Organic Chemistry As a Second Language: Second Semester Topics
4th Edition
ISBN: 9781119110651
Author: David R. Klein
Publisher: WILEY
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Chapter 9.5, Problem 9.27P
Predict the major product for each of the following reactions:
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The structure of compound 1,3,5-trimethylbenzene (mesitylene) is given below.
How many signals would you expect to find in the 'H NMR spectrum of 1,3,5-trimethylbenzene (mesitylene)?
Check
×
1
How many signals do you expect in the 'H NMR spectrum for this molecule?
CI CI
Cl
Write the answer in the table below.
Also, in each of the drawing areas below is a copy of the molecule, with H atoms shown. In each copy, one of the H atoms is highlighted red. Highlight in red all
other H atoms that would contribute to the same signal as the H already highlighted red.
Note for advanced students: Remember, a multiplet is considered one signal in the 'H NMR spectrum.
1
Number of signals in the 'H NMR spectrum.
☐
For the molecule in the top drawing area, highlight in red any other H atoms that will contribute to the same
signal as the H atom already highlighted red.
If no other H atoms will contribute, check the box at right.
No additional H atoms to highlight in
top molecule
For the molecule in the bottom drawing area, highlight in red any other H atoms that will contribute to the
same signal as the H atom already highlighted red.
If no other H atoms will contribute, check the box at…
wrtie the balanced equation and find the E° when the following half- reactions are combined
Zn2+(aq) + 2e---> Zn(s) E°= -0.763V
Ag+(aq) + e---> Ag (s) E°=+0.799V
Chapter 9 Solutions
Organic Chemistry As a Second Language: Second Semester Topics
Ch. 9.2 - Identify how you would use a Gabriel synthesis to...Ch. 9.2 - Identify how you would use a Gabriel synthesis to...Ch. 9.2 - Identify how you would use a Gabriel synthesis to...Ch. 9.2 - Identify how you would use a Gabriel synthesis to...Ch. 9.2 - Identify whether each of the following compounds...Ch. 9.2 - Identify whether each of the following compounds...Ch. 9.2 - Identify whether each of the following compounds...Ch. 9.2 - Identify whether each of the following compounds...Ch. 9.3 - Suggest an efficient synthesis for each of the...Ch. 9.3 - Suggest an efficient synthesis for each of the...
Ch. 9.3 - Suggest an efficient synthesis for each of the...Ch. 9.3 - Suggest an efficient synthesis for each of the...Ch. 9.3 - Suggest an efficient synthesis for each of the...Ch. 9.3 - Prob. 9.18PCh. 9.3 - Prob. 9.19PCh. 9.3 - Prob. 9.20PCh. 9.3 - Prob. 9.21PCh. 9.3 - Prob. 9.22PCh. 9.4 - Prob. 9.24PCh. 9.4 - Prob. 9.25PCh. 9.5 - Predict the major product for each of the...Ch. 9.5 - Predict the major product for each of the...Ch. 9.5 - Predict the major product for each of the...Ch. 9.5 - Predict the major product for each of the...Ch. 9.6 - What reagents would you use to achieve each of the...Ch. 9.6 - What reagents would you use to achieve each of the...Ch. 9.6 - What reagents would you use to achieve each of the...Ch. 9.6 - What reagents would you use to achieve each of the...Ch. 9.6 - What reagents would you use to achieve each of the...
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- Consider this molecule: How many H atoms are in this molecule? How many different signals could be found in its 'H NMR spectrum? Note: A multiplet is considered one signal. ☐arrow_forwardStudy this 'H NMR spectrum, and then answer the questions about it in the table below. Check 1.0- 0.5- 0.0 10.0 9.0 8.0 7.0 6.0 5.0 4.0 3.0 2.0 1.0 0.0 What unit symbol should be written on the horizontal axis? What is the chemical shift & of the doublet? If there is no doublet, just check the box instead. Give your answer to 2 significant digits. What is the chemical shift of the signal immediately upfield of the doublet? If there is no doublet, or no signal upfield of it, check the box instead. What is the chemical shift & of the least deshielded proton? If you can't tell without more information, check the box instead. 血 8 = ☐ There is no doublet. 8 = ☐ No such signal. 8 = 0 Need more information.arrow_forwardhow many moles of H2O2 are required to react with 11g of N2H4 according to the following reaction? (atomic weights: N=14.01, H=1.008, O= 16.00) 7H2O2 + N2H4 -> 2HNO3 + 8H20arrow_forward
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