Organic Chemistry, Binder Ready Version
Organic Chemistry, Binder Ready Version
2nd Edition
ISBN: 9781118454312
Author: David R. Klein
Publisher: WILEY
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Chapter 9.7, Problem 25ATS

(a)

Interpretation Introduction

Interpretation:

Structural formula should be drawn for the molecular formula C5H10 that gives 2-methylbutane on hydrogenation reaction withy 1 mole molecular hydrogen.

Concept introduction:

  • Hydrogenation reaction: hydrogenation is a process of adding hydrogen molecule across the double bond of alkene. This process follows syn pathway. Hydrogen addition mechanism follows adsorption phenomenon.
  • Generally, hydrogenation of alkenes proceeds in presence of transition metal catalysts like Pt, Pd, and Ni etc.

To find: The possible alkenes (X) for the molecular formula C5H10 that gives 2-methylbutane on hydrogenation reaction.

(b)

Interpretation Introduction

Interpretation:

Structural formula should be drawn for the molecular formula C5H10 that gives 2-methylbutane on hydrogenation reaction withy 1 mole molecular hydrogen.

Concept introduction:

  • Hydrogenation reaction: hydrogenation is a process of adding hydrogen molecule across the double bond of alkene. This process follows syn pathway. Hydrogen addition mechanism follows adsorption phenomenon.
  • Generally, hydrogenation of alkenes proceeds in presence of transition metal catalysts like Pt, Pd, and Ni etc.

To predict: The alkene (X), which gives product with no chiral center during hydroboration-oxidation reaction.

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Assign R or S to all the chiral centers in each compound drawn below porat bg 9 Br Br

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