Organic Chemistry, Binder Ready Version
Organic Chemistry, Binder Ready Version
2nd Edition
ISBN: 9781118454312
Author: David R. Klein
Publisher: WILEY
Question
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Chapter 9.11, Problem 34PTS

 (a)

Interpretation Introduction

Interpretation:

Product should be found for the given alkenes while treating with ozone followed by DMS.

Concept introduction:

  • Ozonolysis: ozonolysis is a process of treating alkene with ozone and DMS to get respective carbonyl compounds.
  • This ozonolysis process proceeds via ozonide intermediate, this intermediate further transformed to carbonyl compounds in DMS.

To find: the products for the alkene during the ozonolysis process.

 (b)

Interpretation Introduction

Interpretation:

Product should be found for the given alkenes while treating with ozone followed by DMS.

Concept introduction:

  • Ozonolysis: ozonolysis is a process of treating alkene with ozone and DMS to get respective carbonyl compounds.
  • This ozonolysis process proceeds via ozonide intermediate, this intermediate further transformed to carbonyl compounds in DMS.

To find: the products for the alkene during the ozonolysis process.

(c)

Interpretation Introduction

Interpretation:

Product should be found for the given alkenes while treating with ozone followed by DMS.

Concept introduction:

  • Ozonolysis: ozonolysis is a process of treating alkene with ozone and DMS to get respective carbonyl compounds.
  • This ozonolysis process proceeds via ozonide intermediate, this intermediate further transformed to carbonyl compounds in DMS.

To find: the products for the alkene during the ozonolysis process.

(d)

Interpretation Introduction

Interpretation:

Product should be found for the given alkenes while treating with ozone followed by DMS.

Concept introduction:

  • Ozonolysis: ozonolysis is a process of treating alkene with ozone and DMS to get respective carbonyl compounds.
  • This ozonolysis process proceeds via ozonide intermediate, this intermediate further transformed to carbonyl compounds in DMS.

To find: the products for the alkene during the ozonolysis process.

(e)

Interpretation Introduction

Interpretation:

Product should be found for the given alkenes while treating with ozone followed by DMS.

Concept introduction:

  • Ozonolysis: ozonolysis is a process of treating alkene with ozone and DMS to get respective carbonyl compounds.
  • This ozonolysis process proceeds via ozonide intermediate, this intermediate further transformed to carbonyl compounds in DMS.

To find: the products for the alkene during the ozonolysis process.

(f)

Interpretation Introduction

Interpretation:

Product should be found for the given alkenes while treating with ozone followed by DMS.

Concept introduction:

  • Ozonolysis: ozonolysis is a process of treating alkene with ozone and DMS to get respective carbonyl compounds.
  • This ozonolysis process proceeds via ozonide intermediate, this intermediate further transformed to carbonyl compounds in DMS.

To find: the products for the alkene during the ozonolysis process.

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ion. A student proposes the following Lewis structure for the perchlorate (CIO) io : :0: : Cl : - - : :0: ك Assign a formal charge to each atom in the student's Lewis structure. atom central O formal charge ☐ top O ☐ right O ☐ bottom O ☐ Cl ☐
Decide whether these proposed Lewis structures are reasonable. proposed Lewis structure Yes. Is the proposed Lewis structure reasonable? Cl- : 2: :Z: :Z: N—N : 0: C C1: O CO No, it has the wrong number of valence electrons. The correct number is: ☐ No, it has the right number of valence electrons but doesn't satisfy the octet rule. The symbols of the problem atoms are:* ☐ Yes. No, it has the wrong number of valence electrons. The correct number is: ☐ No, it has the right number of valence electrons but doesn't satisfy the octet rule. The symbols of the problem atoms are:* | Yes. No, it has the wrong number of valence electrons. The correct number is: No, it has the right number of valence electrons but doesn't satisfy the octet rule. The symbols of the problem atoms are:* | If two or more atoms of the same element don't satisfy the octet rule, just enter the chemical symbol as many times as necessary. For example, if two oxygen atoms don't satisfy the octet rule, enter "0,0". ☑
Use the observations about each chemical reaction in the table below to decide the sign (positive or negative) of the reaction enthalpy AH and reaction entropy AS. Note: if you have not been given enough information to decide a sign, select the "unknown" option. reaction observations conclusions ΔΗ is (pick one) A This reaction is faster above 103. °C than below. AS is (pick one) ΔΗ is (pick one) B This reaction is spontaneous only above -9. °C. AS is (pick one) ΔΗ is (pick one) C The reverse of this reaction is always spontaneous. AS is (pick one) 18 Ar

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