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(a)
Interpretation:
The structure for each of the given name is to be drawn.
Concept introduction:
In case of rings containing seven or less than seven carbon atoms, the Z/E configuration is usually omitted for double bonds which are a part of the ring. The E configuration about the double bond is not stable due to ring strain. It is understood that the double bonded carbon atoms have a configuration such that they are cis to each other. In case of rings consisting of more than seven carbon atoms, the double bond, which is a part of the ring, can have E or Z configuration.
If the higher priority groups, attached to the double bonded carbon atoms, are on the same side of the double bond, the
(b)
Interpretation:
The structure for each of the given name is to be drawn.
Concept introduction:
In case of rings containing seven or less than seven carbon atoms, the Z/E configuration is usually omitted for the double bonds which are a part of the ring. The E configuration about the double bond is not stable due to ring strain. It is understood that the double bonded carbon atoms have a configuration such that they are cis to each other. In case of rings consisting of more than seven carbon atoms, the double bond, which is a part of the ring, can have E or Z configuration.
If the higher priority groups, attached to the double bonded carbon atoms, are on the same side of the double bond, the alkene is assigned Z configuration. If the higher priority groups, attached to the double bonded carbon atoms, are on the opposite side of the double bond, the alkene is assigned E configuration.
(c)
Interpretation:
The structure for each of the given name is to be drawn.
Concept introduction:
In case of rings containing seven or less than seven carbon atoms, the Z/E configuration is usually omitted for the double bonds which are a part of the ring. The E configuration about the double bond is not stable due to ring strain. It is understood that the double bonded carbon atoms have a configuration such that they are cis to each other. In case of rings consisting of more than seven carbon atoms, the double bond which is a part of the ring can have E or Z configuration.
If the higher priority groups, attached to the double bonded carbon atoms, are on the same side of the double bond, the alkene is assigned Z configuration. If the higher priority groups, attached to the double bonded carbon atoms, are on the opposite side of the double bond, the alkene is assigned E configuration.
(d)
Interpretation:
The structure for each of the given name is to be drawn.
Concept introduction:
In case of rings containing seven or less than seven carbon atoms, the Z/E configuration is usually omitted for the double bonds which are a part of the ring. The E configuration about the double bond is not stable due to ring strain. It is understood that the double bonded carbon atoms have a configuration such that they are cis to each other. In case of rings consisting of more than seven carbon atoms, the double bond which is a part of the ring can have E or Z configuration.
If the higher priority groups, attached to the double bonded carbon atoms, are on the same side of the double bond, the alkene is assigned Z configuration. If the higher priority groups, attached to the double bonded carbon atoms, are on the opposite side of the double bond, the alkene is assigned E configuration.
(e)
Interpretation:
The structure for the given name is to be drawn.
Concept introduction:
In case of rings containing seven or less than seven carbon atoms, the Z/E configuration is usually omitted for the double bonds which are a part of the ring. The E configuration about the double bond is not stable due to ring strain. It is understood that the double bonded carbon atoms have a configuration such that they are cis to each other. In case of rings consisting of more than seven carbon atoms, the double bond which is a part of the ring can have E or Z configuration.
If the higher priority groups, attached to the double bonded carbon atoms, are on the same side of the double bond, the alkene is assigned Z configuration. If the higher priority groups, attached to the double bonded carbon atoms, are on the opposite side of the double bond, the alkene is assigned E configuration.
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Chapter C Solutions
Organic Chemistry: Principles And Mechanisms
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