Each asymmetric carbon in the given molecule is to be assigned R or S configuration.

Concept introduction:

The four groups attached to an asymmetric carbon are assigned priorities on the basis of the atomic number of the atom that is directly attached. In the case of a tie, the atoms one bond away are compared. If the priority groups 1 to 3 are arranged clockwise with the lowest priority group at the back, the asymmetric carbon is assigned an R configuration. If they are arranged counterclockwise, the configuration is S.

When writing the IUPAC name of a molecule, each R and S designation can be written immediately before the first number used to locate the substituent attached to the asymmetric carbon atom. An alternate way is to write all the R and S designations together at the front of the name. The locator number for each asymmetric carbon atom must appear before its R or S designation and the designations must be separated from each other by a comma.

Interpretation Introduction

(b)

Interpretation:

Each asymmetric carbon in the given molecule is to be assigned R or S configuration.

Concept introduction:

The four groups attached to an asymmetric carbon are assigned priorities on the basis of the atomic number of the atom that is directly attached. In the case of a tie, the atoms one bond away are compared. If the priority groups 1 to 3 are arranged clockwise with the lowest priority group at the back, the asymmetric carbon is assigned an R configuration. If they are arranged counterclockwise, the configuration is S.

When writing the IUPAC name of a molecule, each R and S designation can be written immediately before the first number used to locate the substituent attached to the asymmetric carbon atom. An alternate way is to write all the R and S designations together at the front of the name. The locator number for each asymmetric carbon atom must appear before its R or S designation and the designations must be separated from each other by a comma.

Interpretation Introduction

(c)

Interpretation:

Each asymmetric carbon in the given molecule is to be assigned R or S configuration.

Concept introduction:

The four groups attached to an asymmetric carbon are assigned priorities on the basis of the atomic number of the atom that is directly attached. In the case of a tie, the atoms one bond away are compared. If the priority groups 1 to 3 are arranged clockwise with the lowest priority group at the back, the asymmetric carbon is assigned an R configuration. If they are arranged counterclockwise, the configuration is S.

When writing the IUPAC name of a molecule, each R and S designation can be written immediately before the first number used to locate the substituent attached to the asymmetric carbon atom. An alternate way is to write all the R and S designations together at the front of the name. The locator number for each asymmetric carbon atom must appear before its R or S designation and the designations must be separated from each other by a comma.

Interpretation Introduction

(d)

Interpretation:

Each asymmetric carbon in the given molecule is to be assigned R or S configuration.

Concept introduction:

The four groups attached to an asymmetric carbon are assigned priorities on the basis of the atomic number of the atom that is directly attached. In the case of a tie, the atoms one bond away are compared. If the priority groups 1 to 3 are arranged clockwise with the lowest priority group at the back, the asymmetric carbon is assigned an R configuration. If they are arranged counterclockwise, the configuration is S.

When writing the IUPAC name of a molecule, each R and S designation can be written immediately before the first number used to locate the substituent attached to the asymmetric carbon atom. An alternate way is to write all the R and S designations together at the front of the name. The locator number for each asymmetric carbon atom must appear before its R or S designation and the designations must be separated from each other by a comma.

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Answer 3

Question

Chapter C, Problem C.20P

Interpretation Introduction

(a)

Interpretation:

Each asymmetric carbon in the given molecule is to be assigned R or S configuration.

Concept introduction:

The four groups attached to an asymmetric carbon are assigned priorities on the basis of the atomic number of the atom that is directly attached. In the case of a tie, the atoms one bond away are compared. If the priority groups 1 to 3 are arranged clockwise with the lowest priority group at the back, the asymmetric carbon is assigned an R configuration. If they are arranged counterclockwise, the configuration is S.

When writing the IUPAC name of a molecule, each R and S designation can be written immediately before the first number used to locate the substituent attached to the asymmetric carbon atom. An alternate way is to write all the R and S designations together at the front of the name. The locator number for each asymmetric carbon atom must appear before its R or S designation and the designations must be separated from each other by a comma.

Interpretation Introduction

(b)

Interpretation:

Each asymmetric carbon in the given molecule is to be assigned R or S configuration.

Concept introduction:

The four groups attached to an asymmetric carbon are assigned priorities on the basis of the atomic number of the atom that is directly attached. In the case of a tie, the atoms one bond away are compared. If the priority groups 1 to 3 are arranged clockwise with the lowest priority group at the back, the asymmetric carbon is assigned an R configuration. If they are arranged counterclockwise, the configuration is S.

When writing the IUPAC name of a molecule, each R and S designation can be written immediately before the first number used to locate the substituent attached to the asymmetric carbon atom. An alternate way is to write all the R and S designations together at the front of the name. The locator number for each asymmetric carbon atom must appear before its R or S designation and the designations must be separated from each other by a comma.

Interpretation Introduction

(c)

Interpretation:

Each asymmetric carbon in the given molecule is to be assigned R or S configuration.

Concept introduction:

The four groups attached to an asymmetric carbon are assigned priorities on the basis of the atomic number of the atom that is directly attached. In the case of a tie, the atoms one bond away are compared. If the priority groups 1 to 3 are arranged clockwise with the lowest priority group at the back, the asymmetric carbon is assigned an R configuration. If they are arranged counterclockwise, the configuration is S.

When writing the IUPAC name of a molecule, each R and S designation can be written immediately before the first number used to locate the substituent attached to the asymmetric carbon atom. An alternate way is to write all the R and S designations together at the front of the name. The locator number for each asymmetric carbon atom must appear before its R or S designation and the designations must be separated from each other by a comma.

Interpretation Introduction

(d)

Interpretation:

Each asymmetric carbon in the given molecule is to be assigned R or S configuration.

Concept introduction:

The four groups attached to an asymmetric carbon are assigned priorities on the basis of the atomic number of the atom that is directly attached. In the case of a tie, the atoms one bond away are compared. If the priority groups 1 to 3 are arranged clockwise with the lowest priority group at the back, the asymmetric carbon is assigned an R configuration. If they are arranged counterclockwise, the configuration is S.

When writing the IUPAC name of a molecule, each R and S designation can be written immediately before the first number used to locate the substituent attached to the asymmetric carbon atom. An alternate way is to write all the R and S designations together at the front of the name. The locator number for each asymmetric carbon atom must appear before its R or S designation and the designations must be separated from each other by a comma.

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Answer 4

Question

Chapter C, Problem C.20P

Interpretation Introduction

(a)

Interpretation:

Each asymmetric carbon in the given molecule is to be assigned R or S configuration.

Concept introduction:

The four groups attached to an asymmetric carbon are assigned priorities on the basis of the atomic number of the atom that is directly attached. In the case of a tie, the atoms one bond away are compared. If the priority groups 1 to 3 are arranged clockwise with the lowest priority group at the back, the asymmetric carbon is assigned an R configuration. If they are arranged counterclockwise, the configuration is S.

When writing the IUPAC name of a molecule, each R and S designation can be written immediately before the first number used to locate the substituent attached to the asymmetric carbon atom. An alternate way is to write all the R and S designations together at the front of the name. The locator number for each asymmetric carbon atom must appear before its R or S designation and the designations must be separated from each other by a comma.

Interpretation Introduction

(b)

Interpretation:

Each asymmetric carbon in the given molecule is to be assigned R or S configuration.

Concept introduction:

The four groups attached to an asymmetric carbon are assigned priorities on the basis of the atomic number of the atom that is directly attached. In the case of a tie, the atoms one bond away are compared. If the priority groups 1 to 3 are arranged clockwise with the lowest priority group at the back, the asymmetric carbon is assigned an R configuration. If they are arranged counterclockwise, the configuration is S.

When writing the IUPAC name of a molecule, each R and S designation can be written immediately before the first number used to locate the substituent attached to the asymmetric carbon atom. An alternate way is to write all the R and S designations together at the front of the name. The locator number for each asymmetric carbon atom must appear before its R or S designation and the designations must be separated from each other by a comma.

Interpretation Introduction

(c)

Interpretation:

Each asymmetric carbon in the given molecule is to be assigned R or S configuration.

Concept introduction:

The four groups attached to an asymmetric carbon are assigned priorities on the basis of the atomic number of the atom that is directly attached. In the case of a tie, the atoms one bond away are compared. If the priority groups 1 to 3 are arranged clockwise with the lowest priority group at the back, the asymmetric carbon is assigned an R configuration. If they are arranged counterclockwise, the configuration is S.

When writing the IUPAC name of a molecule, each R and S designation can be written immediately before the first number used to locate the substituent attached to the asymmetric carbon atom. An alternate way is to write all the R and S designations together at the front of the name. The locator number for each asymmetric carbon atom must appear before its R or S designation and the designations must be separated from each other by a comma.

Interpretation Introduction

(d)

Interpretation:

Each asymmetric carbon in the given molecule is to be assigned R or S configuration.

Concept introduction:

The four groups attached to an asymmetric carbon are assigned priorities on the basis of the atomic number of the atom that is directly attached. In the case of a tie, the atoms one bond away are compared. If the priority groups 1 to 3 are arranged clockwise with the lowest priority group at the back, the asymmetric carbon is assigned an R configuration. If they are arranged counterclockwise, the configuration is S.

When writing the IUPAC name of a molecule, each R and S designation can be written immediately before the first number used to locate the substituent attached to the asymmetric carbon atom. An alternate way is to write all the R and S designations together at the front of the name. The locator number for each asymmetric carbon atom must appear before its R or S designation and the designations must be separated from each other by a comma.

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Answer 5

Chapter C, Problem C.20P

Interpretation Introduction

(a)

Interpretation:

Each asymmetric carbon in the given molecule is to be assigned R or S configuration.

Concept introduction:

The four groups attached to an asymmetric carbon are assigned priorities on the basis of the atomic number of the atom that is directly attached. In the case of a tie, the atoms one bond away are compared. If the priority groups 1 to 3 are arranged clockwise with the lowest priority group at the back, the asymmetric carbon is assigned an R configuration. If they are arranged counterclockwise, the configuration is S.

When writing the IUPAC name of a molecule, each R and S designation can be written immediately before the first number used to locate the substituent attached to the asymmetric carbon atom. An alternate way is to write all the R and S designations together at the front of the name. The locator number for each asymmetric carbon atom must appear before its R or S designation and the designations must be separated from each other by a comma.

Interpretation Introduction

(b)

Interpretation:

Each asymmetric carbon in the given molecule is to be assigned R or S configuration.

Concept introduction:

The four groups attached to an asymmetric carbon are assigned priorities on the basis of the atomic number of the atom that is directly attached. In the case of a tie, the atoms one bond away are compared. If the priority groups 1 to 3 are arranged clockwise with the lowest priority group at the back, the asymmetric carbon is assigned an R configuration. If they are arranged counterclockwise, the configuration is S.

When writing the IUPAC name of a molecule, each R and S designation can be written immediately before the first number used to locate the substituent attached to the asymmetric carbon atom. An alternate way is to write all the R and S designations together at the front of the name. The locator number for each asymmetric carbon atom must appear before its R or S designation and the designations must be separated from each other by a comma.

Interpretation Introduction

(c)

Interpretation:

Each asymmetric carbon in the given molecule is to be assigned R or S configuration.

Concept introduction:

The four groups attached to an asymmetric carbon are assigned priorities on the basis of the atomic number of the atom that is directly attached. In the case of a tie, the atoms one bond away are compared. If the priority groups 1 to 3 are arranged clockwise with the lowest priority group at the back, the asymmetric carbon is assigned an R configuration. If they are arranged counterclockwise, the configuration is S.

When writing the IUPAC name of a molecule, each R and S designation can be written immediately before the first number used to locate the substituent attached to the asymmetric carbon atom. An alternate way is to write all the R and S designations together at the front of the name. The locator number for each asymmetric carbon atom must appear before its R or S designation and the designations must be separated from each other by a comma.

Interpretation Introduction

(d)

Interpretation:

Each asymmetric carbon in the given molecule is to be assigned R or S configuration.

Concept introduction:

The four groups attached to an asymmetric carbon are assigned priorities on the basis of the atomic number of the atom that is directly attached. In the case of a tie, the atoms one bond away are compared. If the priority groups 1 to 3 are arranged clockwise with the lowest priority group at the back, the asymmetric carbon is assigned an R configuration. If they are arranged counterclockwise, the configuration is S.

When writing the IUPAC name of a molecule, each R and S designation can be written immediately before the first number used to locate the substituent attached to the asymmetric carbon atom. An alternate way is to write all the R and S designations together at the front of the name. The locator number for each asymmetric carbon atom must appear before its R or S designation and the designations must be separated from each other by a comma.

Answer 6

Chapter C, Problem C.20P

Interpretation Introduction

(a)

Interpretation:

Each asymmetric carbon in the given molecule is to be assigned R or S configuration.

Concept introduction:

The four groups attached to an asymmetric carbon are assigned priorities on the basis of the atomic number of the atom that is directly attached. In the case of a tie, the atoms one bond away are compared. If the priority groups 1 to 3 are arranged clockwise with the lowest priority group at the back, the asymmetric carbon is assigned an R configuration. If they are arranged counterclockwise, the configuration is S.

When writing the IUPAC name of a molecule, each R and S designation can be written immediately before the first number used to locate the substituent attached to the asymmetric carbon atom. An alternate way is to write all the R and S designations together at the front of the name. The locator number for each asymmetric carbon atom must appear before its R or S designation and the designations must be separated from each other by a comma.

Answer 7

Chapter C, Problem C.20P

Interpretation Introduction

(a)

Interpretation:

Each asymmetric carbon in the given molecule is to be assigned R or S configuration.

Concept introduction:

The four groups attached to an asymmetric carbon are assigned priorities on the basis of the atomic number of the atom that is directly attached. In the case of a tie, the atoms one bond away are compared. If the priority groups 1 to 3 are arranged clockwise with the lowest priority group at the back, the asymmetric carbon is assigned an R configuration. If they are arranged counterclockwise, the configuration is S.

When writing the IUPAC name of a molecule, each R and S designation can be written immediately before the first number used to locate the substituent attached to the asymmetric carbon atom. An alternate way is to write all the R and S designations together at the front of the name. The locator number for each asymmetric carbon atom must appear before its R or S designation and the designations must be separated from each other by a comma.

Answer 8

Interpretation Introduction

(b)

Interpretation:

Each asymmetric carbon in the given molecule is to be assigned R or S configuration.

Concept introduction:

The four groups attached to an asymmetric carbon are assigned priorities on the basis of the atomic number of the atom that is directly attached. In the case of a tie, the atoms one bond away are compared. If the priority groups 1 to 3 are arranged clockwise with the lowest priority group at the back, the asymmetric carbon is assigned an R configuration. If they are arranged counterclockwise, the configuration is S.

When writing the IUPAC name of a molecule, each R and S designation can be written immediately before the first number used to locate the substituent attached to the asymmetric carbon atom. An alternate way is to write all the R and S designations together at the front of the name. The locator number for each asymmetric carbon atom must appear before its R or S designation and the designations must be separated from each other by a comma.

Answer 9

Interpretation Introduction

(b)

Interpretation:

Each asymmetric carbon in the given molecule is to be assigned R or S configuration.

Concept introduction:

The four groups attached to an asymmetric carbon are assigned priorities on the basis of the atomic number of the atom that is directly attached. In the case of a tie, the atoms one bond away are compared. If the priority groups 1 to 3 are arranged clockwise with the lowest priority group at the back, the asymmetric carbon is assigned an R configuration. If they are arranged counterclockwise, the configuration is S.

When writing the IUPAC name of a molecule, each R and S designation can be written immediately before the first number used to locate the substituent attached to the asymmetric carbon atom. An alternate way is to write all the R and S designations together at the front of the name. The locator number for each asymmetric carbon atom must appear before its R or S designation and the designations must be separated from each other by a comma.

Answer 10

Interpretation Introduction

(c)

Interpretation:

Each asymmetric carbon in the given molecule is to be assigned R or S configuration.

Concept introduction:

The four groups attached to an asymmetric carbon are assigned priorities on the basis of the atomic number of the atom that is directly attached. In the case of a tie, the atoms one bond away are compared. If the priority groups 1 to 3 are arranged clockwise with the lowest priority group at the back, the asymmetric carbon is assigned an R configuration. If they are arranged counterclockwise, the configuration is S.

When writing the IUPAC name of a molecule, each R and S designation can be written immediately before the first number used to locate the substituent attached to the asymmetric carbon atom. An alternate way is to write all the R and S designations together at the front of the name. The locator number for each asymmetric carbon atom must appear before its R or S designation and the designations must be separated from each other by a comma.

Answer 11

Interpretation Introduction

(c)

Interpretation:

Each asymmetric carbon in the given molecule is to be assigned R or S configuration.

Concept introduction:

The four groups attached to an asymmetric carbon are assigned priorities on the basis of the atomic number of the atom that is directly attached. In the case of a tie, the atoms one bond away are compared. If the priority groups 1 to 3 are arranged clockwise with the lowest priority group at the back, the asymmetric carbon is assigned an R configuration. If they are arranged counterclockwise, the configuration is S.

When writing the IUPAC name of a molecule, each R and S designation can be written immediately before the first number used to locate the substituent attached to the asymmetric carbon atom. An alternate way is to write all the R and S designations together at the front of the name. The locator number for each asymmetric carbon atom must appear before its R or S designation and the designations must be separated from each other by a comma.

Answer 12

Interpretation Introduction

(d)

Interpretation:

Each asymmetric carbon in the given molecule is to be assigned R or S configuration.

Concept introduction:

The four groups attached to an asymmetric carbon are assigned priorities on the basis of the atomic number of the atom that is directly attached. In the case of a tie, the atoms one bond away are compared. If the priority groups 1 to 3 are arranged clockwise with the lowest priority group at the back, the asymmetric carbon is assigned an R configuration. If they are arranged counterclockwise, the configuration is S.

When writing the IUPAC name of a molecule, each R and S designation can be written immediately before the first number used to locate the substituent attached to the asymmetric carbon atom. An alternate way is to write all the R and S designations together at the front of the name. The locator number for each asymmetric carbon atom must appear before its R or S designation and the designations must be separated from each other by a comma.

Answer 13

Interpretation Introduction

(d)

Interpretation:

Each asymmetric carbon in the given molecule is to be assigned R or S configuration.

Concept introduction:

The four groups attached to an asymmetric carbon are assigned priorities on the basis of the atomic number of the atom that is directly attached. In the case of a tie, the atoms one bond away are compared. If the priority groups 1 to 3 are arranged clockwise with the lowest priority group at the back, the asymmetric carbon is assigned an R configuration. If they are arranged counterclockwise, the configuration is S.

When writing the IUPAC name of a molecule, each R and S designation can be written immediately before the first number used to locate the substituent attached to the asymmetric carbon atom. An alternate way is to write all the R and S designations together at the front of the name. The locator number for each asymmetric carbon atom must appear before its R or S designation and the designations must be separated from each other by a comma.

Answer 14

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Answer 15

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Answer 16

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Answer 17

Ch. C - Prob. C.1P Ch. C - Prob. C.2P Ch. C - Prob. C.3P Ch. C - Prob. C.4P Ch. C - Prob. C.5P Ch. C - Prob. C.6P Ch. C - Prob. C.7P Ch. C - Prob. C.8P Ch. C - Prob. C.9P Ch. C - Prob. C.10P

Solution Summary: The author explains that each asymmetric carbon in the given molecule is assigned R or S configuration. Priorities are assigned on the basis of atomic numbers of the atoms directly attached.

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