The energy required to break one of the H − F bonds in H F 2 − be greater than, less than, or the same as the energy required breaking the bond in H F ; the reason behind this should be explained. Concept Introduction Valance bond ( VBT ) theory: This theory explain a chemical bonding theory that explains the bonding between two atoms is caused by the overlap of half-filled atomic orbitals. The two atoms share each other's unpaired electron to form a filled orbital to form a hybrid orbital and bond together. Bond energy: It is defined bond energy as the average value of the gas-phase bond dissociation energies for all bonds of the same type within the same chemical species.

Question

For each compound in the table below, decide whether there would be any hydrogen-bonding force between molecules of the compound, or between molecules of the compound and molecules of water. name acetic acid dimethyl ether compound hypobromous acid formula or Lewis structure H :0: H-C-C-O-H H H H-C-0-C H H H T HBrO | H Between molecules of the compound? yes O O no O yes no yes hydrogen-bonding force no Between molecules of the compound and molecules of water? O O yes no yes no yes no X

Answer 1

Question

Formula Formula Bond dissociation energy (BDE) is the energy required to break a bond, making it an endothermic process. BDE is calculated for a particular bond and therefore consists of fragments such as radicals since it undergoes homolytic bond cleavage. For the homolysis of a X-Y molecule, the energy of bond dissociation is calculated as the difference in the total enthalpy of formation for the reactants and products. X-Y → X + Y BDE = Δ H f X + Δ H f Y – Δ H f X-Y where, ΔHf is the heat of formation.

Chapter 9, Problem 69SCQ

Interpretation Introduction

Interpretation:

The energy required to break one of the H−F bonds in HF2− be greater than, less than, or the same as the energy required breaking the bond in HF; the reason behind this should be explained.

Concept Introduction

Valance bond (VBT) theory: This theory explain a chemical bonding theory that explains the bonding between two atoms is caused by the overlap of half-filled atomic orbitals. The two atoms share each other's unpaired electron to form a filled orbital to form a hybrid orbital and bond together.

Bond energy: It is defined bond energy as the average value of the gas-phase bond dissociation energies for all bonds of the same type within the same chemical species.

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For each compound in the table below, decide whether there would be any hydrogen-bonding force between molecules of the compound, or between molecules of the compound and molecules of water. name acetic acid dimethyl ether compound hypobromous acid formula or Lewis structure H :0: H-C-C-O-H H H H-C-0-C H H H T HBrO | H Between molecules of the compound? yes O O no O yes no yes hydrogen-bonding force no Between molecules of the compound and molecules of water? O O yes no yes no yes no X

Why is the H–N–H angle in NH3 smaller than the H–C–H bond angle in CH4? Why is the H–N–H angle in NH4 + identical to the H–C–H bond angle in CH4?

[Review Topics] [References] Use the References to access important values if needed for this question. Draw a Lewis structure for the C₂H6O molecule, using the connectivity shown in the spacefilling model in the window. (Gray = C; white = H; red = 0; blue = N; dark green = Cl; brown = Br; light green= F; purple = I; yellow = S; orange = P.) The number of C-H bonds = Submitted The number of O-H bonds = 20 The number of C-C single bonds = The number of C-O single bonds = The total number of lone pairs = $ 4 R F 288 V %6 5 PA T Cengage Learning Cengage Technical Support 6 I G MacBook Air B pe Y H & 7 N F7 U J H 8 1 M ( 9 K V 1 ) O L P Previous ¡ Email Instructor Save and Exit Next [ 11 1 D

Answer 2

Question

Formula Formula Bond dissociation energy (BDE) is the energy required to break a bond, making it an endothermic process. BDE is calculated for a particular bond and therefore consists of fragments such as radicals since it undergoes homolytic bond cleavage. For the homolysis of a X-Y molecule, the energy of bond dissociation is calculated as the difference in the total enthalpy of formation for the reactants and products. X-Y → X + Y BDE = Δ H f X + Δ H f Y – Δ H f X-Y where, ΔHf is the heat of formation.

Chapter 9, Problem 69SCQ

Interpretation Introduction

Interpretation:

The energy required to break one of the H−F bonds in HF2− be greater than, less than, or the same as the energy required breaking the bond in HF; the reason behind this should be explained.

Concept Introduction

Valance bond (VBT) theory: This theory explain a chemical bonding theory that explains the bonding between two atoms is caused by the overlap of half-filled atomic orbitals. The two atoms share each other's unpaired electron to form a filled orbital to form a hybrid orbital and bond together.

Bond energy: It is defined bond energy as the average value of the gas-phase bond dissociation energies for all bonds of the same type within the same chemical species.

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Answer 3

Question

Formula Formula Bond dissociation energy (BDE) is the energy required to break a bond, making it an endothermic process. BDE is calculated for a particular bond and therefore consists of fragments such as radicals since it undergoes homolytic bond cleavage. For the homolysis of a X-Y molecule, the energy of bond dissociation is calculated as the difference in the total enthalpy of formation for the reactants and products. X-Y → X + Y BDE = Δ H f X + Δ H f Y – Δ H f X-Y where, ΔHf is the heat of formation.

Chapter 9, Problem 69SCQ

Interpretation Introduction

Interpretation:

The energy required to break one of the H−F bonds in HF2− be greater than, less than, or the same as the energy required breaking the bond in HF; the reason behind this should be explained.

Concept Introduction

Valance bond (VBT) theory: This theory explain a chemical bonding theory that explains the bonding between two atoms is caused by the overlap of half-filled atomic orbitals. The two atoms share each other's unpaired electron to form a filled orbital to form a hybrid orbital and bond together.

Bond energy: It is defined bond energy as the average value of the gas-phase bond dissociation energies for all bonds of the same type within the same chemical species.

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Answer 4

Question

Formula Formula Bond dissociation energy (BDE) is the energy required to break a bond, making it an endothermic process. BDE is calculated for a particular bond and therefore consists of fragments such as radicals since it undergoes homolytic bond cleavage. For the homolysis of a X-Y molecule, the energy of bond dissociation is calculated as the difference in the total enthalpy of formation for the reactants and products. X-Y → X + Y BDE = Δ H f X + Δ H f Y – Δ H f X-Y where, ΔHf is the heat of formation.

Chapter 9, Problem 69SCQ

Interpretation Introduction