More reactive alkyl halide in the given pair when reacts in an E2 reaction with hydroxide ion has to be identified. Concept Introduction: Elimination from a tertiary alkyl halide leads to more substituted product from secondary alkyl halide. Same way elimination from a secondary alkyl halide leads to more substituted alkene than does elimination from primary alkyl halide.

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Answer 1

Question

Chapter 9.7, Problem 24P

(a)

Interpretation Introduction

Interpretation:

More reactive alkyl halide in the given pair when reacts in an E2 reaction with hydroxide ion has to be identified.

Concept Introduction:

Elimination from a tertiary alkyl halide leads to more substituted product from secondary alkyl halide. Same way elimination from a secondary alkyl halide leads to more substituted alkene than does elimination from primary alkyl halide.

(b)

Interpretation Introduction

Interpretation:

More reactive alkyl halide in the given pair when reacts in an E2 reaction with hydroxide ion has to be identified.

Concept Introduction:

Elimination from a tertiary alkyl halide leads to more substituted product from secondary alkyl halide. Same way elimination from a secondary alkyl halide leads to more substituted alkene than does elimination from primary alkyl halide.

(c)

Interpretation Introduction

Interpretation:

More reactive alkyl halide in the given pair when reacts in an E2 reaction with hydroxide ion has to be identified.

Concept Introduction:

Elimination from a tertiary alkyl halide leads to more substituted product from secondary alkyl halide. Same way elimination from a secondary alkyl halide leads to more substituted alkene than does elimination from primary alkyl halide.

(d)

Interpretation Introduction

Interpretation:

More reactive alkyl halide in the given pair when reacts in an E2 reaction with hydroxide ion has to be identified.

Concept Introduction:

Elimination from a tertiary alkyl halide leads to more substituted product from secondary alkyl halide. Same way elimination from a secondary alkyl halide leads to more substituted alkene than does elimination from primary alkyl halide.

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What is the average mass of the 10 pennies? Report your value with correct significant figures. What is the error (uncertainty) associated with each mass measurement due to the equipment? What is the uncertainty associated with the average value? Note that the uncertainty of the balance will propagate throughout the calculation. What is the standard deviation of the 10 mass measurements? Explain the difference between the propagated uncertainty and the standard deviation. Which number would you use to describe the uncertainty in the measurement? Calculate the total mass of the pennies with associated uncertainty. Calculate the average density of a penny based on these data. Propagate the uncertainty values for both mass and volume in your calculations.

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B 1 of 2 Additional problems in preparation to Midterm #1: 1.) How can the following compounds be prepared using Diels-Alder reaction: CH3 O CN (a) (b) CN CH3 2.) What is the missing reagent in the shown reaction? H3C + ? H3C H3C CN H3C ''CN (၁) H 3.) Write the products 1,2-addition and 1,4-addition of DBr to 1,3-cyclohexadiene. Remember, D is deuterium, a heavy isotope of hydrogen. It reacts exactly like hydrogen. 4.) In the shown reaction, which will be the kinetic product and which will be the thermodynamic product? H3C CI H3C HCI H3C + 5.) Which of the following molecules is aromatic? (a) (b) (c) H 6.) Which of the following molecules is aromatic? (a) (b) (c) 7.) Write the mechanism for the shown reaction. + Ха AICI 3 CI 8.) Suggest reagents that would convert benzene into the shown compounds. CI NO2 -8-6-6-8-a (a) (b) (c) (d) (e) (a) SO3H Br

Answer 2

Question

Chapter 9.7, Problem 24P

(a)

Interpretation Introduction

Interpretation:

More reactive alkyl halide in the given pair when reacts in an E2 reaction with hydroxide ion has to be identified.

Concept Introduction:

Elimination from a tertiary alkyl halide leads to more substituted product from secondary alkyl halide. Same way elimination from a secondary alkyl halide leads to more substituted alkene than does elimination from primary alkyl halide.

(b)

Interpretation Introduction

Interpretation:

More reactive alkyl halide in the given pair when reacts in an E2 reaction with hydroxide ion has to be identified.

Concept Introduction:

Elimination from a tertiary alkyl halide leads to more substituted product from secondary alkyl halide. Same way elimination from a secondary alkyl halide leads to more substituted alkene than does elimination from primary alkyl halide.

(c)

Interpretation Introduction

Interpretation:

More reactive alkyl halide in the given pair when reacts in an E2 reaction with hydroxide ion has to be identified.

Concept Introduction:

Elimination from a tertiary alkyl halide leads to more substituted product from secondary alkyl halide. Same way elimination from a secondary alkyl halide leads to more substituted alkene than does elimination from primary alkyl halide.

(d)

Interpretation Introduction

Interpretation:

More reactive alkyl halide in the given pair when reacts in an E2 reaction with hydroxide ion has to be identified.

Concept Introduction:

Elimination from a tertiary alkyl halide leads to more substituted product from secondary alkyl halide. Same way elimination from a secondary alkyl halide leads to more substituted alkene than does elimination from primary alkyl halide.

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Answer 3

Question

Chapter 9.7, Problem 24P

(a)

Interpretation Introduction

Interpretation:

More reactive alkyl halide in the given pair when reacts in an E2 reaction with hydroxide ion has to be identified.

Concept Introduction:

Elimination from a tertiary alkyl halide leads to more substituted product from secondary alkyl halide. Same way elimination from a secondary alkyl halide leads to more substituted alkene than does elimination from primary alkyl halide.

(b)

Interpretation Introduction

Interpretation:

More reactive alkyl halide in the given pair when reacts in an E2 reaction with hydroxide ion has to be identified.

Concept Introduction:

Elimination from a tertiary alkyl halide leads to more substituted product from secondary alkyl halide. Same way elimination from a secondary alkyl halide leads to more substituted alkene than does elimination from primary alkyl halide.

(c)

Interpretation Introduction

Interpretation:

More reactive alkyl halide in the given pair when reacts in an E2 reaction with hydroxide ion has to be identified.

Concept Introduction:

Elimination from a tertiary alkyl halide leads to more substituted product from secondary alkyl halide. Same way elimination from a secondary alkyl halide leads to more substituted alkene than does elimination from primary alkyl halide.

(d)

Interpretation Introduction

Interpretation:

More reactive alkyl halide in the given pair when reacts in an E2 reaction with hydroxide ion has to be identified.

Concept Introduction:

Elimination from a tertiary alkyl halide leads to more substituted product from secondary alkyl halide. Same way elimination from a secondary alkyl halide leads to more substituted alkene than does elimination from primary alkyl halide.

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Answer 4

Question

Chapter 9.7, Problem 24P

(a)

Interpretation Introduction

Interpretation:

More reactive alkyl halide in the given pair when reacts in an E2 reaction with hydroxide ion has to be identified.

Concept Introduction:

Elimination from a tertiary alkyl halide leads to more substituted product from secondary alkyl halide. Same way elimination from a secondary alkyl halide leads to more substituted alkene than does elimination from primary alkyl halide.

(b)

Interpretation Introduction

Interpretation:

More reactive alkyl halide in the given pair when reacts in an E2 reaction with hydroxide ion has to be identified.

Concept Introduction:

Elimination from a tertiary alkyl halide leads to more substituted product from secondary alkyl halide. Same way elimination from a secondary alkyl halide leads to more substituted alkene than does elimination from primary alkyl halide.

(c)

Interpretation Introduction

Interpretation:

More reactive alkyl halide in the given pair when reacts in an E2 reaction with hydroxide ion has to be identified.

Concept Introduction:

Elimination from a tertiary alkyl halide leads to more substituted product from secondary alkyl halide. Same way elimination from a secondary alkyl halide leads to more substituted alkene than does elimination from primary alkyl halide.

(d)

Interpretation Introduction

Interpretation:

More reactive alkyl halide in the given pair when reacts in an E2 reaction with hydroxide ion has to be identified.

Concept Introduction:

Elimination from a tertiary alkyl halide leads to more substituted product from secondary alkyl halide. Same way elimination from a secondary alkyl halide leads to more substituted alkene than does elimination from primary alkyl halide.

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Answer 5

Chapter 9.7, Problem 24P

(a)

Interpretation Introduction

Interpretation:

More reactive alkyl halide in the given pair when reacts in an E2 reaction with hydroxide ion has to be identified.

Concept Introduction:

Elimination from a tertiary alkyl halide leads to more substituted product from secondary alkyl halide. Same way elimination from a secondary alkyl halide leads to more substituted alkene than does elimination from primary alkyl halide.

(b)

Interpretation Introduction

Interpretation:

More reactive alkyl halide in the given pair when reacts in an E2 reaction with hydroxide ion has to be identified.

Concept Introduction:

Elimination from a tertiary alkyl halide leads to more substituted product from secondary alkyl halide. Same way elimination from a secondary alkyl halide leads to more substituted alkene than does elimination from primary alkyl halide.

(c)

Interpretation Introduction

Interpretation:

More reactive alkyl halide in the given pair when reacts in an E2 reaction with hydroxide ion has to be identified.

Concept Introduction:

Elimination from a tertiary alkyl halide leads to more substituted product from secondary alkyl halide. Same way elimination from a secondary alkyl halide leads to more substituted alkene than does elimination from primary alkyl halide.

(d)

Interpretation Introduction

Interpretation:

More reactive alkyl halide in the given pair when reacts in an E2 reaction with hydroxide ion has to be identified.

Concept Introduction:

Elimination from a tertiary alkyl halide leads to more substituted product from secondary alkyl halide. Same way elimination from a secondary alkyl halide leads to more substituted alkene than does elimination from primary alkyl halide.

Answer 6

Chapter 9.7, Problem 24P

(a)

Interpretation Introduction

Interpretation:

More reactive alkyl halide in the given pair when reacts in an E2 reaction with hydroxide ion has to be identified.

Concept Introduction:

Elimination from a tertiary alkyl halide leads to more substituted product from secondary alkyl halide. Same way elimination from a secondary alkyl halide leads to more substituted alkene than does elimination from primary alkyl halide.

Answer 7

Chapter 9.7, Problem 24P

(a)

Interpretation Introduction

Interpretation:

More reactive alkyl halide in the given pair when reacts in an E2 reaction with hydroxide ion has to be identified.

Concept Introduction:

Elimination from a tertiary alkyl halide leads to more substituted product from secondary alkyl halide. Same way elimination from a secondary alkyl halide leads to more substituted alkene than does elimination from primary alkyl halide.

Answer 8

(b)

Interpretation Introduction

Interpretation:

More reactive alkyl halide in the given pair when reacts in an E2 reaction with hydroxide ion has to be identified.

Concept Introduction:

Elimination from a tertiary alkyl halide leads to more substituted product from secondary alkyl halide. Same way elimination from a secondary alkyl halide leads to more substituted alkene than does elimination from primary alkyl halide.

Answer 9

(b)

Interpretation Introduction

Interpretation:

More reactive alkyl halide in the given pair when reacts in an E2 reaction with hydroxide ion has to be identified.

Concept Introduction:

Elimination from a tertiary alkyl halide leads to more substituted product from secondary alkyl halide. Same way elimination from a secondary alkyl halide leads to more substituted alkene than does elimination from primary alkyl halide.

Answer 10

(c)

Interpretation Introduction

Interpretation:

More reactive alkyl halide in the given pair when reacts in an E2 reaction with hydroxide ion has to be identified.

Concept Introduction:

Elimination from a tertiary alkyl halide leads to more substituted product from secondary alkyl halide. Same way elimination from a secondary alkyl halide leads to more substituted alkene than does elimination from primary alkyl halide.

Answer 11

(c)

Interpretation Introduction

Interpretation:

More reactive alkyl halide in the given pair when reacts in an E2 reaction with hydroxide ion has to be identified.

Concept Introduction:

Elimination from a tertiary alkyl halide leads to more substituted product from secondary alkyl halide. Same way elimination from a secondary alkyl halide leads to more substituted alkene than does elimination from primary alkyl halide.

Answer 12

(d)

Interpretation Introduction

Interpretation:

More reactive alkyl halide in the given pair when reacts in an E2 reaction with hydroxide ion has to be identified.

Concept Introduction:

Elimination from a tertiary alkyl halide leads to more substituted product from secondary alkyl halide. Same way elimination from a secondary alkyl halide leads to more substituted alkene than does elimination from primary alkyl halide.

Answer 13

(d)

Interpretation Introduction

Interpretation:

More reactive alkyl halide in the given pair when reacts in an E2 reaction with hydroxide ion has to be identified.

Concept Introduction:

Elimination from a tertiary alkyl halide leads to more substituted product from secondary alkyl halide. Same way elimination from a secondary alkyl halide leads to more substituted alkene than does elimination from primary alkyl halide.

Answer 14

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Answer 15

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Answer 16

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Answer 17

Ch. 9.1 - Prob. 3P Ch. 9.1 - Does increasing the energy barrier for an SN2...Ch. 9.1 - Rank the following alkyl bromides from most...Ch. 9.1 - Prob. 8P Ch. 9.2 - Prob. 9P Ch. 9.2 - Prob. 10P Ch. 9.2 - Prob. 11P Ch. 9.2 - Prob. 12P Ch. 9.2 - Which substitution reaction lakes place more...Ch. 9.2 - Prob. 15P

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