Chemistry In Context
9th Edition
ISBN: 9781259638145
Author: Fahlman, Bradley D., Purvis-roberts, Kathleen, Kirk, John S., Bentley, Anne K., Daubenmire, Patrick L., ELLIS, Jamie P., Mury, Michael T., American Chemical Society
Publisher: Mcgraw-hill Education,
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Chapter 9.9, Problem 9.24YT
Examine the values in Table 9.4 from the American Chemistry Council (ACC).
- a. Are these values comparable to those quoted by the EPA in Your Turn 9.20? Assume that the tons quoted were short tons; that is. 2,000 pounds per ton.
- b. The EPA reported the amounts recycled using one unit (million tons), and the ACC reported in another (million pounds). Several explanations are possible. Propose one.
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Consider the reaction below to answer the following questions:
Acetoacetic ester can be prepared by the Claisen self-condensation reaction of ethyl acetate.
1. NaOEt, EtOH
H&C
OCH CH3 2 H30
H3C
CH2
OCH2CH3
A. Write the complete stepwise mechanism for this reaction. Show all electron flow with arrows and
draw all intermediate structures.
B. Ethyl acetate can be prepared from ethanol as the only organic starting material. Show all reagents
and structures for all intermediates in this preparation.
C. Give the structures of the ester precursors for the following Claisen condensation product and
formulate the reaction.
OEt
Use the phase diagram of Substance X below to find the temperature at which X turns to a gas, if the pressure above the solid is 3.7 atm.
pressure (atm)
32
16
solid
liquid
gas
0
0
200
temperature (K)
Note: your answer must be within 20 °C of the exact answer to be graded correct.
Шос
☑
ك
Starting from bromoethane, how could you prepare the following compounds:
a. Ethanol.
b. Acetaldehyde
f. Acetone.
e. 2-Propanol
i. Acetoacetic ester.
d. 2-Bromoacetic acid.
c. Acetic acid
g. Acetamide.
j. Ethylmalonate
k. Gama ketoacid.
h. Ethyl magnesium bromide.
Chapter 9 Solutions
Chemistry In Context
Ch. 9.1 - Scientific Practices Tennis Anyone? Examine this...Ch. 9.3 - Prob. 9.2YTCh. 9.3 - Prob. 9.3YTCh. 9.4 - Prob. 9.4YTCh. 9.4 - Prob. 9.5YTCh. 9.4 - Prob. 9.6YTCh. 9.4 - Prob. 9.7YTCh. 9.4 - Prob. 9.8YTCh. 9.4 - Prob. 9.9YTCh. 9.5 - Prob. 9.10YT
Ch. 9.5 - Skill Building Benzene and Phenyl The difference...Ch. 9.5 - Prob. 9.13YTCh. 9.5 - Skill Building Polystyrene Possibilities Show the...Ch. 9.6 - Skill Building Esters and Polyesters You have seen...Ch. 9.6 - Prob. 9.16YTCh. 9.7 - Skill Building Kevlar Kevlar is a polyamide used...Ch. 9.8 - Prob. 9.20YTCh. 9.8 - Your Turn 9.22 Skill Building Burning a Plastic...Ch. 9.8 - Your Turn 9.23 Scientific Practices Landfill...Ch. 9.9 - Examine the values in Table 9.4 from the American...Ch. 9.9 - Prob. 9.25YTCh. 9.9 - Prob. 9.26YTCh. 9.9 - Prob. 9.28YTCh. 9.10 - Skill Building The Chemistry of PLA We dont show...Ch. 9.11 - Your Turn 9.31 Scientific Practices Glass or...Ch. 9.11 - Prob. 9.32YTCh. 9.11 - Skill Building Meet DEHP DEHP belongs to a common...Ch. 9 - Prob. 1QCh. 9 - Prob. 2QCh. 9 - Prob. 3QCh. 9 - Prob. 4QCh. 9 - Prob. 5QCh. 9 - Prob. 6QCh. 9 - Prob. 7QCh. 9 - Prob. 8QCh. 9 - Prob. 9QCh. 9 - Prob. 10QCh. 9 - Prob. 11QCh. 9 - Prob. 12QCh. 9 - Prob. 13QCh. 9 - Prob. 14QCh. 9 - Prob. 15QCh. 9 - Prob. 16QCh. 9 - Prob. 17QCh. 9 - Prob. 18QCh. 9 - Prob. 19QCh. 9 - Prob. 20QCh. 9 - Prob. 21QCh. 9 - Prob. 22QCh. 9 - Prob. 23QCh. 9 - Prob. 24QCh. 9 - Prob. 25QCh. 9 - Prob. 26QCh. 9 - Prob. 27QCh. 9 - Prob. 28QCh. 9 - Prob. 29QCh. 9 - Prob. 30QCh. 9 - Prob. 31QCh. 9 - Prob. 32QCh. 9 - Prob. 33QCh. 9 - Prob. 34QCh. 9 - Prob. 35QCh. 9 - Prob. 36QCh. 9 - Prob. 37QCh. 9 - Prob. 38QCh. 9 - Prob. 39QCh. 9 - Prob. 40QCh. 9 - Prob. 41QCh. 9 - Prob. 42QCh. 9 - Prob. 43QCh. 9 - Prob. 44QCh. 9 - Prob. 45QCh. 9 - Prob. 46QCh. 9 - Prob. 47QCh. 9 - Prob. 48QCh. 9 - Prob. 49QCh. 9 - Prob. 50QCh. 9 - Prob. 51QCh. 9 - Prob. 52QCh. 9 - Prob. 53QCh. 9 - Prob. 54QCh. 9 - Prob. 55QCh. 9 - Prob. 56QCh. 9 - Prob. 57QCh. 9 - Prob. 58QCh. 9 - Prob. 59Q
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