Student Study Guide and Solutions Manual T/A Organic Chemistry
Student Study Guide and Solutions Manual T/A Organic Chemistry
2nd Edition
ISBN: 9781118647950
Author: David R. Klein
Publisher: WILEY
Question
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Chapter 9.4, Problem 12PTS

(a)

Interpretation Introduction

Interpretation:

Mechanisms should be drawn for the given hydration reactions of alkene in acidic medium by using curved arrows.

Concept introduction:

  • Hydration of alkene reaction is addition of water molecule to an alkene.
  • In hydration reaction, product purely depends on the stability of carbocation (intermediate). That means sometimes carbocation rearranges to get a more stable carbocation.

To draw: the mechanism for given hydration reaction of alkene is shown below.

(b)

Interpretation Introduction

Interpretation:

Mechanisms should be drawn for the given hydration reactions of alkene in acidic medium by using curved arrows.

Concept introduction:

  • Hydration of alkene reaction is addition of water molecule to an alkene.
  • In hydration reaction, product purely depends on the stability of carbocation (intermediate). That means sometimes carbocation rearranges to get a more stable carbocation.

To draw: the mechanism for given hydration reaction of alkene is shown below.

(c)

Interpretation Introduction

Interpretation:

Mechanisms should be drawn for the given hydration reactions of alkene in acidic medium by using curved arrows.

Concept introduction:

  • Hydration of alkene reaction is addition of water molecule to an alkene.
  • In hydration reaction, product purely depends on the stability of carbocation (intermediate). That means sometimes carbocation rearranges to get a more stable carbocation.

To draw: the mechanism for given hydration reaction of alkene is shown below.

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4. Provide a clear arrow-pushing mechanism for each of the following reactions. Do not skip proton transfers, do not combine steps, and make sure your arrows are clear enough to be interpreted without ambiguity. a. 2. 1. LDA 3. H3O+ HO
b. H3C CH3 H3O+ ✓ H OH
2. Provide reagents/conditions to accomplish the following syntheses. More than one step is required in some cases. a. CH3

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Student Study Guide and Solutions Manual T/A Organic Chemistry

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