(a) Interpretation: The products of the given reaction are to be drawn by indicating the stereochemistry at any stereogenic center. Concept introduction: Alcohols are converted into alkyl tosylates by treatment with p -toluenesulfonyl chloride ( TsCl ) in the presence of pyridine. The overall reaction converts − OH (a poor leaving group) into − OTs (a good leaving group). The stereochemistry of the reaction is retention of configuration.

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Answer 1

Question

Chapter 9.13, Problem 23P

Interpretation Introduction

(a)

Interpretation: The products of the given reaction are to be drawn by indicating the stereochemistry at any stereogenic center.

Concept introduction: Alcohols are converted into alkyl tosylates by treatment with p-toluenesulfonyl chloride (TsCl) in the presence of pyridine. The overall reaction converts −OH (a poor leaving group) into −OTs (a good leaving group). The stereochemistry of the reaction is retention of configuration.

Interpretation Introduction

(b)

Interpretation: The products of the given reaction are to be drawn by indicating the stereochemistry at any stereogenic center.

Concept introduction: Alcohols are converted into alkyl tosylates by treatment with p-toluenesulfonyl chloride (TsCl) in the presence of pyridine. The overall reaction converts −OH (a poor leaving group) into −OTs (a good leaving group). The stereochemistry of the reaction is retention of configuration.

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Answer 2

Question

Chapter 9.13, Problem 23P

Interpretation Introduction

(a)

Interpretation: The products of the given reaction are to be drawn by indicating the stereochemistry at any stereogenic center.

Concept introduction: Alcohols are converted into alkyl tosylates by treatment with p-toluenesulfonyl chloride (TsCl) in the presence of pyridine. The overall reaction converts −OH (a poor leaving group) into −OTs (a good leaving group). The stereochemistry of the reaction is retention of configuration.

Interpretation Introduction

(b)

Interpretation: The products of the given reaction are to be drawn by indicating the stereochemistry at any stereogenic center.

Concept introduction: Alcohols are converted into alkyl tosylates by treatment with p-toluenesulfonyl chloride (TsCl) in the presence of pyridine. The overall reaction converts −OH (a poor leaving group) into −OTs (a good leaving group). The stereochemistry of the reaction is retention of configuration.

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Answer 3

Question

Chapter 9.13, Problem 23P

Interpretation Introduction

(a)

Interpretation: The products of the given reaction are to be drawn by indicating the stereochemistry at any stereogenic center.

Concept introduction: Alcohols are converted into alkyl tosylates by treatment with p-toluenesulfonyl chloride (TsCl) in the presence of pyridine. The overall reaction converts −OH (a poor leaving group) into −OTs (a good leaving group). The stereochemistry of the reaction is retention of configuration.

Interpretation Introduction

(b)

Interpretation: The products of the given reaction are to be drawn by indicating the stereochemistry at any stereogenic center.

Concept introduction: Alcohols are converted into alkyl tosylates by treatment with p-toluenesulfonyl chloride (TsCl) in the presence of pyridine. The overall reaction converts −OH (a poor leaving group) into −OTs (a good leaving group). The stereochemistry of the reaction is retention of configuration.

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Answer 4

Question

Chapter 9.13, Problem 23P

Interpretation Introduction

(a)

Interpretation: The products of the given reaction are to be drawn by indicating the stereochemistry at any stereogenic center.

Concept introduction: Alcohols are converted into alkyl tosylates by treatment with p-toluenesulfonyl chloride (TsCl) in the presence of pyridine. The overall reaction converts −OH (a poor leaving group) into −OTs (a good leaving group). The stereochemistry of the reaction is retention of configuration.

Interpretation Introduction

(b)

Interpretation: The products of the given reaction are to be drawn by indicating the stereochemistry at any stereogenic center.

Concept introduction: Alcohols are converted into alkyl tosylates by treatment with p-toluenesulfonyl chloride (TsCl) in the presence of pyridine. The overall reaction converts −OH (a poor leaving group) into −OTs (a good leaving group). The stereochemistry of the reaction is retention of configuration.

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Answer 5

Chapter 9.13, Problem 23P

Interpretation Introduction

(a)

Interpretation: The products of the given reaction are to be drawn by indicating the stereochemistry at any stereogenic center.

Concept introduction: Alcohols are converted into alkyl tosylates by treatment with p-toluenesulfonyl chloride (TsCl) in the presence of pyridine. The overall reaction converts −OH (a poor leaving group) into −OTs (a good leaving group). The stereochemistry of the reaction is retention of configuration.

Interpretation Introduction

(b)

Interpretation: The products of the given reaction are to be drawn by indicating the stereochemistry at any stereogenic center.

Concept introduction: Alcohols are converted into alkyl tosylates by treatment with p-toluenesulfonyl chloride (TsCl) in the presence of pyridine. The overall reaction converts −OH (a poor leaving group) into −OTs (a good leaving group). The stereochemistry of the reaction is retention of configuration.

Answer 6

Chapter 9.13, Problem 23P

Interpretation Introduction

(a)

Interpretation: The products of the given reaction are to be drawn by indicating the stereochemistry at any stereogenic center.

Concept introduction: Alcohols are converted into alkyl tosylates by treatment with p-toluenesulfonyl chloride (TsCl) in the presence of pyridine. The overall reaction converts −OH (a poor leaving group) into −OTs (a good leaving group). The stereochemistry of the reaction is retention of configuration.

Answer 7

Chapter 9.13, Problem 23P

Interpretation Introduction

(a)

Interpretation: The products of the given reaction are to be drawn by indicating the stereochemistry at any stereogenic center.

Concept introduction: Alcohols are converted into alkyl tosylates by treatment with p-toluenesulfonyl chloride (TsCl) in the presence of pyridine. The overall reaction converts −OH (a poor leaving group) into −OTs (a good leaving group). The stereochemistry of the reaction is retention of configuration.

Answer 8

Interpretation Introduction

(b)

Interpretation: The products of the given reaction are to be drawn by indicating the stereochemistry at any stereogenic center.

Concept introduction: Alcohols are converted into alkyl tosylates by treatment with p-toluenesulfonyl chloride (TsCl) in the presence of pyridine. The overall reaction converts −OH (a poor leaving group) into −OTs (a good leaving group). The stereochemistry of the reaction is retention of configuration.

Answer 9

Interpretation Introduction

(b)

Interpretation: The products of the given reaction are to be drawn by indicating the stereochemistry at any stereogenic center.

Concept introduction: Alcohols are converted into alkyl tosylates by treatment with p-toluenesulfonyl chloride (TsCl) in the presence of pyridine. The overall reaction converts −OH (a poor leaving group) into −OTs (a good leaving group). The stereochemistry of the reaction is retention of configuration.

Answer 10

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Answer 12

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Answer 13

Ch. 9.1 - Problem 9.1 Label each ether and alcohol in...Ch. 9.3 - Give the IUPAC name for each compound.Ch. 9.3 - Problem 9.3 Give the structure corresponding to...Ch. 9.3 - Name each of the following ethers.Ch. 9.3 - Name each epoxide. a. (two ways) b. c. (two...Ch. 9.6 - Problem 9.8 Draw the organic product of each...Ch. 9.6 - Prob. 9P Ch. 9.6 - Problem 9.10 Draw the products of each reaction. ...Ch. 9.8 - Problem 9.11 Draw the products formed when each...Ch. 9.8 - Prob. 12P

Solution Summary: The author explains that the products of the given reaction are drawn by indicating the stereochemistry at any stereogenic center.

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