Student Study Guide and Solutions Manual T/A Organic Chemistry
2nd Edition
ISBN: 9781118647950
Author: David R. Klein
Publisher: WILEY
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Question
Chapter 9.13, Problem 41ATS
(a)
Interpretation Introduction
Interpretation:
Reagents should be predicted for the given transformations.
Concept introduction:
Reagent: reagent is a compound or compound mixture that is used in the chemical transformation of the reactions. Reagents for some reactions are given below.
- Elimination reaction: in elimination reaction, two substituents are removed from the substrate to give the product in presence of base.
- Anti-dihydroxylation: anti- dihydroxylation is a process of adding two –OH groups from different planes to the alkene.
Alkenes are treated with peroxy acids followed by aqueous acids and gives anti-dihydroxylation products. - Syn-dihydroxylation: syn- dihydroxylation is a process of adding two –OH groups from the same plane to the alkene. Potassium per manganite and osmium tetroxide etc, are used as reagents.
To find: the reagent for the given transformation.
(b)
Interpretation Introduction
Interpretation:
Reagents should be predicted for the given transformations.
Concept introduction:
Reagent: reagent is a compound or compound mixture that is used in the chemical transformation of the reactions. Reagents for some reactions are given below.
- Elimination reaction: in elimination reaction, two substituents are removed from the substrate to give the product in presence of base.
- Anti-dihydroxylation: anti- dihydroxylation is a process of adding two –OH groups from different planes to the alkene. Alkenes are treated with peroxy acids followed by aqueous acids and gives anti-dihydroxylation products.
- Syn-dihydroxylation: syn- dihydroxylation is a process of adding two –OH groups from the same plane to the alkene. Potassium per manganite and osmium tetroxide etc, are used as reagents.
To find: the reagent for the given transformation.
(c)
Interpretation Introduction
Interpretation:
Reagents should be predicted for the given transformations.
Concept introduction:
Reagent: reagent is a compound or compound mixture that is used in the chemical transformation of the reactions. Reagents for some reactions are given below.
- Elimination reaction: in elimination reaction, two substituents are removed from the substrate to give the product in presence of base.
- Anti-dihydroxylation: anti- dihydroxylation is a process of adding two –OH groups from different planes to the alkene. Alkenes are treated with peroxy acids followed by aqueous acids and gives anti-dihydroxylation products.
- Syn-dihydroxylation: syn- dihydroxylation is a process of adding two –OH groups from the same plane to the alkene. Potassium per manganite and osmium tetroxide etc, are used as reagents.
To find: the reagent for the given transformation.
(d)
Interpretation Introduction
Interpretation:
Reagents should be predicted for the given transformations.
Concept introduction:
Reagent: reagent is a compound or compound mixture that is used in the chemical transformation of the reactions. Reagents for some reactions are given below.
- Elimination reaction: in elimination reaction, two substituents are removed from the substrate to give the product in presence of base.
- Anti-dihydroxylation: anti- dihydroxylation is a process of adding two –OH groups from different planes to the alkene. Alkenes are treated with peroxy acids followed by aqueous acids and gives anti-dihydroxylation products.
- Syn-dihydroxylation: syn- dihydroxylation is a process of adding two –OH groups from the same plane to the alkene. Potassium per manganite and osmium tetroxide etc, are used as reagents.
To find: the reagent for the given transformation.
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Students have asked these similar questions
1.
Answer the questions about the following reaction:
(a) Draw in the arrows that can be used make this reaction occur and draw in the product of substitution in this
reaction. Be sure to include any relevant stereochemistry in the product structure.
+
SK
F
Br
+
(b) In which solvent would this reaction proceed the fastest (Circle one)
Methanol
Acetone
(c) Imagine that you are working for a chemical company and it was your job to perform a similar reaction to the
one above, with the exception of the S atom in this reaction being replaced by an O atom. During the reaction, you
observe the formation of three separate molecules instead of the single molecule obtained above. What is the likeliest
other products that are formed? Draw them in the box provided.
3. For the reactions below, draw the arrows corresponding to the transformations and draw in the boxes the reactants
or products as indicated. Note: Part A should have arrows drawn going from the reactants to the middle structure
and the arrows on the middle structure that would yield the final structure. For part B, you will need to draw in
the reactant before being able to draw the arrows corresponding to product formation.
A.
B.
Rearrangement
ΘΗ
2. Draw the arrows required to make the following reactions occur. Please ensure your arrows point from exactly
where you want to exactly where you want. If it is unclear from where arrows start or where they end, only partial
credit will be given. Note: You may need to draw in lone pairs before drawing the arrows.
A.
B.
H-Br
人
C
Θ
CI
H
Cl
Θ
+
Br
O
Chapter 9 Solutions
Student Study Guide and Solutions Manual T/A Organic Chemistry
Ch. 9.3 - Prob. 3PTSCh. 9.3 - Prob. 4ATSCh. 9.3 - Prob. 5ATSCh. 9.3 - Prob. 2LTSCh. 9.3 - Prob. 7PTSCh. 9.3 - Prob. 8ATSCh. 9.3 - Prob. 9ATSCh. 9.4 - Prob. 10CCCh. 9.4 - Prob. 11CCCh. 9.4 - Prob. 3LTS
Ch. 9.4 - Prob. 12PTSCh. 9.4 - Prob. 13ATSCh. 9.4 - Prob. 14ATSCh. 9.6 - Prob. 18CCCh. 9.6 - Prob. 4LTSCh. 9.6 - Prob. 19PTSCh. 9.6 - Prob. 20ATSCh. 9.6 - Prob. 21ATSCh. 9.6 - Prob. 22ATSCh. 9.7 - Prob. 23PTSCh. 9.7 - Prob. 24ATSCh. 9.7 - Prob. 25ATSCh. 9.8 - Prob. 26CCCh. 9.8 - Prob. 27PTSCh. 9.8 - Prob. 28ATSCh. 9.8 - Prob. 29ATSCh. 9.9 - Prob. 30PTSCh. 9.9 - Prob. 31ATSCh. 9.9 - Prob. 32ATSCh. 9.10 - Prob. 33CCCh. 9.11 - Prob. 34PTSCh. 9.11 - Prob. 35ATSCh. 9.12 - Prob. 9LTSCh. 9.12 - Prob. 36PTSCh. 9.12 - Prob. 37ATSCh. 9.12 - Prob. 38ATSCh. 9.12 - Prob. 39ATSCh. 9.13 - Prob. 10LTSCh. 9.13 - Prob. 40PTSCh. 9.13 - Prob. 41ATSCh. 9.13 - Prob. 11LTSCh. 9.13 - Prob. 42PTSCh. 9.13 - Prob. 43ATSCh. 9.13 - Prob. 44ATSCh. 9.13 - Prob. 12LTSCh. 9.13 - Prob. 47ATSCh. 9 - Prob. 48PPCh. 9 - Prob. 49PPCh. 9 - Prob. 50PPCh. 9 - Prob. 51PPCh. 9 - Prob. 52PPCh. 9 - Prob. 53PPCh. 9 - Prob. 54PPCh. 9 - Prob. 55PPCh. 9 - Prob. 56PPCh. 9 - Prob. 59PPCh. 9 - Prob. 60PPCh. 9 - Prob. 61PPCh. 9 - Prob. 62PPCh. 9 - Prob. 63PPCh. 9 - Prob. 64PPCh. 9 - Prob. 65PPCh. 9 - Prob. 66PPCh. 9 - Prob. 67PPCh. 9 - Prob. 68PPCh. 9 - Prob. 69PPCh. 9 - Prob. 70PPCh. 9 - Prob. 71PPCh. 9 - Prob. 72PPCh. 9 - Prob. 73PPCh. 9 - Prob. 74IPCh. 9 - Prob. 75IPCh. 9 - Prob. 76IPCh. 9 - Prob. 77IPCh. 9 - Prob. 78IPCh. 9 - Prob. 79IPCh. 9 - Prob. 80IPCh. 9 - Prob. 81IPCh. 9 - Prob. 82IPCh. 9 - Prob. 83IP
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