Organic Chemistry, Binder Ready Version
Organic Chemistry, Binder Ready Version
2nd Edition
ISBN: 9781118454312
Author: David R. Klein
Publisher: WILEY
Question
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Chapter 9.8, Problem 27PTS

 (a)

Interpretation Introduction

Interpretation:

Major product should be found for the given alkene while adding bromine and water.

Concept introduction:

  • Addition of bromine molecule in presence of water gives the halohydrin formation.
  • Addition of bromine and hydroxide group across the double bond of alkene is known as halohydrin formation.
  • Generally, bromination reactions proceeds through a 3-membered cyclic bromonium intermediate then attack of water molecule at most substituted carbon position of the alkene. 

To find: the major product formed during bromination (in water) for the given alkene.

(b)

Interpretation Introduction

Interpretation:

Major product should be found for the given alkene while adding bromine and water.

Concept introduction:

  • Addition of bromine molecule in presence of water gives the halohydrin formation.
  • Addition of bromine and hydroxide group across the double bond of alkene is known as halohydrin formation.
  • Generally, bromination reactions proceeds through a 3-membered cyclic bromonium intermediate then attack of water molecule at most substituted carbon position of the alkene. 

To find: the major product formed during bromination (in water) for the given alkene.

(c)

Interpretation Introduction

Interpretation:

Major product should be found for the given alkene while adding bromine and water.

Concept introduction:

  • Addition of bromine molecule in presence of water gives the halohydrin formation.
  • Addition of bromine and hydroxide group across the double bond of alkene is known as halohydrin formation.
  • Generally, bromination reactions proceeds through a 3-membered cyclic bromonium intermediate then attack of water molecule at most substituted carbon position of the alkene. 

To find: the major product formed during bromination (in water) for the given alkene.

(d)

Interpretation Introduction

Interpretation:

Major product should be found for the given alkene while adding bromine and water.

Concept introduction:

  • Addition of bromine molecule in presence of water gives the halohydrin formation.
  • Addition of bromine and hydroxide group across the double bond of alkene is known as halohydrin formation.
  • Generally, bromination reactions proceeds through a 3-membered cyclic bromonium intermediate then attack of water molecule at most substituted carbon position of the alkene. 

To find: the major product formed during bromination (in water) for the given alkene.

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6. Consider the following exothermic reaction below. 2Cu2+(aq) +41 (aq)2Cul(s) + 12(aq) a. If Cul is added, there will be a shift left/shift right/no shift (circle one). b. If Cu2+ is added, there will be a shift left/shift right/no shift (circle one). c. If a solution of AgNO3 is added, there will be a shift left/shift right/no shift (circle one). d. If the solvent hexane (C6H14) is added, there will be a shift left/shift right/no shift (circle one). Hint: one of the reaction species is more soluble in hexane than in water. e. If the reaction is cooled, there will be a shift left/shift right/no shift (circle one). f. Which of the changes above will change the equilibrium constant, K?
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