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Chapter 9 Solutions
General, Organic, & Biological Chemistry
- Which of the following substances are acids in terms of the Arrhenius concept? Which are bases? Show the acid or base character by using chemical equations. a P4O10 b Na2O c N2H4 d H2Tearrow_forwardConsider the following four biological solutions: (1) bile, pH 8.0, (2) blood, pH 7.4, (3) urine, pH 6.0, and (4) gastric juice, pH 1.6. a. Which solution has the lowest [H3O+]? b. Which solution has the lowest [OH]? c. List the solutions in order of decreasing acidity. d. List the solutions in order of increasing basicity.arrow_forwardTo measure the relative strengths of bases stronger than OH, it is necessary to choose a solvent that is a weaker acid than water. One such solvent is liquid ammonia. (a) Write a chemical equation for the autoionization of ammonia. (b) What is the strongest acid and base that can exist in liquid ammonia? (c) Will a solution of HCI in liquid ammonia be a strong electrical conductor, a weak conductor, or a nonconductor? (d) Oxide ion (O2) is a stronger base than the amide ion (NH2). Write an equation for the reaction of O2 with NH3 in liquid ammonia. Will the equilibrium favor products or reactants?arrow_forward
- Classify each of the following as a strong acid, weak acid, strong base, or weak base in aqueous solution. a. HNO2 b. HNO3 c. CH3NH2 d. NaOH e. NH3 f. HF g. h. Ca(OH)2 i. H2SO4arrow_forwardIn each of the following acid-base reactions, identify the Brnsted acid and base on the left and their conjugate partners on the right. (a) HCO2H(aq) + H2O() HCO2(aq) + H3O+(aq) (b) NH3(aq) + H2S(aq) NH4+(aq) + HS(aq) (c) HSO4(aq) + OH(aq) SO42(aq) + H2O+()arrow_forwardUsing the diagrams shown in Problem 10-37, which of the four acids is the weakest acid?arrow_forward
- Pure liquid ammonia ionizes in a manner similar to that of water. (a) Write the equilibrium for the autoionization of liquid ammonia. (b) Identify the conjugate acid form and the base form of the solvent. (c) Is NaNH2 an acid or a base in this solvent? (d) Is ammonium bromide an acid or a base in this solvent?arrow_forwardWrite equations that show H2PO4- acting both as an acid and as a base.arrow_forwardWill the following oxides give acidic, basic, or neutral solutions when dissolved in water? Write reactions to justify your answers. a. CaO b. SO2 c. Cl2Oarrow_forward
- You are asked to calculate the H+ concentration in a solution of NaOH(aq). Because sodium hydroxide is a base, can we say there is no H+. since having H+ would imply that the solution is acidic?arrow_forwardWhich of the following conditions indicate a basic solution? pOH = 11.21 pH = 9.42 (OH’] > IH+| |OH] > 1.0 X IO’7Marrow_forwardPlace the species in each of the following groups in order of increasing acid strength. a. H2O, H2S, H2Se (bond energies: HO, 467 kJ/mol; HS, 363 kJ/mol; HSe, 276 kJ/mol) b. CH3CO2H, FCH2CO2H, F2CHCO2H, F3CCO2H c. NH4+, HONH3+ d. NH4+, PH4+ (bond energies: NH, 391 kJ/mol; PH, 322 kJ/mol) Give reasons for the orders you chose.arrow_forward
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