Chemistry & Chemical Reactivity
10th Edition
ISBN: 9781337399074
Author: John C. Kotz, Paul M. Treichel, John Townsend, David Treichel
Publisher: Cengage Learning
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Chapter 9.3, Problem 1.1ACP
Photoelectron spectroscopy is s1milar to the
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For this question, if the product is racemic, input both enantiomers in the same Marvin editor.
A) Input the number that corresponds to the reagent which when added to (E)-but-2-ene will result in a
racemic product.
Input 1 for Cl, in the cold and dark
Input 2 for Oy followed by H₂O, Zn
Input 3 for D₂ with metal catalyst
Input 4 for H₂ with metal catalyst
B) Draw the skeletal structure of the major organic product made from the reagent in part A
Marvin JS
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C) Draw the skeletal structure of the major organic product formed when (2)-but-2-ene is treated with
peroxyacetic acid.
Marvin 35
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Michael Reactions
19.52 Draw the products from the following Michael addition reactions.
1.
H&C CH
(a)
i
2. H₂O*
(b)
OEt
(c)
EtO
H₂NEt
(d)
ΕΙΟ
+
1. NaOEt
2. H₂O'
H
H
1. NaOEt
2. H₂O*
Rank the labeled protons (Ha-Hd) in order of increasing acidity, starting with the least acidic.
НОН НЬ
OHd
Онс
Chapter 9 Solutions
Chemistry & Chemical Reactivity
Ch. 9.1 - Use valence bond theory to describe the bonding in...Ch. 9.1 - Identify the hybridization of each underlined atom...Ch. 9.1 - Use valence bond theory to describe the bonding in...Ch. 9.2 - What is the electron configuration of the H2+ ion?...Ch. 9.2 - Could the anion Li2 exist? What is the ions bond...Ch. 9.2 - The cations O2+ and N2+ are formed when molecules...Ch. 9.3 - Photoelectron spectroscopy is s1milar to the...Ch. 9.3 - What is the energy of a photon with a wavelength...Ch. 9.3 - Using the accompanying figure, state which...Ch. 9.3 - The kinetic energy of an electron ejected from the...
Ch. 9.3 - The N2+ ions that are formed when electrons with...Ch. 9.3 - What is the empirical formula of Tynan purple?Ch. 9.3 - Butter yellow absorbs light with a wavelength of...Ch. 9.3 - Prob. 2.3ACPCh. 9 - Draw the Lewis structure for chloroform, CHCl3....Ch. 9 - Draw the Lewis structure for NF3. What are its...Ch. 9 - Draw the Lewis structure for hydroxylamine, H2NOH....Ch. 9 - Draw the Lewis structure for 1,...Ch. 9 - Draw the Lewis structure for carbonyl fluoride,...Ch. 9 - Draw the Lewis structure for acetamide, CH3CONH2....Ch. 9 - Specify the electron-pair and molecular geometry...Ch. 9 - Specify the electron-pair and molecular geometry...Ch. 9 - Prob. 9PSCh. 9 - What is the hybrid orbital set used by each of the...Ch. 9 - Draw the Lewis structures of the acid HPO2F2 and...Ch. 9 - Draw the Lewis structures of the arid HSO3F and...Ch. 9 - What is the hybridization of the carbon atom in...Ch. 9 - What is the hybridization of the carbon atoms in...Ch. 9 - What is the electron-pair and molecular geometry...Ch. 9 - What is the electron-pair and molecular geometry...Ch. 9 - Prob. 17PSCh. 9 - For each compound below, decide whether cis and...Ch. 9 - Molecular Orbital Theory (See Examples 9.49.6.)...Ch. 9 - Give the electron configurations for the ions Li2+...Ch. 9 - Calcium carbide, CaC2, contains the acetylide ion,...Ch. 9 - Platinum hexafluoride is an extremely strong...Ch. 9 - When sodium and oxygen react, one of the products...Ch. 9 - When potassium and oxygen react, one of the...Ch. 9 - Among the following, which has the shortest bond...Ch. 9 - Consider the following list of small molecules and...Ch. 9 - Prob. 27PSCh. 9 - The nitrosyl ion. NO+, has an interesting...Ch. 9 - These questions are not designated as to type or...Ch. 9 - What is the OSO angle and the hybrid orbital set...Ch. 9 - Sketch the resonance structures for the nitrite...Ch. 9 - Sketch the resonance structures for the nitrate...Ch. 9 - Sketch the resonance structures for the N2O...Ch. 9 - Compare the structure and bonding in CO2 and CO32...Ch. 9 - Numerous molecules are detected in deep space....Ch. 9 - Acrolein, a component of photochemical smog, has a...Ch. 9 - The organic compound below is a member of a class...Ch. 9 - The compound sketched below is acetylsalicylic...Ch. 9 - Phosphoserine is a less-common amino acid. (a)...Ch. 9 - Lactic acid is a natural compound found in sour...Ch. 9 - Cinnamaldehyde ocaus naturally in cinnamon oil....Ch. 9 - The ion Si2 was reported in a laboratory...Ch. 9 - The simple valence bond picture of O2 does not...Ch. 9 - Nitrogen, N2, can ionize to form N2+ or add an...Ch. 9 - Which of the homonuclear, diatomic molecules of...Ch. 9 - Which of the following molecules or ions are...Ch. 9 - Prob. 47GQCh. 9 - The structure of amphetamine, a stimulant, is...Ch. 9 - Menthol is used in soaps, perfumes, and foods. It...Ch. 9 - Prob. 50GQCh. 9 - Suppose you carry out the following reaction of...Ch. 9 - Ethylene oxide is an intermediate in the...Ch. 9 - The sulfamate ion, H2NSO3, can be thought of as...Ch. 9 - The compound whose structure is shown here is...Ch. 9 - Prob. 55ILCh. 9 - Carbon dioxide (CO2), dinitrogen monoxide (N2O),...Ch. 9 - Draw the two resonance structures that describe...Ch. 9 - Draw a Lewis structure for diimide, HNNH. Then,...Ch. 9 - Prob. 59SCQCh. 9 - Consider the three fluorides BF4, SiF4, and SF4....Ch. 9 - When two amino acids react with each other, they...Ch. 9 - What is the connection between bond order, bond...Ch. 9 - When is it desirable to use MO theory rather than...Ch. 9 - Show how valence bond theory and molecular orbital...Ch. 9 - Three of the four molecular orbitals for...Ch. 9 - Lets look more closely at the process of...Ch. 9 - Borax has the molecular formula Na2B4O5(OH)4. The...Ch. 9 - A model of the organic compound allene is shown...Ch. 9 - Prob. 69SCQCh. 9 - Prob. 70SCQCh. 9 - Bromine forms a number of oxides of varying...Ch. 9 - Prob. 72SCQCh. 9 - Urea reacts with malonic acid to produce...
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- Can the target compound at right be efficiently synthesized in good yield from the unsubstituted benzene at left? ? starting material target If so, draw a synthesis below. If no synthesis using reagents ALEKS recognizes is possible, check the box under the drawing area. Be sure you follow the standard ALEKS rules for submitting syntheses. + More... Note for advanced students: you may assume that you are using a large excess of benzene as your starting material. C :0 T Add/Remove step Garrow_forwardThe following equations represent the formation of compound MX. What is the AH for the electron affinity of X (g)? X₂ (g) → 2X (g) M (s) → M (g) M (g) M (g) + e- AH = 60 kJ/mol AH = 22 kJ/mol X (g) + e-X (g) M* (g) +X (g) → MX (s) AH = 118 kJ/mol AH = ? AH = -190 kJ/mol AH = -100 kJ/mol a) -80 kJ b) -30 kJ c) -20 kJ d) 20 kJ e) 156 kJarrow_forwardA covalent bond is the result of the a) b) c) d) e) overlap of two half-filled s orbitals overlap of a half-filled s orbital and a half-filled p orbital overlap of two half-filled p orbitals along their axes parallel overlap of two half-filled parallel p orbitals all of the abovearrow_forward
- Can the target compound at right be efficiently synthesized in good yield from the unsubstituted benzene at left? starting material target If so, draw a synthesis below. If no synthesis using reagents ALEKS recognizes is possible, check the box under the drawing area. Be sure you follow the standard ALEKS rules for submitting syntheses. + More... Note for advanced students: you may assume that you are using a large excess of benzene as your starting material. C T Add/Remove step X ноarrow_forwardWhich one of the following atoms should have the largest electron affinity? a) b) c) d) 으으 e) 1s² 2s² 2p6 3s¹ 1s² 2s² 2p5 1s² 2s² 2p 3s² 3p² 1s² 2s 2p 3s² 3p6 4s2 3ds 1s² 2s² 2p6arrow_forwardAll of the following are allowed energy levels except _. a) 3f b) 1s c) 3d d) 5p e) 6sarrow_forward
- A student wants to make the following product in good yield from a single transformation step, starting from benzene. Add any organic reagents the student is missing on the left-hand side of the arrow, and any addition reagents that are necessary above or below the arrow. If this product can't be made in good yield with a single transformation step, check the box below the drawing area. Note for advanced students: you may assume that an excess of benzene is used as part of the reaction conditions. : ☐ + I X This product can't be made in a single transformation step.arrow_forwardPredict the major products of this organic reaction:arrow_forwardCalculate the density of 21.12 g of an object that displaces 0.0250 L of water.arrow_forward
- Draw the expected reactant R28. Cu(II) CO₂Mearrow_forwardPpplllleeeaaasssseeee helllppp wiithhh thisss Organic chemistryyyyyy I talked like this because AI is very annoyingarrow_forwardName the family to which each organic compound belongs. The first answer has been filled in for you. compound CH₂ || CH3-C-NH2 0 ။ CH3-C-CH₂ CH=O–CH=CH, CH₂ HO CH2-CH2-CH-CH3 family amine Darrow_forward
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