Organic Chemistry, Binder Ready Version
2nd Edition
ISBN: 9781118454312
Author: David R. Klein
Publisher: WILEY
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Question
Chapter 9, Problem 49PP
Interpretation Introduction
Interpretation:
Major product should be drawn for the given reactions according the reagents mentioned.
Concept introduction:
- Hydro halogenation: addition of hydrogen and halogen molecules across the double bond of
alkene is known as hydro halogenation reaction - Syn-dihydroxylation: syn- dihydroxylation is a process of adding two –OH groups from the same plane to the alkene.
- Hydrogenation: addition of hydrogen molecule across the double bond in presence of
transition metal catalyst is known as hydrogenation process. - Bromination reaction: addition of bromine molecule across the double bond is known as bromination reaction.
- Hydration: addition of water molecule across the double bond is known as hydration reaction. In oxymercuration-demercuration hydration process, -OH group is added at the most substituted carbon position of the alkene.
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Students have asked these similar questions
Please help me find the 1/Time, Log [I^-] Log [S2O8^2-], Log(time) on the data table. With calculation steps. And the average for runs 1a-1b. Please help me thanks in advance. Will up vote!
Q1: Answer the questions for the reaction below:
..!! Br
OH
a) Predict the product(s) of the reaction.
b) Is the substrate optically active? Are the product(s) optically active as a mix?
c) Draw the curved arrow mechanism for the reaction.
d) What happens to the SN1 reaction rate in each of these instances:
1. Change the substrate to
Br
"CI
2. Change the substrate to
3. Change the solvent from 100% CH3CH2OH to 10% CH3CH2OH + 90% DMF
4. Increase the substrate concentration by 3-fold.
Experiment 27 hates & Mechanisms of Reations
Method I visual Clock Reaction
A. Concentration effects on reaction Rates
Iodine
Run [I] mol/L [S₂082] | Time
mo/L
(SCC)
0.04 54.7
Log
1/ Time Temp Log [ ] 13,20] (time)
/ [I] 199
20.06
23.0
30.04 0.04
0.04 80.0
22.8
45
40.02
0.04 79.0
21.6
50.08
0.03 51.0
22.4
60-080-02 95.0
23.4
7 0.08
0-01 1970
23.4
8 0.08 0.04 16.1
22.6
Chapter 9 Solutions
Organic Chemistry, Binder Ready Version
Ch. 9.3 - Prob. 3PTSCh. 9.3 - Prob. 4ATSCh. 9.3 - Prob. 5ATSCh. 9.3 - Prob. 2LTSCh. 9.3 - Prob. 7PTSCh. 9.3 - Prob. 8ATSCh. 9.3 - Prob. 9ATSCh. 9.4 - Prob. 10CCCh. 9.4 - Prob. 11CCCh. 9.4 - Prob. 3LTS
Ch. 9.4 - Prob. 12PTSCh. 9.4 - Prob. 13ATSCh. 9.4 - Prob. 14ATSCh. 9.6 - Prob. 18CCCh. 9.6 - Prob. 4LTSCh. 9.6 - Prob. 19PTSCh. 9.6 - Prob. 20ATSCh. 9.6 - Prob. 21ATSCh. 9.6 - Prob. 22ATSCh. 9.7 - Prob. 23PTSCh. 9.7 - Prob. 24ATSCh. 9.7 - Prob. 25ATSCh. 9.8 - Prob. 26CCCh. 9.8 - Prob. 27PTSCh. 9.8 - Prob. 28ATSCh. 9.8 - Prob. 29ATSCh. 9.9 - Prob. 30PTSCh. 9.9 - Prob. 31ATSCh. 9.9 - Prob. 32ATSCh. 9.10 - Prob. 33CCCh. 9.11 - Prob. 34PTSCh. 9.11 - Prob. 35ATSCh. 9.12 - Prob. 9LTSCh. 9.12 - Prob. 36PTSCh. 9.12 - Prob. 37ATSCh. 9.12 - Prob. 38ATSCh. 9.12 - Prob. 39ATSCh. 9.13 - Prob. 10LTSCh. 9.13 - Prob. 40PTSCh. 9.13 - Prob. 41ATSCh. 9.13 - Prob. 11LTSCh. 9.13 - Prob. 42PTSCh. 9.13 - Prob. 43ATSCh. 9.13 - Prob. 44ATSCh. 9.13 - Prob. 12LTSCh. 9.13 - Prob. 47ATSCh. 9 - Prob. 48PPCh. 9 - Prob. 49PPCh. 9 - Prob. 50PPCh. 9 - Prob. 51PPCh. 9 - Prob. 52PPCh. 9 - Prob. 53PPCh. 9 - Prob. 54PPCh. 9 - Prob. 55PPCh. 9 - Prob. 56PPCh. 9 - Prob. 59PPCh. 9 - Prob. 60PPCh. 9 - Prob. 61PPCh. 9 - Prob. 62PPCh. 9 - Prob. 63PPCh. 9 - Prob. 64PPCh. 9 - Prob. 65PPCh. 9 - Prob. 66PPCh. 9 - Prob. 67PPCh. 9 - Prob. 68PPCh. 9 - Prob. 69PPCh. 9 - Prob. 70PPCh. 9 - Prob. 71PPCh. 9 - Prob. 72PPCh. 9 - Prob. 73PPCh. 9 - Prob. 74IPCh. 9 - Prob. 75IPCh. 9 - Prob. 76IPCh. 9 - Prob. 77IPCh. 9 - Prob. 78IPCh. 9 - Prob. 79IPCh. 9 - Prob. 80IPCh. 9 - Prob. 81IPCh. 9 - Prob. 82IPCh. 9 - Prob. 83IP
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