EP FUND.OF GENERAL,ORG...-MOD.MASTERING
8th Edition
ISBN: 9780134326061
Author: McMurry
Publisher: PEARSON CO
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Chapter 9.6, Problem 9.14P
The concentration of cholesterol (C27H46O) in blood is approximately 5.0 mM. How many grams of cholesterol are in 250 mL of blood?
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The preferred substrate is T because the enzyme half-saturates at 7.00 mM for T, but requires 28.0 mM for U, and 112 mM for S.
b
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The rate constant k 2 with substrate S is 9.60×107 sec-1, with substrate T, k 2 = 6.00×104 sec-1, and with substrate U, k 2 = 2.40×106 sec-1.
Calculate the catalytic efficiency with S, T, and U.
Catalytic efficiency with S =
Catalytic efficiency with T =
Catalytic efficiency with U =
Does enzyme A use substrate S, substrate T, or substrate U with greater catalytic efficiency?
Fumerase catalyzes the conversion of fumerate to malate.
fumerate + H2O ⇋ malate
The turnover number, kcat, for fumerase is 8.00×102 sec-1. The Km of this enzyme for fumerate is 5.00×10-3 μmol mL-1.
a
In an experiment using 2.00×10-3 μmol·mL-1, what is Vmax?
Suppose you wanted to make a buffer of exactly pH 7.00 using KH2PO4 and Na2HPO4. If the final solution was 0.18 M in KH2PO4, you would need 0.25 M Na2HPO4. Now assume you wish to make a buffer at the same pH, using the same substances, but want the total phosphate molarity ([HPO42−]+[H2PO−4]) to equal 0.20 M. What concentration of the Na2HPO4 would be required?
Chapter 9 Solutions
EP FUND.OF GENERAL,ORG...-MOD.MASTERING
Ch. 9.1 - Classify the following liquid mixtures as...Ch. 9.2 - Write the formula of sodium sulfate decahydrate,...Ch. 9.2 - What mass of Glaubers salt must be used to provide...Ch. 9.2 - Which of the following pairs of substances would...Ch. 9.4 - A solution is prepared by dissolving 12.5 g of KBr...Ch. 9.5 - Prob. 9.4PCh. 9.5 - Prob. 9.5PCh. 9.6 - How does the body increase oxygen availability at...Ch. 9.6 - A metal alloy contains 15.8% nickel (m/m)%. What...Ch. 9.6 - Prob. 9.7P
Ch. 9.6 - Prob. 9.8PCh. 9.6 - Prob. 9.9PCh. 9.6 - Prob. 9.10PCh. 9.6 - Prob. 9.11PCh. 9.6 - What is the molarity of a solution that contains...Ch. 9.6 - How many moles of solute are present in the...Ch. 9.6 - The concentration of cholesterol (C27H46O) in...Ch. 9.6 - Prob. 9.15PCh. 9.7 - Prob. 9.16PCh. 9.7 - Prob. 9.17PCh. 9.8 - Prob. 9.5CIAPCh. 9.8 - Prob. 9.6CIAPCh. 9.8 - Prob. 9.7CIAPCh. 9.8 - Prob. 9.18PCh. 9.8 - Prob. 9.19PCh. 9.9 - A solution is prepared by dissolving 0.67 mol of...Ch. 9.9 - Prob. 9.21PCh. 9.9 - Prob. 9.22KCPCh. 9.9 - What is the freezing point of a solution of 1.0...Ch. 9.9 - Prob. 9.24PCh. 9.10 - What is the osmolarity of the following solutions?...Ch. 9.10 - Prob. 9.26PCh. 9.11 - Prob. 9.8CIAPCh. 9.11 - Prob. 9.9CIAPCh. 9 - Assume that two liquids are separated by a...Ch. 9 - Prob. 9.28UKCCh. 9 - Prob. 9.29UKCCh. 9 - Assume that you have two full beakers, one...Ch. 9 - A beaker containing 150.0 mL of 0.1 M glucose is...Ch. 9 - Prob. 9.32APCh. 9 - Prob. 9.33APCh. 9 - Prob. 9.34APCh. 9 - Prob. 9.35APCh. 9 - Which of the following are solutions? (a)Italian...Ch. 9 - Prob. 9.37APCh. 9 - The solubility of NH3 gas in water at an NH3...Ch. 9 - Prob. 9.39APCh. 9 - Is a solution highly concentrated if it is...Ch. 9 - How is mass/volume percent concentration defined...Ch. 9 - Prob. 9.42APCh. 9 - Prob. 9.43APCh. 9 - A 750.0 mL bottle of Listerine is of a 21% (v/v)...Ch. 9 - Prob. 9.45APCh. 9 - Prob. 9.46APCh. 9 - Prob. 9.47APCh. 9 - Prob. 9.48APCh. 9 - Prob. 9.49APCh. 9 - How many moles of each substance are needed to...Ch. 9 - Prob. 9.51APCh. 9 - If you had only 23 g of KOH remaining in a bottle,...Ch. 9 - Prob. 9.53APCh. 9 - The lethal dosage of potassium cyanide (KCN) in...Ch. 9 - What is the molarity of the following solutions?...Ch. 9 - How many grams of solute are in the following...Ch. 9 - How many milliliters of a 0.75 M HCl solution do...Ch. 9 - Prob. 9.58APCh. 9 - Prob. 9.59APCh. 9 - Sodium thiosulfate (Na2S2O3), the major component...Ch. 9 - Prob. 9.61APCh. 9 - What is the final volume of NaOH solution prepared...Ch. 9 - Prob. 9.63APCh. 9 - What is the concentration of a NaCl solution, in...Ch. 9 - Concentrated (12.0 M) hydrochloric acid is sold...Ch. 9 - Dilute solutions of NaHCO3 are sometimes used in...Ch. 9 - Prob. 9.67APCh. 9 - Prob. 9.68APCh. 9 - Prob. 9.69APCh. 9 - What is the total anion concentration (in mEq/L)...Ch. 9 - Kaochlor, a 10% (m/v) KCl solution, is an oral...Ch. 9 - Prob. 9.72APCh. 9 - The concentration of Cl ion in blood is...Ch. 9 - Prob. 9.74APCh. 9 - Which lowers the freezing point of 2.0 kg of water...Ch. 9 - Which solution has the higher boiling point, 0.500...Ch. 9 - Methanol, CH3OH, is sometimes used as an...Ch. 9 - Hard candy is prepared by dissolving pure sugar...Ch. 9 - Prob. 9.79APCh. 9 - Prob. 9.80APCh. 9 - Which of the following solutions has the higher...Ch. 9 - Which of the following solutions will give rise to...Ch. 9 - A pickling solution for preserving food is...Ch. 9 - Prob. 9.84APCh. 9 - Prob. 9.85CPCh. 9 - Emergency treatment of cardiac arrest victims...Ch. 9 - Nitric acid, HNO3, is available commercially at a...Ch. 9 - Prob. 9.88CPCh. 9 - A typical dosage of statin drugs for the treatment...Ch. 9 - Prob. 9.90CPCh. 9 - Prob. 9.91CPCh. 9 - Prob. 9.92CPCh. 9 - Prob. 9.93CPCh. 9 - Prob. 9.94CPCh. 9 - Prob. 9.95CPCh. 9 - Prob. 9.96GPCh. 9 - Look up the maximum concentrations set by the U.S....Ch. 9 - Look up the composition of Ringers solution used...Ch. 9 - To prevent accumulation of ice on roads and...Ch. 9 - Many carbonate minerals are insoluble in water and...Ch. 9 - Prob. 9.101GP
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