OWLV2 FOR MOORE/STANITSKI'S CHEMISTRY:
5th Edition
ISBN: 9781285460369
Author: STANITSKI
Publisher: Cengage Learning
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Textbook Question
Chapter 9.9, Problem 9.16CE
Look in Appendix D and compare the electron configurations shown there with the fusion enthalpies for the metals shown in Table 9.7. Is there any correlation between these configurations and this property? Does strength of attraction among metal atoms correlate with number of valence electrons? Explain your answers.
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Use the following data to calculate the lattice energy of cesium oxide. You
must write all thermochemical equations for the steps of the cycle.
Enthalpy of formation of CSO = -233 kJ/mol
Enthalpy of sublimation of Cs = +78 kJ/mol
First ionization energy of Cs = +375 kJ/mol
Enthalpy of dissociation of O₂ (g) = + 494 kJ/mol
First electron affinity of O = - 141 kJ/mol
Second electron affinity of O = + 845 kJ/mol
-750 kJ/mol
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+1690 kJ/mol
O -1045 kJ/mol
Given the following thermodynamic data, calculate the lattice energy of LiCl:ΔH°f[LiCl(s)] = -409 kJ/molΔH°sublimation [Li] = 161 kJ/molBond energy [Cl-Cl] = 243 kJ/molIE1 (Li) = 520 kJ/molEA1 (Cl) = -349 kJ/mol
-1682 kJ/mol
-984 kJ/mol
-1560 kJ/mol
-862 kJ/mol
-1213 kJ/mol
The lattice energy of magnesium sulfide is the energy change accompanying the process
Mg2*(g) +
+ S2-(g) → MgS(s)
Calculate the lattice energy of MgS using the following data:
Mg(s) → Mg(g)
AH° = 148 kJ/mol
Mg(g) → Mg2*(g) + 2e-
AH° = 2186 kJ/mol
Sg(s) → 8S(g)
AH° = 2232 kJ/mol
S(g) + 2e-- s2-(g)
AH° = 450 kJ/mol
8Mg(s) + Sg(s) → 8MGS(s)
AH° = -2744 kJ/mol
Mg2*(g) + S2-(g)→ MgS(s)
AH°lattice
= ?
Chapter 9 Solutions
OWLV2 FOR MOORE/STANITSKI'S CHEMISTRY:
Ch. 9.1 - Prob. 9.1CECh. 9.2 - Prob. 9.2CECh. 9.2 - Prob. 9.1PSPCh. 9.2 - What mass (g) of ethanol, CH3CH2OH(), can be...Ch. 9.3 - Prob. 9.3CECh. 9.3 - Prob. 9.4CECh. 9.3 - Prob. 9.3PSPCh. 9.4 - What types of solids are these substances? (a) The...Ch. 9.4 - Prob. 9.5PSPCh. 9.4 - Prob. 9.5E
Ch. 9.4 - Prob. 9.6CECh. 9.4 - Sublimation is an excellent means of purification...Ch. 9.4 - Prob. 9.6PSPCh. 9.4 - Prob. 9.8ECh. 9.4 - Prob. 9.9ECh. 9.5 - Predict which liquid—glycerol, HOCH2CH(OH)CH2OH,...Ch. 9.5 - Prob. 9.11CECh. 9.6 - Crystalline polonium has a primitive cubic unit...Ch. 9.6 - Calculate the unit cell edge length of copper...Ch. 9.6 - Vanadium metal crystallizes in a body-centered...Ch. 9.6 - Prob. 9.13ECh. 9.6 - Prob. 9.14ECh. 9.6 - Prob. 9.9PSPCh. 9.9 - Prob. 9.10PSPCh. 9.9 - The graph below is obtained when a liquid metal is...Ch. 9.9 - Look in Appendix D and compare the electron...Ch. 9.11 - Prob. 9.11PSPCh. 9 - Prob. ISPCh. 9 - Prob. IISPCh. 9 - Prob. IIISPCh. 9 - Prob. 1QRTCh. 9 - Prob. 2QRTCh. 9 - Prob. 3QRTCh. 9 - Prob. 4QRTCh. 9 - Prob. 5QRTCh. 9 - Prob. 6QRTCh. 9 - Which processes are endothermic? (a) Condensation...Ch. 9 - Prob. 8QRTCh. 9 - Prob. 9QRTCh. 9 - Prob. 10QRTCh. 9 - Prob. 11QRTCh. 9 - Prob. 12QRTCh. 9 - Prob. 13QRTCh. 9 - After exercising on a hot summer day and working...Ch. 9 - Prob. 15QRTCh. 9 - The molar vaporization enthalpy of methanol is...Ch. 9 - Prob. 17QRTCh. 9 - Mercury is highly toxic. Although it is a liquid...Ch. 9 - Prob. 19QRTCh. 9 - Prob. 20QRTCh. 9 - Prob. 21QRTCh. 9 - Prob. 22QRTCh. 9 - Prob. 23QRTCh. 9 - Prob. 24QRTCh. 9 - Prob. 25QRTCh. 9 - Prob. 26QRTCh. 9 - A liquid has a vapH of 38.7 kJ/mol and a boiling...Ch. 9 - Prob. 28QRTCh. 9 - The vapor pressure of ethanol, C2H5OH, at 50.0 C...Ch. 9 - Prob. 30QRTCh. 9 - Prob. 31QRTCh. 9 - Prob. 32QRTCh. 9 - Which would you expect to have the higher fusion...Ch. 9 - Prob. 34QRTCh. 9 - Prob. 35QRTCh. 9 - Prob. 36QRTCh. 9 - Prob. 37QRTCh. 9 - Prob. 38QRTCh. 9 - Prob. 39QRTCh. 9 - Prob. 40QRTCh. 9 - Prob. 41QRTCh. 9 - Prob. 42QRTCh. 9 - Prob. 43QRTCh. 9 - Prob. 44QRTCh. 9 - At the critical point for carbon dioxide, the...Ch. 9 - Prob. 46QRTCh. 9 - Prob. 47QRTCh. 9 - On the basis of the description given, classify...Ch. 9 - On the basis of the description given, classify...Ch. 9 - Prob. 50QRTCh. 9 - Prob. 51QRTCh. 9 - Prob. 52QRTCh. 9 - Prob. 53QRTCh. 9 - Prob. 54QRTCh. 9 - Prob. 55QRTCh. 9 - Prob. 56QRTCh. 9 - Prob. 57QRTCh. 9 - Prob. 58QRTCh. 9 - Prob. 59QRTCh. 9 - Prob. 60QRTCh. 9 - Prob. 61QRTCh. 9 - The ionic radii of Cs+ and Cl are 181 and 167 pm,...Ch. 9 - Prob. 63QRTCh. 9 - Prob. 64QRTCh. 9 - Prob. 65QRTCh. 9 - Tungsten has a body-centered cubic unit cell and...Ch. 9 - Prob. 67QRTCh. 9 - Prob. 68QRTCh. 9 - Prob. 69QRTCh. 9 - Prob. 70QRTCh. 9 - Prob. 71QRTCh. 9 - Prob. 72QRTCh. 9 - Prob. 73QRTCh. 9 - Prob. 74QRTCh. 9 - Prob. 75QRTCh. 9 - Prob. 76QRTCh. 9 - Prob. 77QRTCh. 9 - Prob. 78QRTCh. 9 - Prob. 79QRTCh. 9 - Prob. 80QRTCh. 9 - Which substance has the greatest electrical...Ch. 9 - Prob. 82QRTCh. 9 - Prob. 83QRTCh. 9 - Prob. 84QRTCh. 9 - Prob. 85QRTCh. 9 - Prob. 86QRTCh. 9 - What makes a glass different from a crystalline...Ch. 9 - Prob. 88QRTCh. 9 - Prob. 89QRTCh. 9 - Prob. 90QRTCh. 9 - Will a closed container of water at 70 C or an...Ch. 9 - Prob. 92QRTCh. 9 - Prob. 95QRTCh. 9 - Prob. 96QRTCh. 9 - Prob. 97QRTCh. 9 - Prob. 98QRTCh. 9 - Prob. 99QRTCh. 9 - Prob. 100QRTCh. 9 - Prob. 101QRTCh. 9 - Prob. 102QRTCh. 9 - Prob. 103QRTCh. 9 - Consider this information regarding two compounds....Ch. 9 - Prob. 105QRTCh. 9 - Prob. 106QRTCh. 9 - If you get boiling water at 100 C on your skin, it...Ch. 9 - Prob. 108QRTCh. 9 - The normal boiling point of SO2 is 263.1 K and...Ch. 9 - Butane is a gas at room temperature; however, if...Ch. 9 - Prob. 111QRTCh. 9 - Examine the nanoscale diagrams and the phase...Ch. 9 - Consider the phase diagram and heating-curve...Ch. 9 - Prob. 115QRTCh. 9 - Prob. 116QRTCh. 9 - The phase diagram for water over a relative narrow...Ch. 9 - Prob. 118QRTCh. 9 - Prob. 119QRTCh. 9 - Prob. 120QRTCh. 9 - Prob. 121QRTCh. 9 - Prob. 122QRTCh. 9 - Titanium metal crystallizes in a body-centered...Ch. 9 - Prob. 9.ACPCh. 9 - Prob. 9.BCPCh. 9 - Prob. 9.CCP
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- 1) Write the balanced reaction between magnesium and oxygen to create 1 mole of magnesium oxide. Show the calculation of the theoretical enthalpy of reaction using the heats of formation values from your textbook. Show all your work including all phase labels. Report your answer in kJ/1 mole of magnesium.arrow_forwardDefine valency by taking examples of silicon and sulphur?arrow_forwardCalculate the lattice energy of ionic solid MX, given the following thermodynamic data: M(s) + X2(9) → MX(s) AHræn M(s) → M(g) AHrän= 88. kJ Bond energy of X2 = 196. kJ/mol lonization energy for M(s) = 485. kJ /mol Electron affinity of X = -281. kJ/mol AHrxn = -616. Enter your answer in decimal notation, rounded to the appropriate number of significant figures.arrow_forward
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